Whiting, Andrew - Durham University - Department of Chemistry

个人简介

PhD (1981-’84): University of Newcastle upon Tyne, working on beta-lactam chemistry. Post-doctoral research (1984-’86): Boston College, MA, USA, working on natural product synthesis and asymmetric synthesis and developing chiral Diels-Alder Lewis-acid catalysts. Industrial experience (1986-’88): Ciba-Geigy plc., Central Research UK, working on varied topics, including developing new methodology for the preparation of novel amino-acid analogues and asymmetric synthesis. Academic experience: Chemistry Department, UMIST (1989-2001), moved to Readership at Durham (2001) and promoted to Professor in 2009.

研究领域

Asymmetric Catalysis Bifunctional Catalysis Target and Natural Product Synthesis

近期论文

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Girling, P.R., Batsanov, A.S., Calow, A.D.J., Shen, H.C. & Whiting, A. (2016). Alternative tandem cyclisation pathways in the reaction between imines and enones,. Tetrahedron 72(8): 1105-1113. Chisholm, David R., Valentine, Roy, Pohl, Ehmke & Whiting, Andrew (2016). Conjugate Addition of 3Buytn-2-one to Anilines in Ethanol: Alkene Geometric Insights through In Situ FTIR Monitoring. The Journal of Organic Chemistry 81(17): 7557-7565. Chisholm, D. R., Zhou, G.-L., Pohl, E., Valentine, R. & Whiting, A. (2016). Practical synthetic strategies towards lipophilic 6-iodotetrahydroquinolines and -dihydroquinolines. Beilstein Journal of Organic Chemistry 12: 1851-1862. Liu, S., Zhang, Q., Li, H., Yang, Y., Tiana, X. & Whiting, A. (2015). A visible light induced α-H chlorination of alkylarenes with inorganic chloride under nanoAg@AgCl. Chemistry: A European Journal 21(27): 9671-9675. Chaiyaveij, D., Batsanov, A.S., Fox, M.A., Marder, T.B. & Whiting, A. (2015). An experimental and computational approach to understanding the reactions of acyl nitroso compounds in [4+2]-cycloadditions. The Journal of Organic Chemistry 80(19): 9518-9534. Whiting, Andrew, Madden, Katrina S., David, Sylvain & Knowles, Jonathan P. (2015). Heck-Mizoroki Coupling of Vinyliodide and Applications in The Synthesis of Dienes and Trienes. Chemical Communications 51(57): 11409-11412. Pujol, A., Calow, A. D. J., Batsanov, A. S. & Whiting, A. (2015). One-pot catalytic asymmetric borylation of unsaturated aldehyde-derived imines; functionalisation to homoallylic boronate carboxylate ester derivatives. Organic & Biomolecular Chemistry 13(18): 5122-5130. Eberlin, Ludovic, Carboni, Bertrand & Whiting, Andrew (2015). Regioisomeric and substituent effects upon the outcome of the reaction of 1-borodienes with nitrosoarene compounds. The Journal of Organic Chemistry 80(13): 6574-6583. La Cascia, E., Sanz, X., Bo, C., Whiting, A. & Fernandez, E. (2014). Asymmetric metal free β-boration of α,β-unsaturated imines assisted by (S)-MeBoPhoz. Organic and Biomolecular Chemistry 13(5): 1328-1332. Batsanov, A. S., Georgiou, I., Girling, P. R., Pommier, L., Shen, H. C. & Whiting, A. (2014). Asymmetric synthesis and application of homologous pyrroline-2-alkylboronic acids: Identification of the B-N distance for eliciting bifunctional catalysis of an asymmetric aldol reaction. Asian Journal of Organic Chemistry 3(4): 470-479. Madden, K. S., Mosa, F. A. & Whiting, A. (2014). Non-isoprenoid polyene natural products - structures and synthetic strategies. Org. Biomol. Chem 12: 7877-7899. Calow, A. D. J., Carbó, J. J., Cid, J., Fernández, E. & Whiting, A. (2014). Understanding α,β-unsaturated imine formation from amine additions to α,β-unsaturated aldehydes and ketones: an analytical and theoretical investigation. The Journal of Organic Chemistry 79(11): 5163-5172. Tripoteau, F., Eberlin, L., Fox, M. A., Carboni, B. & Whiting, A. (2013). A novel, efficient synthesis of N-aryl pyrroles via reaction of 1-boronodienes with arylnitroso compounds. Chemical Communications 49(47): 5414-5416. Calow, A. D. J., Batsanov, A. S., Pujol, A., Solé, C., Fernández, E. & Whiting, A. (2013). A selective transformation of enals into chiral γ-amino alcohols. Organic Letters 15(18): 4810-4813. Calow, A. D. J., Solé, C., Whiting. A. & Fernández, E. (2013). Base-free β-boration of α,β-unsaturated imines catalysed by Cu2O with concurrent enhancement of asymmetric induction. ChemCatChem 5(8): 2233-2239. Clemens, G., Flower, K.R., Gardner, P., Henderson, A. P., Knowles, J. P., Marder, T. B., Whiting, A. & Przyborski, S. A. (2013). Design and biological evaluation of synthetic retinoids: Probing length vs. stability vs. activity. Molecular BioSystems 9(12): 3124-3134. Liu, S., Yang, Y., Liu, X., Ferdousi, F. K., Batsanov, A. S. & Whiting, A. (2013). Direct Amidation of Amino Acid Derivatives Catalyzed by Arylboronic Acids: Applications in Dipeptide Synthesis. European Journal of Organic Chemistry 2013(25): 5692-5700. Ilyashenko, G., Al-Safadi, R., Donnan, R., Dubrovka, R., Pancholi, J., Watkinson, M. & Whiting, A. (2013). Facile synthesis of a 1,1’-desymmetrised ferrocene backbone and its one-pot double-“click” functionalisation. RSC Advances 3(38): 17081-17087. Zhou, G.-L., Tams, D. M., Marder, T. B., Valentine, R., Whiting, A. & Przyborski, S. A. (2013). Synthesis and applications of 2,4-disubstituted thiazoles derivatives as small molecule modulators of cellular development. Organic & Biomolecular Chemistry 11(14): 2323-2334. Clemens, G., Flower, K. R., Henderson, A. P., Whiting, A., Przyborski, S. A., Jimenez-Hernandez, M., Ball, F., Bassan, P., Cinque, G. & Gardner, P. (2013). The action of all-trans-retinoic acid (ATRA) and synthetic retinoid analogues (EC19 and EC23) on human pluripotent stem cells differentiation investigated using single cell infrared microspectroscopy. Molecular BioSystems 9(4): 677-692.