个人简介

B.S., North Central College (2006) Ph.D., University of Illinois at Urbana-Champaign (2010) Seaborg Postdoctoral Fellow, Los Alamos National Lab (2010-2012)

研究领域

Inorganic Chemistry

Research in the Daly Group is focused on understanding how to manipulate chemical bonding and structure in metal complexes to address long-standing challenges in energy science, medicine and catalysis. Our work relies heavily on the synthesis and design of new inorganic and organometallic compounds, and synthetic efforts are often complimented with state of the art synchrotron spectroscopy and radiochemistry to achieve desired objectives. Current projects include in-situ ligand K-edge XAS investigations of small molecule binding and activation, exploratory coordination chemistry and ligand design, and synthesis of molecular nanocapsules for radiopharmaceutical applications. Please see our website for additional details.

近期论文

查看导师最新文章 （温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Olson, A. C.; Keith, J. M.; Batista, E. R.; Boland, K. S.; Daly, S. R.; Kozimor, S. A.; MacInnes, M. M.; Martin, R. L.; Scott, B. L. "Using solution- and solid-state S K-edge X-ray absorption spectroscopy with density functional theory to evaluate M–S bonding for MS42− (M = Cr, Mo, W) dianions." Dalton Trans. 2014, 43, 17283-17295 (link). Donahue, C. M.; Lezama Pacheco, J. S.; Keith, J. M.; Daly, S. R. "Sulfur K-edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory of Arsenic Dithiocarbamates." Dalton Trans. 2014, 43, 9189-9201 (link). Wen, X. D.; Löble, M. W.; Batista, E. R.; Bauer, E.; Boland, K. S.; Burrell, A. K.; Conradson, S. D.; Daly, S. R.; Kozimor, S. A.; Minasian, S. G.; Martin, R. L; McCleskey, T. M; Scott, B. L; Shuh, D. K; Tyliszczak, T. "Electronic structure and O K-edge XAS spectroscopy of U3O8." J. Electron Spectrosc. 2014, (special issue in honor of Richard Martin) 194, 81-87 (link). Donahue, C. M.; Black, C. M.; Pecnik, S. L; Savage, T. R.; Scott, B. L; Daly, S. R. "Synthesis, Characterization and Structural Comparisons of Phosphonium and Arsenic Dithiocarbamates with Alkyl and Phenyl Substituents." Polyhedron 2014, 135, 110-117 (link). Minasian, S. G.; Keith, J. K.; Batista, E. R.; Boland, K. S.; Bradley, J. A.; Daly, S. R.; Kozimor, S. A.; Lukens, W. W.; Martin, R. L.; Nordlund, D.; Seidler, G. T.; Shuh, D. K.; Sokara, D.; Tyliszczak, T.; Wagner, G. L.; Weng, T.; Yang, P. "Covalency in Metal-Oxygen Bonds Evaluated using Oxygen K-edge Spectroscopy and Electronic Structure Theory." J. Am. Chem. Soc. 2013, 135, 1864-1871 (link). Shaista, B.; Kumar, N.; Zhang, P.; Daly, S. R.; Dunbar, A. C.; Girolami, G. S.; Abelson, J. R. "Growth Inhibitors to Enhance Nucleation Density in Thin Film Chemical Vapor Deposition." Chem. Mat. 2013, 25, 662-667 (link). Vlaisavljevich, B.; Miro, P.; Koballa, D.; Todorova, T. K.; Daly, S. R.; Girolami, G. S.; Cramer, C. J.; Gagliardi, L. "Volatilities of Actinide and Lanthanide N,N-Dimethylaminodiboranate Chemical Vapor Deposition Precursors: A DFT Study." J. Phys. Chem. C 2012, 116, 23194-23200 (link). Daly, S. R.; Keith, J. M.; Batista, E. R.; Boland, K. S.; Clark, D. L; Kozimor, S. A.; Martin, R. L. "S K-edge XAS and TDDFT of Dithiophosphinate Extractants: Minor Actinide Selectivity and Electronic Structure Correlations." J. Am. Chem. Soc. 2012, 134, 14408-14422 (link). Schmucker, S. W.; Kumar, N.; Abelson, J. R.; Daly, S. R.; Girolami, G. S.; Bischof, M. R.; Jaeger, D. L.; Reidy, R. F.; Gorman, B. P.; Alexander, J.; Ballard, J. B.; Randall, J. N.; Lyding, J. W. "Field-directed sputter sharpening for tailored probe materials and atomic-scale lithography." Nature Commun. 2012, 3, 1907/1-1907/8 (link). Daly, S. R.; Keith, J. M.; Batista, E. R.; Boland, K. S.; Kozimor, S. A.; Martin, R. L.; Scott, B. L. "Probing Ni[S2PR2]2 Electronic Structure to Generate Insight Relevant to Minor Actinide Extraction Chemistry." Inorg. Chem. 2012, 51, 7551-7560 (link). Daly, S. R.; Kim, D. Y.; Girolami, G. S. "Lanthanide N,N-Dimethylaminodiboranates as a New Class of Highly Volatile Chemical Vapor Deposition Precursors." Inorg. Chem. 2012, 51, 7050-7065 (link). Daly, S. R.; Bellott, B. J.; Nesbit, M. A.; Girolami, G. S. "Synthesis and Structural Diversity of Barium N,N-Dimethylaminodiboranates." Inorg. Chem. 2012, 51, 6449-6459 (link). Daly, S. R.; Boland, K. S.; Klaehn, J. R.; Kozimor, S. A.; Peterman, D. R.; Scott, B. L. "NMR Spectroscopy and Structural Characterization of Dithiophosphinates Relevant to Minor Actinide Extraction Processes." Dalton Trans. 2012, 41, 2163-2175 (link). Daly, S. R.; Ephritikhine, M.; Girolami, G. S. "Crystal Structure and Spectroscopic Study of the Uranium Oxo Complex U2(μ-O)(BH4)6(dme)2 (dme = 1,2-dimethoxyethane) and Reformulation of U2(μ-H)2(BH4)6(dme)2." Polyhedron 2012, 33, 41-44 (link). Kraft, S. J.; Williams, U. J.; Daly, S. R.; Schelter, E.; Kozimor, S. A.; Boland, K. S.; Kikkawa, J. M.; Forrest, W. P.; Christensen, C. N.; Schwarz, D. E.; Fanwick, P. E.; Clark, D. L.; Conradson, S. D.; Bart, S. C. "The Synthesis, Characterization, and Multi-Electron Reduction Chemistry of Uranium Supported by Redox-Active α-Diimine Ligands." Inorg. Chem. 2011, 50, 9838-9848 (link). Piccoli, P. M. B.; Schultz, A. J.; Todorova, T. K.; Gagliardi, L.; Daly, S. R.; Girolami, G. S. "Big Metals, Small Ligands: Characterization of the 15-Coordinate Complex Thorium Aminodiboranate [Th(H3BN(CH3)2BH3)4] by Single Crystal Neutron Diffraction," Am. Cryst. Assn. Symp. Trans. 2010, TR.01.3 (link). Daly, S. R.; Bellott, B. J.; Kim, D. Y.; Girolami, G. S. "Synthesis of the Long-Sought Unsubstituted Aminodiboranate Na(H3BNH2BH3) and its N-Alkyl and N,N-Dialkyl Analogs." J. Am. Chem. Soc. 2010, 132, 7254-7255 (link). Daly, S. R.; Girolami, G. S. "Synthesis, Characterization, and Structures of Divalent Europium and Ytterbium N,N-Dimethylaminodiboranates." Inorg. Chem. 2010, 49, 4578-4585 (link). Daly, S. R.; Girolami, G. S. "Synthesis, Characterization, and Structures of Uranium(III) N,N-Dimethylaminodiboranate Complexes." Inorg. Chem. 2010, 49, 5157-5166 (link). Daly, S. R.; Kim, D. Y.; Yang, Y.; Abelson, J. R.; Girolami, G. S. "Lanthanide N,N-Dimethylaminodiboronates: Highly Volatile Precursors for the Deposition of Lanthanide-Containing Thin Films." J. Am. Chem. Soc. 2010, 132, 2106-2107 (link).