宋利娟 - 哈尔滨工业大学（深圳）

个人简介

宋利娟2011年本科毕业于四川大学应用化学专业。后保送至北京大学物理化学专业吴云东院士课题组，获得博士学位。2018年获得洪堡学者，在德国吉森大学化学会主席Peter. R Schreiner课题组进行博士后研究。2021年3月加入哈尔滨工业大学任助理教授。宋利娟的研究方向主要是运用计算化学方法研究有机化学反应机理，为催化剂及底物的设计、筛选提供理论指导。目前已在国际期刊 Nat. Chem., Nat. Cat., J. Am. Chem. Soc.，Angew. Chem. Int. Ed. 等发表高水平论文 20多篇。教育经历 2007-2011 应用化学四川大学本科导师：冯小明院士 2011-2016 物理化学北京大学博士导师：吴云东院士工作经历 2016.9-2019.12 博士后、洪堡学者德国吉森大学合作导师：Peter. R Schreiner 2020.1-2021.3 助理研究员深圳湾实验室 2021.3-至今助理教授哈尔滨工业大学理学院

研究领域

有机反应机理运用量子化学理论计算方法，实现有机小分子及金属催化的有机反应热力学性质的高精度计算，阐明有机化学反应中的结构-性能关系; 化学反应的反应机理研究，理解并分析反应活性和选择性的决定因素，为催化剂及底物的设计、筛选提供理论指导非共价相互作用对范德华作用的主要组成部分色散力进行研究，通过色散吸引作用来实现对结构的稳定作用，基于此对催化剂结构进行改进设计，实现反应选择性的控制。将非共价相互作用发展成为一个调控化学反应选择性的原则应用于设计新的化学反应和催化剂材料计算储能电极材料，二维材料等的第一性原理计算，从分子水平设计新型材料

近期论文

查看导师最新文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Zhang, Z#.; Zhang, X#.; Wang, Y.; Liu, Y.; Wang, Y.; Zhang, X*.; Ma, J*.; Song, L*.;Nitro – a traceless directing group for reversing the radical site-selectivity of styrene derivatives. Org. Chem. Front., 2023, 10, 5496-5504. (# co-first author) Zeng, J.; Chen, W.; Zhang, G.; Yang, S.; Yu, L.; Cao, X.; Chen, H.; Liu, Y.; Song, L.*; Qiu, Y.*, In-situ prepared NiMoO4 nanocrystals synergizes with nickel micro-tubes with hydrodynamic effects for energy-saving watersplitting. Chem. Eng. J. 2023, 471, 144657. Xu, A.; Li, C.; Huang, J.; Pang, H.; Zhao, C.; Song, L.*; You, H.*; Zhang, X.; Chen, F.-E.*, Highly enantioselective synthesi s of both tetrahydroquinoxalines and dihydroquinoxalinones via Rh–thiourea catalyzed asymmetric hydrogenation. Chem. Sci. 2023, 14, 9024-9032. Xu, J.; Xu, W.; Zhang, X.; Wu, J.; Zhang, P.;* Song, L.;* Liu, X.* Divergent Synthesis of Quinolones through Radical C–H Functionalization/Cyclization. Adv. Synth. Catal. 2023, 365, 1853-1863. Xie, Y.; Liu, H.; Li, Z.-L.; Zhang, X.; Song, L.; Zhou, K.; Yuan, F.; You, H.; Zhao, E.; He, Z.* Construction of chiral through-space luminophores by sequenced chlorination triggered symmetry break.” Sci China Chem, 2023, 66, 2083-2090. Bai, J. R.; Li, S. J.; Qi, D.; Song, Z. H.; Li, B.; Guo, L.; Song, L. J.;* Xia, W. J., Visible-Light-Induced Trifluoromethylsulfonylation Reaction of Diazo Compounds Enabled by Manganese Catalysis. Org. Lett. 2023. 15, 2410-2414. Wang, Y.; Li, Y,; Wang, L.; Ding, S.; Song, L.;* Zhang, X.;* Wu, Y.;* Sun, J.* Ir-Catalyzed Regioselective Dihydroboration of Thioalkynes toward Gem-Diboryl Thioethers J. Am. Chem. Soc. 2023, 145, 2305–2314. Tang, C.; Song, L.;# Zhou, K.; Ren, P.;* Zhao, EG.;* He, Z.* Manipulating D-A interaction to achieve stable photoinduced organic radicals in triphenylphosphine crystals. Chem. Sci., 2023, 14, 2041-6539. (# co-first author) Zhu, J. Y.; Moreno, I.; Quinn, P.; Yufit, D. S.; Song, L. J.; Young, C. M.; Duan, Z. A.; Tyler, A. R.; Waddell, P. G.; Hall, M. J.; Probert, M. R.; Smith, A. D.; O'Donoghue, A. C., The Role of the Fused Ring in Bicyclic Triazolium Organocatalysts: Kinetic, X-ray, and DFT Insights. J. Org. Chem. 2022, 87, 4241-4253. Feng, Q.; Li, S, Li, Z., Yan, Q., Lin, X., Song, L.*, Zhang, X.*, Wu, Y.*, and Sun, J.* Ru- catalyzed hydroboration of ynones leads to a nontraditional mode of reactivity. J. Am. Chem.Soc. 2022, 144, 14846–14855. Tan, Y.-X.; Li, S.; Song,L.; *Zhang, X.;* Wu, Y.-D.;* Sun, J.,* Ruthenium-catalyzed geminal hydroborative cyclization of enynes. Angew. Chem. Int. Ed. 2022, 61, e202204319. Qi, D.; Bai, J.; Zhang, H.; Li, B.; Song, Z.; Ma, N.; Guo, L.;* Song, L.;* Xia, W. Photoinduced synthesis of functionalized oxetanes via diradical-mediated ring contraction. Green Chem. 2022.24, 5046-5051. Gan, S.; Yin, J.; Yu, Z.; Song, L.;* Shi, L.,* A one-pot and two-stage Baeyer–Villiger reaction using 2,2′-diperoxyphenic acid under biomolecule-compatible conditions. Green Chem. 2022. 24, 2332-2339. Hou, Z.;# Wang, Y.;# Wan, C.;# Song, L.;# Wang, R.; Guo, X.; Yang, D.; Zhang, Y.; Qin,X.; Zhou, Z.; Zhang, X.; Yin, F.; Li, Z. Sulfonium triggered alkyne–azide click cycloaddition. Org. Lett. 2022, 24, 1448-1453. (# co-first author) Chen, H.; Wang, L.; Xu, S.; Liu, X.; He, Q.; Song, L.;* Ji, H.* Selective functionalization of hydrocarbons using a ppm bioinspired molecular tweezer via proton-coupled electron transfer. ACS Catal. 2021, 6810-6815. Feng, Q.; Wu, A.; Zhang, X.; Song, L.;* Sun, J.* An unusual formal migrative cycloaddition of aurone-derived azadienes: synthesis of benzofuran-fused nitrogen heterocycles. Chem. Sci. 2021, 12, 7953-7957. Ge, L.; Zhou, H.; Chiou, M.-F.; Jiang, H.; Jian, W.; Ye, C.; Li, X.; Zhu, X.; Xiong, H.; Li, Y.; Song, L.; Zhang, X.;* Bao, H.*. Iron-catalysed asymmetric carboazidation of styrenes. Nature Catalysis, 2021, 4, 28-35. Sun, S.; Wang, Z.; Li, S.; Zhou, C.; Song, L.; Huang, H.; Sun, J.* An organocatalytic kinetic resolution of aziridines by thiol nucleophiles. Org. Lett. 2021, 23, 554-558. (Before join HITSZ.) Eschmann, C.;# Song, L.;# Schreiner, P. R. London Dispersion Interactions Rather than Steric Hindrance Determine the Enantioselectivity of the Corey–Bakshi–Shibata Reduction. Angew. Chem. Int. Ed. 2021, 60, 4823-4832. (# co-first author) Properzi, R.; Kaib, P. S. J.; Leutzsch, M.; Pupo, G.; Mitra, R.; De, C. K.; Song, L.; Schreiner, P. R.; List, B. Catalytic enantiocontrol over a non-classical carbocation. Nature Chem. 2020, 12, 1174-1179. Feng, Q.; Wu H.; Li, X.; Song, L-J; Chung, L. W.;* Wu,* Y-D.; Sun, J.;* Ru-Catalyzed Geminal hydroboration of internal alkynes via a new gem-addition mechanism. J. Am. Chem. Soc. 2020, 142, 13867–13877. Ganesamoorthy, C.; Schoening, J.; W？lper, C.; Song, L-J.; Schreiner, P. R.;* Schulz, S.*. A silicon–carbonyl complex stable at room temperature. Nat. Chem. 2020, 12, 608–614. Song, L-J.;# Feng, Q.;# Wang, Y.; Ding, S.; Wu, Y-D., Zhang, X.; Chung, L. W.;* Sun, J.* Ru-catalyzed migratory geminal semi-hydrogenation of internal alkynes to terminal olefins. J. Am. Chem. Soc. 2019, 141, 43, 17441-17451. (#co-first author) Song, L-J.; Keul, F.; Mardyukov, A. Preparation and spectroscopic identification of methyl-Se-nitrososelenol. Chem. Commun. 2019, 55, 9943-9946. Song, L-J.; Schoening, J.; W？lper, C.; Schulz, S.;* Schreiner, P. R.* The role of london dispersion interactions in ga‐substituted dipnictenes. Organometallics, 2019, 38, 1640-1647. Krüger, J.; W？lper, C.; John, L.; Song, L-J.; Schreiner, P. R.;* Schulz, S.* Syntheses, Structures, and Bonding Analyses of Carbene-Stabilized Stibinidenes. Eur. J. Inorg. Chem. 2019, 1669-1678. Song, L-J.; Wang, T.; Zhang, X.;* Chung, L. W.;* Wu, Y-D.* A combined DFT/IM-MS study on the reaction mechanism of cationic Ru(II)-catalyzed hydroboration of alkynes. ACS catal. 2017, 7, 1361–136. Combe, S. H.; Hosseini, A.; Song, L-J.; Hausmann, H.; Schreiner, P. R.* Catalytic Halogen Bond Activation in the Benzylic C–H Bond Iodination with Iodohydantoins. Org. Lett. 2017, 19, 6156-6159. Song, L-J.;# Ding, S.;# Wang,Y.; Zhang, X.;* Wu, Y-D.;* Sun, J.* Ir-Catalyzed Regio- and Stereoselective Hydrosilylation of Internal Thioalkynes: A Combined Experimental and Computational Study. J. Org. Chem. 2016, 81, 6157–6164. (#co-first author) Wang, Y.; Song, L-J.; Zhang, X.;* Sun, J.* Metal-Free [2+2+2] Cycloaddition of Ynamides and Nitriles: Mild and Regioselective Synthesis of Fully Substituted Pyridines. Angew. Chem. Int. Ed. 2016, 55, 9704–9708. Ding, S.;# Song, L-J.;# Wang, Y.; Zhang, X.;* Chung, L. W.;* Wu, Y-D.;* Sun, J.* Highly Regio- and Stereoselective Hydrosilylation of Internal Thioalkynes Under Mild Conditions. Angew. Chem. Int. Ed. 2015, 54, 5632 –5635. (#co-first author) Ding, S.;# Song, L-J.;# Chung, L. W.; Zhang, X.; Sun, J.;* Wu, Y-D.* Ligand-Controlled Remarkable Regio- and Stereodivergence in Intermolecular Hydrosilylation of Internal Alkynes: Experimental and Theoretical Studies. J. Am. Chem. Soc. 2013, 135, 13835-13842. (#co-first author) Cheng, G-J.; Song, L-J.; Yang, Y-F.; Zhang, X.;* Wiest, O.;* Wu, Y-D.* Computational Studies on the Mechanism of the Copper-Catalyzed sp3-C-H Cross-Dehydrogenative Coupling Reaction. ChemPlusChem, 2013, 78, 943-951.