王元桦 - 四川大学

个人简介

四川大学化学系本科毕业。2004年在中国科学院成都有机化学研究所获有机化学博士学位。2005-2007年在美国马里兰大学(University of Maryland, College Park)化学与生物化学系进行博士后研究。2007-2011年在美国斯克普利斯研究所(The Scripps Research Institute)担任助理研究员。2011年，作为四川大学引进人才回国工作，从事教学科研工作。2013年至今，开始独立进行科研工作。

研究领域

课题组研究围绕过渡金属催化烯烃和烷烃的选择性官能化反应展开，重点探索金属自由基反应在碳氧键形成和碳氮键形成中的应用；基于双核铑金属的单电子氧化反应，提出了不同于经典的双核铑卡宾，氮宾中间体的新反应模式，发展了基于双核铑单电子氧化中间体的高效绿色氧化和碳氮键形成反应。利用高价金属化学策略，基于稳定双铑化合物的结构特点，从金属配合物的定量反应来探索活性中间体的微观结构和反应成键模式，建立与催化反应直接的直接关系，发展新型高效的金属催化剂。

近期论文

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Liu, X. Y., Wang, Z. F., Wang, Q. W. Wang, Y. H.*, Rhodium(II)‐Catalyzed C(sp3)–H Diamination of Arylcyclobutanes. Angew. Chem. Int. Ed. 2022. DOI: 10.1002/anie.202205493. Wang, Z. F., Yang, B. Q., Yang, Q., Wang, Y. H.* C(sp3)–H 1,3-diamination of cumene derivatives catalyzed by a dirhodium(ii) catalyst. Org. Chem. Front. 2022. DOI:10.1039/D2QO00461E. Fan, Z. Y., Wang, Z. F., Shi, R. Y., Wang, Y. H.* Dirhodium(ii)-catalyzed diamination reaction via a free radical pathway. Org. Chem. Front. 2021, 8, 5098-5104. Ning, Y.-B., Tan, J.-T., Wang, Z.-F., Wang, Y.-H.*, Fine-tuning dirhodium compounds with bridging ligands: Synthesis, structure, catalytic efficiency. J. Organomet. Chem. 2021, 122078, 954. Wang, Y., Fang Z.X., Chen, X. C., and Wang, Y. H.* “Dirhodium(II)-Catalyzed C(sp2)-H Azidation of Benzaldehydes” Chemistry-A European Journal, 2020, 26, 6805. (Front Cover) Wang, Y., Chen, X. C., Jin, H.* and Wang, Y. H.* “Mild and Practical Dirhodium(II)/NHPI‐Mediated Allylic and Benzylic Oxidations with Air as the Oxidant” Chemistry—A European Journal, 2019, 10.1002/chem.201902739 (Front Cover) Liu, W. T., Kuang, Y., Wang, Z. F., Zhu, J, Wang, Y. H.* “Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives” Beilsten Journal of Organic Chemistry, 2019, 15, 542. Fang, Z. X., Wang, Y., Wang, Y. H.* “Synthesis of 4-Iodoisoquinolin-1(2H)-ones by a Dirhodium(II)-Catalyzed 1,4-Bisfunctionalization of Isoquinolinium Iodide Salts” Organic Letters, 2019, 21, 434. Wang, Y., Fang, Z. X., Chen, X. C*, Wang, Y. H.* “Mild Dirhodium(II)-Catalyzed Chemo- and Regioselective Azidation of Arenes” Organic Letters, 2018, 20, 5732. (Highlighted by www.organic-chemistry.org) Ma, Z. L., Wang, Y. H.* “Dirhodium(II)/P(t-Bu)3 catalyzed tandem reaction of α,β-unsaturated aldehydes with arylboronic acids” Organic & Biomolecular Chemistry , 2018, 16, 7470. Kuang, Y., Ning, Y. B., Zhu, J and Wang, Y. H.* “Dirhodium(II)-Catalyzed (3 + 2) Cycloaddition of the N-Arylaminocyclopropane with Alkene Derivatives” Organic Letters, 2018, 20, 2693. Zhao, L. L., Wang, Y., Ma, Z. L., Wang, Y. H.* “Dirhodium(II)-Catalyzed Carbonylation Peroxidation of α, β-Unsaturated Esters: Mechanistic Insight into the Role of Aryl Aldehydes” Inorganic Chemistry, 2017, 56, 8166. Wang, Y., Kuang, Y., Zhang, H. Y., Ma, R. C., Wang, Y. H.* “Recyclable Dirhodium(II) Catalyst Rh2(esp)2 for the Allylic Oxidation of Δ5-Steroids” Journal of Organic Chemistry, 2017, 82, 4729. Tan, J. T., Kuang, Y., Wang, Y., Huang, Q.*, Zhu, J., Wang, Y. H.* “Axial Tri-tert-butylphosphane Coordination to Rh2(OAc)4: Synthesis, Structure, and Catalytic Studies” Organometallics, 2016, 35, 3139. Zhao, L. L., Zhang, H. Y., Wang, Y. H.* “Dirhodium(II)-Catalyzed Sulfide Oxygenations: Catalyst Removal by Coprecipitation with Sulfoxides” Journal of Organic Chemistry, 2016, 81, 129. (Highlighted by X-MOL, www.organic-chemistry.org) Wang, Y., Kuang, Y., Wang, Y. H.* “Rh2(esp)2-catalyzed allylic and benzylic oxidations” Chemical Communication, 2015, 51, 5852. Kuang Y., Wang, Y. H.* “Dirhodium(II)-catalyzed Cross-Coupling Reactions of Aryl Aldehydes with Arylboronic Acids in Water” European Journal of Organic Chemistry, 2014, 1163.