个人简介
Education
2012-2017 State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, China. Received Ph.D. Degree in July, 2017(with Prof.Qi-Lin Zhou).
2008-2012 China Pharmaceutical University, Nanjing, China. Received B. Sc. Degree in July, 2012.
Academic Career
2021- Professor (tenure-track),State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, China.
2018-2021 Postdoctoral Associate, Department of Chemistry, The Scripps Research Institute. San Diego, USA. (with Prof. Jin-Quan Yu).
HONORS AND AWARDS
2023 Thieme Chemistry Journals Award
2022 National Outstanding Young Talents Program (NSFC)
2021 Nankai University Hundred Young Academic Leaders Program
研究领域
(1) Organometallic Chemistry
(2) Transition-Metal Catalysis
(3) Catalytic Asymmetric Synthesis
近期论文
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Tianze Zhang, Shan Jiang, Meng-Ying Qian, Qi-Lin Zhou, Li-Jun Xiao*. Ligand-Controlled Regiodivergent Nickel-Catalyzed Hydroaminoalkylation of Unactivated Alkenes. J. Am. Chem. Soc. 2024, 146, DOI: 10.1021/jacs.3c13060.
Jin-Tao Ma, Tianze Zhang, Bo-Ying Yao, Li-Jun Xiao*, Qi-Lin Zhou. Diastereodivergent and Enantioselective Synthesis of Homoallylic Alcohols via Nickel-Catalyzed Borylative Coupling of 1,3-Dienes with Aldehydes. J. Am. Chem. Soc. 2023, 145, 19195−19201.
Wei-Guo Xiao, Bin Xuan, Li-Jun Xiao*, Qi-Lin Zhou. Practical Synthesis of Allylic Amines via Nickel-Catalysed Multicomponent Coupling of Alkenes, Aldehydes, and Amides. Chem. Sci. 2023, 14, 8644–8650.
Ming-Ming Li, Tianze Zhang, Lei Cheng, Wei-Guo Xiao, Jin-Tao Ma, Li-Jun Xiao*, Qi-Lin Zhou*. Ketone α-Alkylation at the More-Hindered Site. Nat. Commun. 2023, 14, 3326.
Biao Wang, Tianze Zhang, Li-Jun Xiao*, Qi-Lin Zhou*. Nickel-Catalyzed Intermolecular Reductive Coupling of Styrene and Its Derivatives with Imines Using Methanol as a Reductant. ACS Catal. 2023, 13, 8692−8699.
Biao Wang, Xian-Ming Liu, Kai-Xiang Zhang, Wei-Min Feng, Li-Jun Xiao*, Qi-Lin Zhou*. Diastereoselective and Enantioselective Nickel-Catalyzed Reductive Coupling of Imines and Unactivated Alkenes. CCS Chem. 2023, 5, 814–822.
Xiao-Ya Sun, Bo-Ying Yao, Bin Xuan, Li-Jun Xiao*, Qi-Lin Zhou*. Recent Advances in Nickel-Catalyzed Asymmetric Hydrofunctionalization of Alkenes. Chem Catalysis 2022, 2, 1–23.
Chao Fan, Xin-Yang Lv, Li-Jun Xiao*, Jian-Hua Xie, Qi-Lin Zhou*. Alkenyl Exchange of Allylamines via Nickel(0)-Catalyzed C−C Bond Cleavage. J. Am. Chem. Soc. 2019, 141, 2889−2893.
Lei Cheng, Ming-Ming Li, Li-Jun Xiao*, Jian-Hua Xie, Qi-Lin Zhou*. Nickel(0)-Catalyzed Hydroalkylation of 1,3-Dienes with Simple Ketones. J. Am. Chem. Soc. 2018, 140, 11627–11630.
Xin-Yang Lv, Chao Fan, Li-Jun Xiao*, Jian-Hua Xie, Qi-Lin Zhou*. Ligand-Enabled Ni-Catalyzed Enantioselective Hydroarylation of Styrenes and 1,3-Dienes with Arylboronic Acids. CCS Chem. 2019, 1, 328−334.
Li-Jun Xiao, Kai Hong, Fan Luo, Liang Hu, William R. Ewing, Kap-Sun Yeung, Jin-Quan Yu*, PdII-Catalyzed Enantioselective C(sp3)–H Arylation of Cyclobutyl Ketones Using a Chiral Transient Directing Group, Angew. Chem. Int. Ed. 2020, 59, 9594−9600.
Jin-Tang Cheng#, Li-Jun Xiao#, Shao-Qun Qian, Zhe Zhuang, An Liu, Jin-Quan Yu*. Palladium(II)-Catalyzed Selective Arylation of Tertiary C–H Bonds of Cyclobutylmethyl Ketones Using Transient Directing Groups. Angew. Chem. Int. Ed. 2022, 61, e202117233.
Guowei Kang#, Li-Jun Xiao#, Kevin D. Hesp, Chan Woo Huh, Yajing Lian, Paul Richardson, Daniel C. Schmitt, Kai Hong, Jin-Quan Yu*. Synthesis of Highly Substituted Aminotetrahydropyrans Enabled by Stereospecific Multivector C−H Functionalization. Org. Lett. 2023, 25, DOI: 10.1021/acs.orglett.3c01439.
Li-Jun Xiao, Chao-Yue Zhao, Lei Cheng, Bo-Ya Feng, Wei-Min Feng, Jian-Hua Xie, Xiu-Fang Xu*, Qi-Lin Zhou*, Nickel(0)-Catalyzed Hydroalkenylation of Imines with Styrene and Its Derivatives, Angew. Chem. Int. Ed. 2018, 57, 3396−3400.
Li-Jun Xiao, Lei Cheng, Wei-Min Feng, Mao-Lin Li, Jian-Hua Xie, Qi-Lin Zhou*, Nickel(0)-Catalyzed Hydroarylation of Styrenes and 1,3-Dienes with Organoboron Compounds, Angew. Chem. Int. Ed. 2018, 57, 461−464.
Li-Jun Xiao, Xiao-Ning Fu, Min-Jie Zhou, Jian-Hua Xie, Li-Xin Wang, Xiu-Fang Xu*, Qi-Lin Zhou*, Nickel-Catalyzed Hydroacylation of Styrenes with Simple Aldehydes: Reaction Development and Mechanistic Insights, J. Am. Chem. Soc. 2016, 138, 9, 2957–2960.