江智勇 - 河南师范大学 - 化学化工学院

个人简介

江智勇，中共党员，博士，教授，博士生导师，国家杰青，河南师范大学副校长，化学化工学院院长。2019年获国家杰出青年科学基金;先后入选教育部新世纪优秀人才支持计划、百千万人才工程国家级人选、国家有突出贡献中青年专家、享受国务院特殊津贴专家、省特聘教授、省优秀专家、省杰出专业技术人才；兼任《有机化学》等SCI期刊编委，中国化学会高级会员，中国化学会光化学专业委员会委员、中国感光学会光化学与光生物专委会委员、省化学学会常务理事。教育经历 1999.09-2004.01 浙江大学化学系，有机化学专业，理学博士 1992.09-1996.06 浙江大学化学系，化学专业，理学学士工作经历 2021.09—至今，河南师范大学，学术副校长 2018.08—至今，河南师范大学化学化工学院教授，博士生导师，院长 2009.08—2018.08，河南大学河南省天然药物与免疫工程重点实验室教授，博士生导师，副主任 2013.04—2013.10，新加坡南洋理工大学化学与生物化学学院，高级研究员 2005.08—2009.08，新加坡国立大学化学系，博士后，合作导师：Choon-Hong Tan教授 2004.02—2005.04，香港浸会大学化学系，博士后，合作导师：Wing-Hong Chan教授

研究领域

1. 光氧化还原不对称催化 2. 手性C2 对称双六员环胍催化剂的设计和合成 3. 不对称相转移催化

近期论文

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Fu, Q., Cao S., Wang J.*, Lv, X.*, Wang, H., Zhao, X., Jiang, Z.*, Enantioselective [2π + 2σ] Cycloadditions of Bicyclo[1.1.0]butanes with Vinylazaarenes through Asymmetric Photoredox Catalysis. J. Am. Chem. Soc. 2024, DOI:org/10.1021/jacs.3c14077 Zhang, L., Ma, J., Ban, X., Zhao, X., Yin, Y., Jiang, Z.*, Direct Enantioselective Reduction of C=C Bond of β-Polyfluoro-alkylated Enones via Asymmetric Photoredox Catalysis. Sci China Chem. 2024, 67 DOI:org/10.1007/s11426-023-1896-5 Kong, M., Wang, Z., Ban, X., Zhao, X.,Yin, Y., Zhang, J., Jiang, Z.*, Radical Cross Coupling and Enantioselective Protonation through Asymmetric Photoredox Catalysis. Adv. Sci. 2024, DOI:10.1002/advs.202307773. Ma, C., Shen, J., Qu, C., Shao, T.*, Cao, S.*, Yin, Y., Zhao, X., Jiang, Z.*, Enantioselective Chemodivergent Three-Component Radical Tandem Reactions through Asymmetric Photoredox Catalysis. J. Am. Chem. Soc. 2023. DOI：10.1021/jacs.3c08883. https://doi.org/10.1021/jacs.3c08883 Liu, Y., Zhang, L., Zhang, Y., Cao, S., Ban, X., Yin, Y., Zhao, X., Jiang, Z.*, Asymmetric Olefin Isomerization via Photoredox Catalytic Hydrogen Atom Transfer and Enantioselective Protonation. J. Am. Chem. Soc. 2023, 145 (33), 18307-18315. https://doi.org/10.1021/jacs.3c03732 Wang, B., Liu, Y., Jiang, C., Cao, Z., Cao, S., Zhao, X., Ban, X.*, Yin, Y.*, Jiang, Z.* Catalytic Asymmetric Hydrophosphinylation of 2-Vinylazaarenes to Access P-Chiral 2-Azaaryl-Ethylphosphine Oxides. Angew. Chem. Int. Ed. 2023, e202216605. https://doi.org/10.1002/anie.202216605 Wang, G., Li, L., Jiang, Y., Zhao, X., Ban, X. , Shao, T., Yin, Y. , Jiang, Z.* Kinetic Resolution of Azaarylethynyl Tertiary Alcohols by Chiral Bronsted Acid Catalysed Phosphine-Mediated Deoxygenation. Angew. Chem. Int. Ed. 2023, 62, e202214838. https://doi.org/10.1002/anie.202214838 Yao, S., Zhao, X., Ban, X., Shao, T., Yin, Y., Hu, W.*, Jiang, Z.* Visible light-driven direct access to imine-containing azaarene-substituted highly functionalized pyrroles. Org. Chem. Front. 2023. DOI: 10.1039/d3qo01056b. https://doi.org/10.1039/d3qo01056b. Luo, C., Yin, Y., Jiang, Z.* Recent Advances in Asymmetric Synthesis of P-Chiral Phosphine Oxides. Chinese J. Org. Chem. 2023, 43 (6), 1963-1976. https://doi.org/10.6023/cjoc202212024 Yin. Y., Jiang, Z.* Copper(I)-Catalyzed Asymmetric Conjugate Addition of 1,4-Dienes to β-Substituted Alkenyl Azaarenes. Chinese J. Org. Chem. 2023, 43 (3), 1203-1205. https://doi.org/10.6023/cjoc202300014 Song, X., Zhang, Y., Li, Y., Zhao, X., Yin, Y., Ban, X., Jiang, Z.* Catalytic Asymmetric Synthesis of Azaarene-Functionalized Tertiary Amines and α-Amino Acid Derivatives from E/Z-Ketimine Mixtures via Enantioselective Radical Coupling. ACS Catal. 2023, 13 (9), 6396-6402. https://doi.org/10.1021/acscatal.3c00756 Lv, X., Qi, Y.-N., Wang, J., Zhao, X., Jiang, Z.* Photoinduced Vinylogous Dearomatization. Org. Lett. 2023, 25 (17), 3114-3119. https://doi.org/10.1021/acs.orglett.3c00966 Wang, J., Lv, X., Jiang, Z.* Visible-Light-Mediated Photocatalytic Deracemization. Chem. Eur. J. 2023, 29 (29), e202204029. https://doi.org/10.1002/chem.202204029 Lv, X.*, Gao, P., Zhao, X., Jiang, Z.* Metal-Free Construction of Multisubstituted Indolizines via Intramolecular Amination of Allylic Alcohols. J. Org. Chem. 2023, 88 (13), 9459-9468. https://doi.org/10.1021/acs.joc.3c00469 Guo, Y.-Y. *, Tian, Z.-H., Han, Y.-C., Ma, D., Shao, T., Jiang, Z.*, Hantzsch Ester as Efficient and Economical NAD(P)H Mimic for In Vitro Bioredox Reactions. Chem. Eur. J. 2023, 29 (45), e202301180. https://doi.org/10.1002/chem.202301180 Shao, T.*, Ban, X., Jiang, Z.* α-Amino Acids: An Emerging Versatile Synthon in Visible Light-Driven Decarboxylative Transformations. Chem. Rec. 2023, e202300122. https://doi.org/10.1002/tcr.202300122 Dai, Y., Huang, H., Liang, S., Yin, Y., Ban, X., Zhao, X., Jiang, Z.* Catalytic Asymmetric Intermolecular [3 + 2] Photocycloaddition of Cyclopropylamines with Electron-Deficient Olefins. Org. Lett. 2023, 25 (24), 4551-4555. https://doi.org/10.1021/acs.orglett.3c01585 Gu, Z., Zhang, L., Li, H., Cao, S.*, Yin, Y., Zhao, X., Ban, X., Jiang, Z.* Deracemization through Sequential Photoredox-Neutral and Chiral Bronsted Acid Catalysis. Angew. Chem. Int. Ed. 2022, 61, e202211241. https://doi.org/10.1002/anie.202211241 Chai, X., Hu, X., Zhao, X., Yin, Y.*, Cao, S.*, Jiang, Z.* Asymmetric Hydroaminoalkylation of Alkenylazaarenes via Cooperative Photoredox and Chiral Hydrogen-Bonding Catalysis. Angew. Chem. Int. Ed. 2022, 61, e202115110. https://doi.org/10.1002/anie.202115110 Li, Y., Han, C., Wang, Y., Huang, X., Zhao, X., Qiao, B.*, Jiang, Z.* Catalytic Asymmetric Reductive Azaarylation of Olefins via Enantioselective Radical Coupling. J. Am. Chem. Soc. 2022, 144(17), 7805−7814. https://doi.org/10.1021/jacs.2c01458 Li, S., Tian, D., Zhao, X., Yin, Y., Lee, R., Jiang, Z.* Visible light-driven copper(II) catalyzed aerobic oxidative cleavage of carbon-carbon bonds: a combined experimental and theoretical study. Org. Chem. Front. 2022, 9, 6299. https://doi.org/10.1039/D2QO01264B Tan, Y., Yin, Y.*, Cao, S., Zhao, X., Qu, G., Jiang, Z.* Conjugate addition-enantioselective protonation to forge tertiary stereocentres alpha to azaarenes via cooperative hydrogen atom transfer and chiral hydrogen-bonding catalysis. Chin. J. Catal. 2022, 43, 558−563. https://doi.org/10.1016/S1872-2067(21)63887-1 Dai, Y., Liang, S., Zeng, G., Huang, H., Zhao, X., Cao, S., Jiang, Z.* Asymmetric [3+2] photocycloadditions of cyclopropylamines with electron-rich and electron-neutral olefins. Chem. Sci. 2022, 13, 3787-3795. https://doi.org/10.1039/D1SC07044D Cao, K., Li, C., Tian, D., Zhao, X.., Yin, Y.*, Jiang, Z.* Catalytic Enantioselective Reductive Cross Coupling of Electron-Deficient Olefins. Org. Lett. 2022, 24, 4788−4792. https://doi.org/10.1021/acs.orglett.2c01801 Sun, X ., Qu, C., Ma, C., Zhao, X., Chai, G.*, Jiang, Z.* Photoredox Catalytic Cascade Radical Addition to Construct 1,4-Diketone-Functionalized Quinoxalin-2(1H)-one Derivatives. Chin. J. Org. Chem. 2022, 42, 1396−1406. https://doi.org/10.6023/cjoc202201025 Tian, D., Sun, X., Cao, S., Wang, E., Yin, Y., Zhao, X., Jiang, Z.* Enantioselective intermolecular [2+2] photocycloadditions of vinylazaarenes with triplet-state electron-deficient olefins. Chin. J. Catal. 2022, 43, 2732−2742. https://doi.org/10.1016/S1872-2067(22)64156-1 Yin, Y., Zhao, X.*, Jiang, Z.*.Asymmetric Photocatalytic Synthesis of Enantioenriched Azaarene Derivatives. Chin. J. Org. Chem. 2022, 42, 1609−1625. https://doi.org/10.6023/cjoc202201047 Ban, X. , Jiang, Z.* Synergistic Photoredox Catalyzed Asymmetric Allylic Alkylation via C-H Dehydrogenation. Chin. J. Org. Chem. 2022, 42, 2248−2249. https://doi.org/10.6023/cjoc202200031 Kong, M., Tan, Y., Zhao, X., Qiao, B., Tan, C., Cao, S., Jiang, Z.* Catalytic Reductive Cross Coupling and Enantioselective Protonation of Olefins to Construct Remote Stereocenters for Azaarenes. J. Am. Chem. Soc. 2021,143, 4024−4031. https://doi.org/10.1021/jacs.1c01073 Chen, X., Wei, W., Li, C., Zhou, H., Qiao, B*., Jiang, Z.* Photoredox-Catalyzed Synthesis of Remote Fluoroalkylated Azaarene Derivatives and the alpha-Deuterated Analogues via 1,n-Hydrogen-Atom-Transfer-Involving Radical Reactions. Org. Lett. 2021, 23, 8744−8749. https://doi.org/10.1021/acs.orglett.1c03204 Xu, H., Liu, J., Nie, F., Zhao, X.,Jiang, Z.* Metal-Free Hydropyridylation of Thioester-Activated Alkenes via Electroreductive Radical Coupling. J. Org. Chem. 2021, 86, 16204−16212. https://doi.org/10.1021/acs.joc.1c01526 Yin, Y., Fan, Y., Zhao, X., Chai, G.,Jiang, Z.* Organocatalytic Enantioselective and Diastereodivergent Mannich Reactions of 5-Substituted Oxazolidin-2,4-Diones. Asian J. Org.Chem. 2021,10, 2538−2543. https://doi.org/10.1002/ajoc.202100480 Yang, H., Li, H., Wei, G.*, Jiang, Z.* Photoredox Catalytic Phosphite-Mediated Deoxygenation of alpha-Diketones Enables Wolff Rearrangement and Staudinger Synthesis of beta-Lactams. Angew. Chem. Int. Ed. 2021, 60, 19696−19700. https://doi.org/10.1002/anie.202107080 Guo, Z., Chen, X., Fang, H ., Zhao, X.*, Jiang, Z.* Divergent asymmetric synthesis of azaarene-functionalized cyclic alcohols through stereocontrolled Beckwith-Enholm cyclizations. Sci. China Chem. 2021, 6543−6550. https://doi.org/10.1007/s11426-021-1019-2 Hu, W., Zhan, Q., Zhou, H., Cao, S.* , Jiang, Z.* Radical-based functionalization-oriented construction: rapid assembly of azaarene-substituted highly functionalized pyrroles. Chem. Sci. 2021, 12, 6543-6550. https://doi.org/10.1039/D1SC01470F Jia, H., Qiao, B.*, Jiang, Z.* Photoredox Catalytic Radical Coupling to Access beta-Fluoro alpha-Amino Acid Derivatives. Acta Chim. Sinica, 2021, 79, 1477−1480. https://doi.org/10.6023/A21090432 Ban, X., Fan, Y., Kha, T., Lee, R., Kee, C. Jiang, Z.*, Tan, C.* Pentanidium-Catalyzed Direct Assembly of Vicinal All-Carbon Quaternary Stereocenters through C(sp3)-C(sp3) Bond Formation. CCS Chem. 2021, 3, 2192−2200. https://doi.org/10.31635/ccschem.021.202101013 Yin, Y., Li, Y., Goncalves, T. , Zhan, Q., Wang, G., Zhao, X., Qiao, B. , Huang, K*., Jiang, Z.* All-Carbon Quaternary Stereocenters α to Azaarenes via Radical-Based Asymmetric Olefin Difunctionalization. J. Am. Chem. Soc. 2020, 142, 19451−19456. https://doi.org/10.1021/jacs.0c08329 Lv, X., Xu, H., Yin, Y., Zhao, X., Jiang, Z.* Visible Light-Driven Cooperative DPZ and Chiral Hydrogen-Bonding Catalysis. Chin. J. Chem. 2020, 38, 1480−1488. https://doi.org/10.1002/cjoc.202000306 Xu, H., Jiang, Z.* Photoredox-Catalysed New Radical Borylation Pathways for Organoboron Synthesis. Chin. J. Org. Chem. 2020, 40, 3483−3484. https://doi.org/10.6023/cjoc202000069 Yin, Y., Zhao, X.*, Jiang, Z.* Advances in the Synthesis of Imine-Containing Azaarene Derivatives via Photoredox Catalysis. ChemCatChem 2020, 12, 4471−4489. https://doi.org/10.1002/cctc.202000741 Yin, Y., Zhao, X., Qiao, B.*, Jiang, Z.* Cooperative photoredox and chiral hydrogen-bonding catalysis. Org. Chem. Front. 2020, 7, 1283-1296. https://doi.org/10.1039/D0QO00276C Li, F., Tian, D., Fan, Y., Lee, R., Lu, G., Yin, Y., Qiao, B., Zhao, X., Xiao, Z., Jiang, Z.* Chiral Acid-Catalysed Enantioselective C−H Functionalization of Toluene and Its Derivatives Driven by Visible Light. Nat. Commun. 2019, 10, 1774. https://doi.org/10.1038/s41467-019-09857-9 Cao, K., Tan, S. M., Lee, R., Yang, S., Jia, H., Zhao, X., Qiao, B., Jiang, Z.* Catalytic Enantioselective Addition of Prochiral Radicals to Vinylpyridines. J. Am. Chem. Soc. 2019, 141, 5437−5443. https://doi.org/10.1021/jacs.9b00286 Shao, T., Li, Y., Ma, N., Li, C., Chai, G., Zhao, X., Qiao, B.*, Jiang, Z.* Photoredox-Catalyzed Enantioselective α-Deuteration of Azaarenes with D2O. iScience 2019, 16, 410−419. https://doi.org/10.1016/j.isci.2019.06.007 Hou, M., Lin, L., Chai, X., Zhao, X., Qiao, B.*, Jiang, Z.* Enantioselective Photoredox Dehalogenative Protonation. Chem. Sci. 2019,10, 6629−6634. https://doi.org/10.1039/C9SC02000D Zhu, B., Lu, B., Zhang, H., Xu, X., Jiang, Z.*, Chang, J.* Phase-Transfer-Catalyzed, Enantioselective Vinylogous Conjugate Addition−Cyclization of Olefinic Azlactones To Access Multifunctionalized Chiral Cyclohexenones. Org. Lett. 2019, 21, 3271−3275. https://doi.org/10.1021/acs.orglett.9b01001 Qiao, B., Li, C., Zhao, X., Yin, Y., Jiang, Z.* Enantioselective Reductive of Azaarene-Based Ketones via Visible Light-Driven Photoredox Asymmetric Catalysis. Chem. Commun. 2019, 55, 7534−7537. https://doi.org/10.1039/C9CC03661J Zeng, G., Li, Y., Qiao, B., Zhao, X.*, Jiang, Z.* Photoredox Asymmetric Catalytic Enantioconvergent Substitution of 3-Chlorooxindoles. Chem. Commun. 2019, 55, 11362-11365. https://doi.org/10.1039/C9CC05304B Liu, X., Yin, Y.*, Jiang, Z.* Photoredox-Catalysed Formal [3+2] Cycloaddition of N-Aryl α-Amino Acids with Isoquinoline N-Oxides. Chem. Commun. 2019,55, 11527-11530. https://doi.org/10.1039/C9CC06249A