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S. Lin; Z. Mo; P. Wang; C. He*. Oxidation and Phenolysis of Peptide/Protein C-Terminal Hydrazides Afford Salicylaldehyde Ester Surrogates for Chemical Protein Synthesis. J. Am. Chem. Soc. 2023, Accepted Article. (10.1021/jacs.3c05190) Y. Chen#; Y. Zhou#; C. He*. Insertion of unnatural metal ligand in the heme pocket of nitrophorin through protein semi-synthesis: toward biomimicking binuclear active sites. Chin. Chem. Lett., 2023, Accepted Article. (#equal contribution) (10.1016/j.cclet.2023.108251) Z. Mo; Z. Xiao; C. He*. Functional expression of a thrombin exosite I inhibitor triabin in Escherichia coli and elucidation of the role of key residues in its inhibitory activity. Biochimie, 2023, 208, 13–19. (10.1016/j.biochi.2022.12.013) S. Huang; W-H. Deng; R-Z. Liao* and C. He*. Repurposing a Nitric Oxide Transport Hemoprotein Nitrophorin 2 for Olefin Cyclopropanation. ACS Catal., 2022, 12(21), 13725–13731 (10.1021/acscatal.2c03515) Y. Zhou; Y. Sun; K. Yi; Z. Wang; Y. Liu and C. He*. Solid-phase synthesis of peptides with azopyridine side-chains for Mn(i)–CO binding and red-light responsive CO release. Inorg. Chem. Front., 2022, 9(22), 5941–5949 (10.1039/D2QI01653B) Y. Yang; M. Liang; R. Wang; Z. Wang* and C. He*. key modulation mechanism of the tyrosine-O-sulfation in inducing strengthened inhibitory activity of hirudin. Chin. Chem. Lett., 2022, 34(5), 107806. (10.1016/j.cclet.2022.107806) P. Liao; H. Liu* and C. He*. Chemical Synthesis of Human Selenoprotein F and Elucidation of Its Thiol-Disulfide Oxidoreductase Activity. ChemRxiv, 2022. (10.26434/chemrxiv-2022-j6nwl) Z. Mo; S. Lin; W. Chen and C. He*. Protein Ligation and Labeling Enabled by a C-Terminal Tetracysteine Tag. Angew. Chem. Int. Ed., 2022, Accepted Article. (10.1002/anie.202115377) P. Liao and C. He*. Chemical Synthesis of the Sec-To-Cys Homologue of Human Selenoprotein F and Elucidation of Its Disulfide-pairing Mode. Front. Chem., 2021, 9, 735149. (10.3389/fchem.2021.735149) Y. Zhang#; J. Chen# and C. He*. On Demand Attachment and Detachment of rac-2-Br-DMNPA Tailoring to Facilitate Chemical Protein Synthesis. Org. Lett., 2021, 23, 6477-6481. (10.1021/acs.orglett.1c02295) S. Lin and C. He*. Development of Nonheme {FeNO}7 Complexes Based on the Pyrococcus furiosus Rubredoxin for Red-Light-Controllable Nitric Oxide Release. Inorg. Chem., 2021, 60, 14364-14370. (10.1021/acs.inorgchem.1c02089) Y. Zhou#; Y. Chen# and C. He*. Solid-phase synthesis of peptide Mn(I)–carbonyl bioconjugates and their CO release upon visible light activation. Dalton Trans., 2021, Advance Article. (#equal contribution) (10.1039/D1DT00395J) S. Lin; C. He*. Streamlined purification and characterization of Pyrococcus furiosus rubredoxins with different N-terminal modifications by reversed-phase HPLC. Anal. Biochem., 2021, 619, 114128. (10.1016/j.ab.2021.114128) C. Li; C. He*. Facile synthesis of the sulfotyrosine-containing α-Conotoxins. Org. Biomol. Chem., 2020, Accepted Manuscript. (10.1039/D0OB01526A) Y. Zhou; C. He*. Functional expression and purification of the untagged C-terminal domain of MMP-2 from Escherichia coli inclusion bodies. Protein Expr. Purif., 2020, 176, 105726. (10.1016/j.pep.2020.105726) S. Lin; C. He*. A mini-review on the enzyme-mediated manipulation of proteins/peptides. Chin. Chem. Lett., 2018, 29, 1017–1021. (10.1016/j.cclet.2018.05.006) C. He*; H. Ogata; W. Lubitz*. Elucidation of the heme active site electronic structure affecting the unprecedented nitrite dismutase activity of the ferriheme b proteins, the nitrophorins. Chem. Sci., 2016, 7, 5332–5340. C. He; S.S. Kulkarni; F. Thuaud; J.W. Bode. Chemical synthesis of the 20 kDa heme protein nitrophorin 4 by α-ketoacid hydroxylamine (KAHA) ligation. Angew. Chem. Int. Ed. 2015, 54, 12996–13001. C. He *; B.D. Howes; G. Smulevich; S. Rumpel; E.J. Reijerse; W. Lubitz*; N. Cox*; M. Knipp. Nitrite Dismutase reaction mechanism: Kinetic and spectroscopic investigation of the interaction between. C. He; K. Nishikawa; O.F. Erdem; E. Reijerse; H. Ogata; W. Lubitz; M.Knipp. Complexes of ferriheme nitrophorin 4 with low-molecular weight thiol(ate)s occurring in blood plasma. J. Inorg. Biochem. 2013, 122, 38–48. S. Abbruzzetti; C. He; H. Ogata; S. Bruno; C. Viappiani; M. Knipp.Heterogeneous kinetics of the carbon monoxide association and dissociation reaction to nitrophorin 4 and 7 coincide with structural heterogeneity of the gate-loop. J. Am. Chem. Soc. 2012, 134, 9986–9998. M. Knipp; J. J. Taing; C. He; C. Viappiani. A caged cyanide. Photochem. Photobiol. Sci. 2012, 11, 620–622. C. He H. Ogata; M. Knipp. Insertion of an H-bonding residue into the distal pocket of the ferriheme protein nitrophorin 4: Effect on nitrite–iron coordination and nitrite disproportionation. Chem. Biodivers. 2012, 9, 1761–1775. (Special Issue: Bioinorganic Chemistry-ICBIC XV) C. He; M. Fuchs; H. Ogata; M. Knipp. Guanidine–ferroheme coordination in the mutant protein Nitrophorin 4 (L130R). Angew. Chem. Int. Ed. 2012, 51, 4470–4473.