个人简介

Professor, born 1955; B.A. LaSalle College (1977); Ph.D. Cornell University (1981); Postdoctoral Fellow, Northwestern University (1981-1983); DuPont Teaching Award, Department of Chemistry, Cornell University (1978); Cornell University College of Arts and Sciences Clark Teaching Award (1979); Rohm and Haas Summer Faculty Fellowship, 1984; National Science Foundation Presidential Young Investigator (1984-1989); Prytanean Society Faculty Enrichment Award, 1986; Exxon Fellowship for Solid State Chemistry, 1987; Sloan Foundation Fellowship (1988-1990); Camille and Henry Dreyfus Teacher-Scholar Award (1988); Distinguished Teaching Award, University of California (1991), Faculty Award for Women Scientists and Engineers, National Science Foundation (1991); Lawrence Berkeley Laboratory Technology Transfer Certification of Merit (1991); President's Chair for Teaching, University of California (1993-1996); Francis P. Garvan-John M. Olin Medal, American Chemical Society (1994), Catalyst Award, Chemical Manufacturers Association (1995); The Donald Sterling Noyce Prize for Excellence in Undergraduate Teaching (1996); Iota Sigma Pi Award for Professional Excellence (1996); James Flack Norris Award for Outstanding Achievement in the Teaching of Chemistry (1998).

研究领域

Solid State, Physical and Inorganic Chemistry — As chemists interested in solids, we synthesize materials with interesting physical properties that can be applied to emerging technologies and elucidate their behavior. Interest in the Stacy Lab is in solid-state inorganic chemistry, with particular emphasis on the synthesis and characterization of new solid state materials with novel electronic and magnetic properties. We are able to make new materials, or grow crystals of materials that have previously only been made at high temperatures, by choosing unusual reaction conditions. Our goal is to exploit changes in chemical composition or size in order to tailor structural parameters and physical properties. A main theme in the Stacy Lab is the development of new synthetic methodologies, including the use of molten salts for the synthesis of oxide superconductors, electrodeposition (in aqueous solutions and molten salts) for the synthesis of thermoelectric materials, and the use of plasma-solid reactions for the synthesis of fluorides with interesting catalytic properties. We are also using our plasma chamber for the development of chemistries for emission reduction of perfluorocarbon compounds produced by plasma processing of semiconductor devices. A current interest in our lab is exploring two-dimensional and one-dimensional quantum confined thermoelectric materials. These materials are made by electrodeposition through a porous membrane to produce wires and by pulsed laser deposition to produce multilayered thin films. In each of these cases we are learning about an unusual or new synthetic approach in order to target a material in which we are interested. It is important to us that we understand the behavior of our materials, as well as the conditions of our syntheses so we can more carefully control which products we get. For the oxides, we have been exploring the use of Raman spectroscopy to characterize the chemistry of the molten alkali metal hydroxides that we use as a solvent system. A new project in our lab has focused on the transport properties of mixed metal chalcoplyrites (such as CuInSe2). We are systematically doping with Zn to see which affects the transport properties more, the dopant or the defects. We are using diffraction and electron microscopy to characterize this system. As chemists interested in solids, an important contribution is to discover advanced materials that can be applied to emerging technologies. In addition, we have the fun of deciphering new and unusual behavior of materials.

Solid State, Physical and Inorganic Chemistry — As chemists interested in solids, we synthesize materials with interesting physical properties that can be applied to emerging technologies and elucidate their behavior. Interest in the Stacy Lab is in solid-state inorganic chemistry, with particular emphasis on the synthesis and characterization of new solid state materials with novel electronic and magnetic properties. We are able to make new materials, or grow crystals of materials that have previously only been made at high temperatures, by choosing unusual reaction conditions. Our goal is to exploit changes in chemical composition or size in order to tailor structural parameters and physical properties. A main theme in the Stacy Lab is the development of new synthetic methodologies, including the use of molten salts for the synthesis of oxide superconductors, electrodeposition (in aqueous solutions and molten salts) for the synthesis of thermoelectric materials, and the use of plasma-solid reactions for the synthesis of fluorides with interesting catalytic properties. We are also using our plasma chamber for the development of chemistries for emission reduction of perfluorocarbon compounds produced by plasma processing of semiconductor devices. A current interest in our lab is exploring two-dimensional and one-dimensional quantum confined thermoelectric materials. These materials are made by electrodeposition through a porous membrane to produce wires and by pulsed laser deposition to produce multilayered thin films. In each of these cases we are learning about an unusual or new synthetic approach in order to target a material in which we are interested. It is important to us that we understand the behavior of our materials, as well as the conditions of our syntheses so we can more carefully control which products we get. For the oxides, we have been exploring the use of Raman spectroscopy to characterize the chemistry of the molten alkali metal hydroxides that we use as a solvent system. A new project in our lab has focused on the transport properties of mixed metal chalcoplyrites (such as CuInSe2). We are systematically doping with Zn to see which affects the transport properties more, the dopant or the defects. We are using diffraction and electron microscopy to characterize this system. As chemists interested in solids, an important contribution is to discover advanced materials that can be applied to emerging technologies. In addition, we have the fun of deciphering new and unusual behavior of materials.

近期论文

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Brogan L, Stacy AM, "Sparse Nanowire Arrays for Facile Transport Measurement" MAT LETT 64 (15): 1674-1676 , 2010. Trahey L, Becker CR, Stacy AM, "Electrodeposited Bismuth Telluride nanowire Arrays with Uniform Growth Fronts" NANO LETT 7 (8): 2535-2539, 2007. Keyani J, Stacy AM, "Assembly and measurement of a hybrid nanowire-bulk thermoelectric device" APPL PHYS LETT 89(23): 233106/1-233106/3, 2006. Martín-González M, Snyder GJ, Prieto AL, Gronsky R, Sands T, Stacy AM, "Direct electrodeposition of highly dense 50 nm Bi2Te3-ySey nanowire arrays" NANO LETT 3 (7): 973-977 JUL 2003. Martín-González M, Prieto AL, Gronsky R, Sands T, Stacy AM, "High-density 40 nm diameter Sb-rich Bi2-xSbxTe3 nanowire arrays" ADV MATER 15 (12): 1003-+ JUN 17 2003. Martín-González MS, Delattre JL, Stacy AM, "Sr18Ru1.9Bi4.1O33: crystallization of a Ru(V)/Bi(V) oxide from molten hydroxide" J SOLID STATE CHEM 173 (1): 203-208 JUN 2003. Delattre JL, Stacy AM, "Synthesis and structure of BaKFeO3: a new quaternary oxide with 1-D ferrate chains" J SOLID STATE CHEM 172 (2): 261-264 MAY 2003. Martín-González M, Prieto AL, Knox MS, Gronsky R, Sands T, Stacy AM, "Electrodeposition of Bi1-xSbx films and 200-nm wire arrays from a nonaqueous solvent" CHEM MATER 15 (8): 1676-1681 APR 22 2003. Prieto AL, Martín-González M, Keyani J, Gronsky R, Sands T, Stacy AM, "The electrodeposition of high-density, ordered arrays of Bi1-xSbx nanowires" J AM CHEM SOC 125 (9): 2388-2389 MAR 5 2003. Sander MS, Gronsky R, Sands T, Stacy AM, "Structure of bismuth telluride nanowire arrays fabricated by electrodeposition into porous anodic alumina templates" CHEM MATER 15 (1): 335-339 JAN 14 2003. Martín-González MS, Prieto AL, Gronsky R, Sands T, Stacy AM, "Insights into the electrodeposition of Bi2Te3" J ELECTROCHEM SOC 149 (11): C546-C554 NOV 2002. Reisner BA, Keller SW, Stacy AM, "Crystallization of metal oxides from molten hydroxides," ABSTR PAP AM CHEM S 224: 231-INOR Part 1 AUG 18 2002. Sander MS, Prieto AL, Gronsky R, Sands T, Stacy AM, "Fabrication of high-density, high aspect ratio, large-area bismuth telluride nanowire arrays by electrodeposition into porous anodic alumina templates" ADV MATER 14 (9): 665-667 MAY 3 2002. Caylor JC, Sander MS, Stacy AM, Harper JS, Gronsky R, Sands T. "Epitaxial growth of skutterudite (CoSb3) thin films on (001) InSb by pulsed laser deposition." J MATER RES 16 (9): 2467-2470 SEP 2001. Prieto AL, Sander MS, Martín-González MS, Gronsky R, Sands T, Stacy AM. “Electrodeposition of Ordered Bi2Te3 Nanowire Arrays.” J AM CHEM SOC 123: (29) 7160-7161 JULY 2001. Delattre JL, Chupas PJ, Grey CP, and Stacy AM. “Plasma-Fluorination Synthesis of High Surface Area Aluminum Trifluoride from a Zeolite Precursor.” J AM CHEM SOC 123: (22) 5364-5365 JUNE 2001. Caylor JC, Stacy AM, Gronsky R, Sands T. “Pulsed laser deposition of skutterudite thin films.” J APPL PHYS 89 (6): 3508-3513 MAR 15 2001. Sugita H, Wada S, Fisher RA, Luce JL, Stacy AM. “Nuclear magnetic resonance investigation of complex magnetic behavior in rare-earth cuprates: RCu2O4 (R=La and Nd).” PHYSICAL REVIEW B 62: (18) 12254-12261 NOV 1 2000. Washburn NR, Stacy AM, Portis AM. "Magnetic and Transport Properties of LaMn0.8Na0.2O3." J PHYS CHEM B 104: (7) 1447-1453 FEB 24 2000. Delattre JL, Friedman TL, Stacy AM. "Destructive abatement of CF4 and C2F6 via a plasma induced reaction with CaO." J VAC SCI TECHNOL B 17: (6) 2664-2666 NOV-DEC 1999. Bornick RM, Stacy AM, Taylor RD, Kwei GH. "An investigation of the europium valence in EuCu1.75P2 by Eu Mossbauer and Eu L-III-Edge X-ray absorption spectroscopy." J SOLID STATE CHEM 144: (2) 252-254 MAY 1999. Reisner BA, Stacy AM. "Sr(3)ARhO(6) (A = Li, Na): Crystallization of a rhodium(V) oxide from molten hydroxide." J AM CHEM SOC 120: (37) 9682-9683 SEP 23 1998. Fisher RA, Wright DA, Radhakrishna P, Luce JL, Stacy AM, Phillips NE. "The specific heat of LaCu2O4 and NdCu2O4 in fields to 7 T." J MAGN MAGN MATER 177: 787-788 Part 2 JAN 1998. Badding JV, Stacy AM. "Czochralski growth of single crystals of EuNi5P3 in an arc furnace." J CRYST GROWTH 181: (4) 363-366 NOV 1997. Washburn NR, Stacy AM, Portis AM. "Low-temperature, flux-grown, Na-doped LaMnO3: Magnetic properties (vol 70, pg 1622, 1997)". APPL PHYS LETT 71: (16) 2397-2397 OCT 20 1997.