曲剑萍 - 南京工业大学 - 化学与分子工程学院

个人简介

2016年至今南京工业大学，先进化学制造研究院，教授 2011-2015 海德堡大学化学系，博士后，洪堡学者 (Günter Helmchen 教授) 2006-2011 上海有机化学研究所，理学博士（唐勇研究员） 2001-2005 山东师范大学化学系，理学学士

研究领域

1. 新型过渡金属催化剂的设计以及在新反应开发、配位聚合反应中的应用； 2. 新型功能聚合物的合成方法以及应用开发； 3.手性聚酯、聚酰胺、聚砜等光学活性聚合物的研究。

近期论文

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1. Copper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay, X.-H. Shan, H.-X. Zheng, B. Yang, L. Tie, Jia-Le Fu, J.-P. Qu*, Y.-B. Kang,* Nature Commun. 2019, 10, 908. 2. Organocatalyzed Aerobic Oxidation of Aldehydes to Acids, P.-F. Dai, J.-P. Qu*, Y.-B. Kang,* Org. Lett. DOI: 10.1021/acs.orglett.9b00101 3. Iridium-Catalyzed Asymmetric Allylic Substitution Reactions, Q. Cheng, H.-F. Tu, C. Zheng, J.-P. Qu, G. Helmchen,* Shu-Li You,* Chem. Rev. 2019, 119, 1855. 4. One-pot one-base conditions for two shots: organocatalyzed tandem isomerization-olefination of allylic alcohols, H.-X. Zheng, Qu, J.-P. Qu*, Y.-B. Kang,* Org. Chem. Front. 2018, 5, 2349. 5. Phenanthroline-tBuOK Promoted Intramolecular C–H Arylation of Indoles with ArI under Transition-Metal-Free Conditions, X.-H. Shan, B. Yang, H.-X. Zheng, Qu, J.-P. Qu*, Y.-B. Kang,* Org. Lett. 2018, 20, 7898. 6. Strategy for Overcoming Full Reversibility of Intermolecular Radical Addition to Aldehydes: Tandem C-H and C-O Bonds Cleaving Cyclization of (Phenoxymethyl)arenes with Carbonyls to Benzofurans, H.-X. Zheng, X.-H. Shan, J.-P. Qu*, Y.-B. Kang,* Org. Lett. 2018, 20, 3310. 7. Synthesis of Functionalized Indoles via Palladium-Catalyzed Aerobic Cycloisomerization of o-Allylanilines Using Organic Redox Cocatalyst, X.-S. Ning, M.-M. Wang, Qu, J.-P. Qu*, Y.-B. Kang,* J. Org. Chem. 2018, 83, 13523. 8. Tuning Regioselectivity of Wacker Oxidation in One Catalytic System: Small Change Makes Big Step, K.-F. Hu, X.-S. Ning, J.-P. Qu*, Y.-B. Kang,* J. Org. Chem. 2018, 83, 11327. 9. Pd-tBuONO Cocatalyzed Aerobic Indole Synthesis, X.-S. Ning, X. Liang, K.-F. Hu, C.-Z. Yao, J.-P. Qu*, Y.-B. Kang,* Adv. Synth. Catal. 2018, 360, 1590. 10. nBu4NOTf-Promoted Radical Self-Hydrogen Transferring Isomerization under Transition Metal-Free Conditions H.-X. Zheng, C.-Z. Yao, J.-P. Qu*, Y.-B. Kang,* Org. Chem. Front. 2018, 5, 1213. 11. Synthesis of Highly Functionalized Indoles and Indolones via Selectivity-Switchable Olefinations, T.-H. Ding, Z.-F. Xiao, J.-P. Qu*, Y.-B. Kang*, J. Org. Chem. 2018, 83, 2467. 12. Direct Wittig Olefination of Alcohols, Q.-Q. Li, Z. Shah, J.-P. Qu*, Y.-B. Kang*, J. Org. Chem. 2018, 83, 296. 13. Applications of Iridium-Catalyzed Asymmetric Allylic Substitution Reactions in Target-Oriented Synthesis, J.-P. Qu, G. Helmchen*, Acc. Chem. Res. 2017, 50, 2539. 14. Dehydrogenative Synthesis of Linear α,β-Unsaturated Aldehydes with Oxygen at Room Temperature Enabled by tBuONO, M.-M. Wang, X.-S. Ning J.-P. Qu*, Y.-B. Kang*, ACS Catal. 2017, 7, 4000. 15. Organopromoted Selectivity-Switchable Synthesis of Polyketones, J. Liu, K.-F. Hu, J.-P. Qu*, Y.-B. Kang*, Org. Lett. 2017, 19, 5593. 16. H.-X. Zheng, X.-H. Shan, J.-P. Qu*, Y.-B. Kang*, Transition-Metal-Free Hydrogenation of Aryl Halides: From Alcohol to Aldehyde, Org. Lett. 2017, 19, 5114. Selected Post-Doctoral and Ph.D. Publications 1. Enantio- and Regioselective Iridium-Catalyzed Allylic Esterification, J.-P. Qu, L. Roeberg, G. Helmchen*, J. Am. Chem. Soc. 2014, 136, 1272. 2. Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor–Acceptor Cyclopropanes: Accessing 3a-Hydroxy [n.3.0] Carbobicycles,Xu, J.-P. Qu, S. Liao, H. Xiong, Y. Tang*, Angew. Chem. Int. Ed. 2013, 52, 4004. 3. Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity,J.-P. Qu, Y. Liang, H. Xu, X. Sun, Z. Yu, Y. Tang*, Chem. Eur. J. 2012, 18, 2196. 4. Switchable Reactions of Cyclopropanes with Enol Silyl Ethers. Controllable Synthesis of Cyclopentanes and 1,6-Dicarbonyl Compounds,J.-P. Qu, C. Deng, J. Zhou, X. Sun, Y. Tang*, J. Org. Chem. 2009, 74, 7684. 5. Ligand-accelerated Asymmetric [1,2]-Stevens Rearrangment of Sufur Ylides via Decomposition of Diazomalonates Catalyzed by Chiral Bisoxazoline/Copper Complex,J.-P. Qu, Z. Xu, J. Zhou, C. Cao, X. Sun, L. Dai, Y. Tang*, Adv. Synth. Catal. 2009, 351, 308.