个人简介
Biography
Prior to his appointment at PNNL, Dr. Thallapally was a postdoctoral research fellow at University of Missouri-Columbia working with Prof. Jerry L. Atwood. During his stay at Columbia, he developed porous organic and metal organic frameworks for Gas (Hydrogen, Methane and Acetylene) storage and separation (CO2) applications. He is major contributor for DOE - EERE collaborative project with PNNL on crystalline solids for Hydrogen storage applications and played a major role in The Alliance for Collaborative Research in Alternative Fuel Technology (ALL-CRAFT) program on materials for Methane Storage Applications. His work has been highlighted in several external press including Science Editorial Choice [Science 2005], Chemical Engineering News, several highly accessed and hot articles in Angew Chem Int. Ed., and Chemical Communications. Dr. Thallapally currently is a scientist working on the development of Hierarchical porous materials for Energy and Environmental applications including gas storage, separation heating and cooling and so on.
Education and Credentials
Ph.D Crystal Engineering, University of Hyderabad, INDIA 2002
M.S., Physical Organic Chemistry, University of Hyderabad, INDIA 1997
B.S., Chemistry, Osmania University, INDIA 1995
近期论文
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Huynh M.T., N. Gantzlen, S. Hough, D. Roundy, P.K. Thallapally, and C. Simon. 2021. "Adsorbed xenon propellant storage: are nanoporous materials worth the weight?." Materials Advances 2, no. 12:4081-4092. PNNL-SA-159628. doi:10.1039/D1MA00167A
Kim K., K. Kim, J.T. Culp, P. Ohodnicki, P.K. Thallapally, and J. Tao. 2021. "Synthesis of High-Quality Mg-MOF-74 Thin Films via Vapor-Assisted Crystallization." ACS Applied Materials & Interfaces 13, no. 29:35223-35231. PNNL-SA-159567. doi:10.1021/acsami.1c12000
Kim M., and P.K. Thallapally. 2021. "Effective CH4/N2 Separation using NU-1000 at High Pressures." Journal of Coordination Chemistry 74, no. 1-3:216-225. PNNL-SA-160589. doi:10.1080/00958972.2021.1891415
Saha D., M. Kim, A.J. Robinson, R. Babarao, and P.K. Thallapally. 2021. "Elucidating the Mechanisms of Paraffin-Olefin Separations using Nanoporous Adsorbents: An Overview." iScience 24, no. 9:Article number 103042. PNNL-SA-166062. doi:10.1016/j.isci.2021.103042
Surbella R.G., D.D. Reilly, M.A. Sinnwell, B.K. Mcnamara, L.E. Sweet, J.M. Schwantes, and P.K. Thallapally. 2021. "Multifunctional two-dimensional metal-organic frameworks for radionuclide sequestration and detection." ACS Applied Materials & Interfaces 13, no. 38:45696-45707. PNNL-SA-161938. doi:10.1021/acsami.1c11018
Thallapally P.K. 2021. Metal Organic Frameworks for Noble Gas Management in the Liquid Fluoride Thorium Reactor (LFTR) - CRADA 459. PNNL-SA-161158. Richland, WA: Pacific Northwest National Laboratory.
Zheng J., M. Wahiduzzaman, D. Barpaga, B.A. Trump, O.Y. Gutierrez-Tinoco, P.K. Thallapally, and S. Ma, et al. 2021. "Porous Covalent Organic Polymers for efficient Fluorocarbon-based Adsorption Cooling." Angewandte Chemie International Edition 60, no. 33:18037-18043. PNNL-SA-153417. doi:10.1002/anie.202102337
Chakraborty D., S. Nandi, R. Maity, R.K. Motkuri, K. Han, S. Collins, and P.H. Humble, et al. 2020. "An Ultra-microporous Metal-Organic Framework with Exceptional Xe Capacity." Chemistry - A European Journal 26, no. 55:Article No.12544. PNNL-SA-151859. doi:10.1002/chem.202002331
Han Y., M.A. Sinnwell, R.G. Surbella, W. Xue, H. Huang, J. Zheng, and B. Peng, et al. 2020. "Postsynthetic Oxidation of the Coordination Site in a Heterometallic Metal-Organic Framework: Tuning Catalytic Behaviors." Chemistry of Materials 32, no. 12:5192-5199. PNNL-SA-148450. doi:10.1021/acs.chemmater.0c01267
Lucero J., J.B. Jasinski, M. Song, D. Li, L. Liu, J. Liu, and J.J. De Yoreo, et al. 2020. "Synthesis of porous organic cage CC3 via solvent modulated evaporation." Inorganica Chimica Acta 501. PNNL-SA-155960. doi:10.1016/j.ica.2019.119312
Moore R.C., C.I. Pearce, J.W. Morad, S. Chatterjee, T.G. Levitskaia, R.M. Asmussen, and A.R. Lawter, et al. 2020. "Iodine Immobilization by Materials through Sorption and Redox-Driven Processes: A Literature Review." Science of the Total Environment 716. PNNL-SA-138461. doi:10.1016/j.scitotenv.2019.06.166
Pearce C.I., R.C. Moore, J.W. Morad, R.M. Asmussen, S. Chatterjee, A.R. Lawter, and T.G. Levitskaia, et al. 2020. "Technetium Immobilization by Materials through Sorption and Redox-Driven Processes: A Literature Review." Science of the Total Environment 716. PNNL-SA-138464. doi:10.1016/j.scitotenv.2019.06.195
Riley B.J., S. Chong, W. Kuang, T. Varga, A.S. Helal, M. Galanek, and J. Li, et al. 2020. "Metal-Organic Framework-Polyacrylonitrile Composite Beads for Xenon Capture." ACS Applied Materials & Interfaces 12, no. 40:45342-45350. PNNL-SA-154134. doi:10.1021/acsami.0c13717
Sinnwell M.A., Q. Miller, L. Liu, J. Tao, M.E. Bowden, L. Kovarik, and D. Barpaga, et al. 2020. "Kinetics and Mechanisms of ZnO to ZIF-8 Transformations in Supercritical CO2 Revealed by in situ X-ray Diffraction." ChemSusChem 13, no. 10:2602-2612. PNNL-SA-149718. doi:10.1002/cssc.202000434
Sinnwell M.A., Q. Miller, L. Palys, D. Barpaga, L. Liu, M.E. Bowden, and Y. Han, et al. 2020. "Molecular Intermediate in the Directed Formation of a Zeolitic Metal-Organic Framework." Journal of the American Chemical Society 142, no. 41:17598-17606. PNNL-SA-154537. doi:10.1021/jacs.0c07862
Tao J., M. Lee, M.L. Sushko, J.J. De Yoreo, J. Liu, Z. Zhang, and D. Banerjee, et al. 2020. "Controlling Metal-Organic Framework/ZnO heterostructure kinetics through selective ligand binding to ZnO surface steps." Chemistry of Materials 32, no. 15:6666-6675. PNNL-SA-153263. doi:10.1021/acs.chemmater.0c02123
Thallapally P.K., J. Liu, M.A. Sinnwell, and R.K. Motkuri. 2020. "Noble Gas Separation using Metal Organic Frameworks at Low Temperature." In GLOBAL 2019 - International Nuclear Fuel Cycle Conference and TOP FUEL 2019 - Light Water Reactor Fuel Performance Conference, September 22-27, 2019, Seattle, WA. La Grange Park, Illinois:American Nuclear Society. PNNL-SA-146852.
Chakraborty D., S. Nandi, M.A. Sinnwell, J. Liu, R. Kushwaha, P.K. Thallapally, and R. Vaidhyanathan. 2019. "Hyper-Cross-linked Porous Organic Frameworks with Ultramicropores for Selective Xenon Capture." ACS Applied Materials & Interfaces 11, no. 14:13279-13284. PNNL-SA-140970. doi:10.1021/acsami.9b01619
Forrest K.A., T. Pham, S.K. Elsaidi, M.H. Mohamed, P.K. Thallapally, M.J. Zaworotko, and B. Space. 2019. "Investigating CO2 Sorption in SIFSIX-3-M (M = Fe, Co, Ni, Cu, Zn) Through Computational Studies." Crystal Growth & Design 19, no. 7:3732-3743. PNNL-SA-141171. doi:10.1021/acs.cgd.9b00086
Han Y., K. Liu, M.A. Sinnwell, L. Liu, H. Huang, and P.K. Thallapally. 2019. "Direct Observation of Li+ Ions Trapped in a Mg2+-Templated Metal- Organic Framework." Inorganic Chemistry 58, no. 14:8922-8926. PNNL-SA-147562. doi:10.1021/acs.inorgchem.9b01207
Han Y., M.A. Sinnwell, S.J. Teat, M.L. Sushko, M.E. Bowden, Q. Miller, and H.T. Schaef, et al. 2019. "Desulfurization Efficiency Preserved in a Heterometallic MOF: Synthesis and Thermodynamically Controlled Phase Transition." Advanced Science 6, no. 7:1802056. PNNL-SA-136448. doi:10.1002/advs.201802056