廖骞 - 大连理工大学

个人简介

教育经历 2003.92007.6 清华大学化学学士 2007.92012.7 清华大学化学博士 2003年考入清华大学化学系。2007年本科毕业后继续在清华大学化学系攻读博士学位，师从席婵娟教授，从事过渡金属催化的有机合成研究。期间，于2011年赴美国西北太平洋国家实验室交流学习1年。2012年获得博士学位，同年赴法国图卢兹第三大学/法国国家科学院，杂原子化学基础与应用实验室，从事博士后研究工作，直至2016年，合作导师：Dr. Nicolas Mézailles。2017年起任职于大连理工大学-张大煜学院。

研究领域

1) 金属有机化学 2) 配位化学 3) 过渡金属催化的小分子活化 (N2, H2, 等) 4) 过渡金属催化的有机合成 5) 均相反应的中间体分离表征及机理研究

近期论文

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G. Zhang, T. Liu, J. Song, Y. Quan, L. Jin, M. Si, Q. Liao*, N2 cleavage on d4/d4 molybdenum centers and its further conversion into iminophosphorane under mild conditions. J. Am. Chem. Soc. 2022, 144, 2444. J. Song, Q. Liao*, X. Hong, L. Jin, N. Mézailles*, Conversion of dinitrogen into nitrile: cross metathesis of N2-derived molybdenum nitride with alkynes. Angew. Chem., Int. Ed., 2021, 60, 12242. Q. Liao, T. Liu, S. I. Johnson, C. M. Klug, E. S. Wiedner, R. Morris Bullock, D. L. DuBois, Evaluation of attractive interactions in the second coordination sphere of iron complexes containing pendant amines. Dalton Trans. 2019, 48, 4867. Direct Synthesis of Silylamine from N2 and Silane: Mediated by a Tridentate Phosphine Mo Fragment,Angew. Chem., Int. Ed,2016,55:11212-11216 N2 Reduction into Silylamine at Tridentate Phosphine/Mo Center: Catalysis and Mechanistic Study,ACS Catal,2015,5:6902-6906 Catalytic dinitrogen reduction at the molybdenum center promoted by a bulky tetradentate phosphin...,Angew. Chem., Int. Ed,2014,53:14206-14210 Copper-Catalyzed Domino Reactions for the Synthesis of Cyclic Compounds,J. Org. Chem,2014,79:8507-8515 Copper-catalyzed tandem S-alkylation and S-alkenylation of sodium sulfide: synthesis of 2,3-dihyd...,Tetrahedron Lett,2013,54:1475-1477 Domino N-H/C-H Bond Activation: Copper-Catalyzed Synthesis of Nitrogen-Bridgehead Heterocycles Us...,Org. Lett,2011,13:228-231 Copper-catalyzed double N-vinylation of aromatic amines: An efficient synthesis of various substi...,Eur. J. Org. Chem,2010,2010:5426-5431 A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides,J. Org. Chem,2009,74:6371-6373 Fernandez Espada Maria.Room Temperature Functionalization of N2 to Borylamine at a Mo Complex[J],2019