个人简介
University of California, Riverside - B.A. (2002-2005)
University of California, Riverside - Ph.D. (2005-2008)
Caltech - Postdoc. (2008-2011)
研究领域
Organic Chemistry/Inorganic Chemistry
Our research interests are strongly rooted in creative chemical synthesis. This is an intentionally broad description. Since we draw no boundaries between inorganic and organic chemistry, we work with elements from all over the periodic table. The overall goal of our program is to develop novel and creative chemical solutions to the most urgent and challenging unsolved problems in synthetic chemistry. One of the most prominent themes in our group is catalyst design, which can allow for the development of novel chemical transformations that are useful for industries ranging from energy to pharma, and thus the general public.
近期论文
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Synthesis of a Hybrid m-Terphenyl/o-Carborane Building Block: Applications in Phosphine Ligand Design. C. Lugo, C. Moore, A. Rheingold, V. Lavallo, Inorg. Chem., 2015, 54, 2094–2096.
Synthesis of Unsymmetrical N-Carboranyl NHCs: Directing Effect of the Carborane Anion. M. J. Asay, S. P. Fisher, S. E. Lee, D. Borchardt, F. S. Tham, V. Lavallo, Chem. Commun., 2015, 51, 5359-5362.
Synthesis and Characterization of Anionic Polybrominated Carboranyl Azides. J. Fajardo, Jr., A. L. Chan, F.S. Tham, V. Lavallo, Inorg. Chim. Acta, 2014, 422, 206-208.
Fusing N-Heterocyclic Carbenes with Carborane Anions. A. El-Hellani, V. Lavallo, Angew. Chem. Int. Ed., 2014, 53, 4489-4493.
Comparative Reactivity of Different Types of Stable Cyclic and Acyclic Mono- and Di-Amino Carbenes with Simple Organic Substrates. D. Martin, Y. Canac, V. Lavallo, G. Bertrand J. Am. Chem. Soc., 2014, 136, 5023-5030.
Structure and Bonding of a Zwitterionic Ir Complex Supported by a Phosphine with the Parent Carba-closo-Dodecaborate CB11H11- Ligand Substituent. A. El-Hellani, C. E. Kefalidis, F. S. Tham, L. Maron, V. Lavallo, Organometallics, 2013, 32, 6887-6890.
Observation of Room Temperature B-Cl Activation of the HCB11Cl11- Anion and Isolation of a Stable Anionic Carboranyl Phosphazide. A. L. Chan, J. Fajardo, Jr., J. Wright II, M. Asay, V. Lavallo, Inorg. Chem., 2013, 52, 12308-12310.
Isolation of a Carborane-Fused Triazole Radical Anion. M. Asay, C. E. Kefalidis, J. Estrada, D. S. Weinberger, J. Wright, C. E. Moore, A. L. Rheingold, L. Maron, V. Lavallo, Angew. Chem. Int. Ed., 2013, 52, 11560-11563.
Click-Like Reactions with the Inert HCB11Cl11– Anion Lead to Carborane-Fused Heterocycles with Unusual Aromatic Character. J. H. Wright II, C. E. Kefalidis, F. S. Tham, L. Maron, V. Lavallo, Inorg. Chem., 2013, 52, 6223-6229.
Perhalogenated Carba-closo-dodecaborate Anions as Ligand Substituents: Applications in Gold Catalysis. V. Lavallo, J. H. Wright II, F. S. Tham, and S. Quinlivan, Angew. Chem. Int. Ed., 2013, 52, 3172-3176.
Olefin Metathesis Catalysts Bearing Cyclic Alkyl Amino Carbenes. D.S. Weinberger and V.Lavallo, book chapter in Handbook of Metathesis, 2nd edition. Wiley-VCH. In press.