Long, Jeffrey R. - University of California, Berkeley - Chemical & Biomolecular Engineering

个人简介

Prof. Jeffrey R. Long obtained his doctorate in Chemistry from Harvard University in 1995 and conducted postdoctoral research at Harvard and UC Berkeley before joining the UC Berkeley faculty in 1997. He was appointed to Associate Professor in 2003 and to Full Professor of Chemistry in 2008. In 2015, Prof. Long received a joint appointment as Professor of Chemistry & Biomolecular Engineering, and in 2022 he was named the C. Judson King Distinguished Professor. Prof. Long’s research program focuses on the design and controlled synthesis of novel inorganic materials and molecules toward the fundamental understanding of new physical phenomena, with applications in gas storage, molecular separations, conductivity, catalysis, and magnetism. He has published more than 375 papers with over 85,000 citations as well as 21 patents. His contributions to inorganic and materials chemistry have been recognized with numerous awards and honors, including the Royal Society of Chemistry Ludwig Mond Award and the American Chemical Society F. Albert Cotton Award in Synthetic Inorganic Chemistry, and he is an elected member of the American Academy of Arts and Sciences. Prof. Long served as Co-Founder and Director of Mosaic Materials from 2014 to 2022, a carbon capture technology company acquired by Baker Hughes in 2022. He is also a Co-Founder of ChemFinity Technologies, a startup founded in 2022 with prior Ph.D. students to commercialize membrane technology developed in his laboratory for water purification applications.

研究领域

Research in the Long Group is focused on controlling chemical structure and function through molecular design. Within this paradigm, we employ the principles of coordination chemistry in the tailored synthesis of atomically precise molecules and materials with programmed properties, with the goal of achieving fundamental advances relevant to our technological, environmental, and energy future. We are developing new porous materials for diverse applications ranging from gas storage to water purification. We are also creating new high-performance magnetic molecules and conductive extended solids. Researchers in the group are rigorously trained in air-stable and inert-atmosphere molecular and materials chemistry and learn a range of physical methods to rigorously analyze and characterize new compounds, including gas adsorption analysis, X-ray and neutron diffraction, in situ spectroscopies, and SQUID magnetometry. Active research areas and representative publications are highlighted in individual research tabs. Research directions are continually evolving, and interested Ph.D. students and postdoctoral scholars are encouraged to read our recent papers and contact Prof. Long or group members affiliated with various research direction for additional information. Functional Metal–Organic Frameworks Quantum Magnetism in Molecular Materials Porous Polymers and Composite Membranes

近期论文

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"Long Duration Energy Storage Using Hydrogen in Metal–Organic Frameworks: Opportunities and Challenges" Peng, P.; Jiang, H. Z. H.; Collins, S.; Furukawa, H.; Long, J. R.; Breunig, H. ACS Energy Lett. 2024, 9, 2727−2735. "High-Capacity, Cooperative CO2 Capture in a Diamine-Appended Metal–Organic Framework through a Combined Chemisorptive and Physisorptive Mechanism" Zhu, Z. T.; Tsai, H.; Parker, S. T.; Lee, J.-H.; Yabuuchi, Y.; Jiang, H. Z. H.; Wang, Y.; Xiong, S.; Forse, A. C.; Dinakar, B.; Huang, A.; Dun, C.; Milner, P. J.; Smith, A.; Guimarães Martins, P.; Meihaus, K. R.; Urban, J. J.; Reimer, J. A.; Neaton, J. B.; Long, J. R. J. Am. Chem. Soc. 2024, 146, 6072−6083. "Quantum Chemical Modeling of Hydrogen Binding in Metal–Organic Frameworks: Validation, Insight, Predictions and Challenges" Chakraborty, R.; Talbot, J. J.; Shen, H.; Yabuuchi, Y.; Carsch, K. M.; Jiang, H. Z. H.; Furukawa, H.; Long, J. R.; Head-Gordon, M. Phys. Chem. Chem. Phys. 2024, 26, 6490-6511. "Selective Adsorption of Oxygen from Humid Air in a Metal–Organic Framework with Trigonal Pyramidal Copper(I) Sites" Carsch, K. M.; Huang, A. J.; Dods, M. N.; Parker, S. T.; Rohde, R. C.; Jiang, H. Z. H.; Yabuuchi, Y.; Karstens, S. L.; Kwon, H.; Chakraborty, R.; Taw, E.; Meihaus, K. R.; Furukawa, H.; Neaton, J. B.; Minor, A. M.; Head-Gordon, M.; Long, J. R. J. Am. Chem. Soc. 2024, 146, 3160-3170. "Development of a Chemistry-Based Isotherm Model and Techno-Economic Optimization of a Moving Bed Process for CO2 Capture Using a Functionalized Metal-Organic Framework" Hughes, R.; Kotamreddy, G.; Bhattacharyya, D.; Parker, S.; Dods, M.; Long, J. R.; Omell, B.; Matuszewski, M. Chem. Eng. Sci. 2024, 287, 119679. "Understanding 2p Core-Level Excitons of Late Transition Metals by Analysis of Mixed-Valence Copper in a Metal–Organic Framework" Wang, H.; Su, G. M.; Barnett, B. R.; Drisdell, W. S.; Long, J. R.; Prendergast, D. Phys. Chem. Chem. Phys. 2024, 26, 11980-11987. "Cooperative Carbon Dioxide Capture in Diamine-Appended Magnesium–Olsalazine Frameworks" Zhu, Z. T.; Parker, S. T.; Forse, A. C.; Lee, J.-H.; Siegelman, R. L.; Milner, P. J.; Tsai, H.; Ye, M.; Paley, M.; Uliana, A. A.; Oktawiec, J.; Dinakar, B.; Didas, S. A.; Meihaus, K. R.; Reimer, J. A.; Neaton, J. B.; Long, J. R. J. Am. Chem. Soc. 2023, 145, 17151-17163. "Synthesis and Crystallographic Characterization of a Reduced Bimetallic Yttrium Ansa-Metallocene Hydride Complex, [K(crypt)][(–CpAn)Y(–H)]2 (CpAn = Me2Si[C5H3(SiMe3)-3]2), with a 3.4 Å Yttrium-Yttrium Distance" Wedal, J. C.; Anderson-Sanchez, L. M.; Dumas, M. T.; Gould, C. A.; Beltrán-Leiva, M. J.; Celis-Barros, C.; Páez-Hernández, D.; Ziller, J. W.; Long, J. R.; Evans, W. E. J. Am. Chem. Soc. 2023, 145, 10730-10742. "Assessment of Adsorbate π-backbonding in Copper(I) Metal–Organic Frameworks via Multinuclear NMR Spectroscopy and Density Functional Theory Calculations" Funke, L. M.; Chakraborty, R.; Carsch, K. M.; Head-Gordon, M.; Long, J. R.; Reimer, J. A. J. Phys. Chem. C 2023, 127, 7513-7519. "Permanent Porosity in the Room-Temperature Magnet and Magnonic Material V(TCNE) 2" Park, J. G.; Jaramillo, D. E.; Shi, Y.; Jiang, H. Z. H.; Yusuf, H.; Furukawa, H.; Bloch, E. D.; Cormode, D. S.; Miller, J. S.; Harris, T. D.; Johnston-Halperin, E.; Flatté, M. E.; Long, J. R. ACS Cent. Sci. 2023, 9, 777-786. "A Trinuclear Gadolinium Cluster with a Three-Center One-Electron Bond and an S = 11 Ground State" McClain, K. R.; Kwon, H.; Chakarawet, K.; Nabi, R.; Kragskow, J. G. C.; Chilton, N. F.; Britt, R. D.; Long, J. R.; Harvey, B. G. J. Am. Chem. Soc. 2023, 145, 8996-9002. "High-Throughput Screening of Hypothetical Metal-Organic Frameworks for Thermal Conductivity" Islamov, M.; Babaei, H.; Anderson, R.; Sezginel, K.; Long, J. R.; McGaughey, A. J. H.; Gomez-Gualdron, D. A.; Wilmer, C. E. Nat. Comp. Mater. 2023, 11. "Electron Density Analysis of Metal–Metal Bonding in a Ni4 Cluster Featuring Ferromagnetic Exchange" Stampe Leiszner, S.; Chakarawet, K.; Long, J. R.; Nishibori, E.; Sugimoto, K.; Platts, J.; Overgaard, J. Inorg. Chem. 2023, 62, 193–200. "Strong Axiality in a Dysprosium(III) Bis(borolide) Complex Leads to Magnetic Blocking at 65 K" Vincent, A.; Whyatt, Y. L.; Chilton, N. F.; Long, J. R. J. Am. Chem. Soc. 2023, 145, in press. "Solvent-Derived Defects Suppress Adsorption in MOF-74" Fu, Y.; Yao, Y.; Forse, A. C.; Mochizuki, K.; Long, J. R.; Reimer, J. A.; De Paëpe, G.; Kong, X. Nat. Commun. 2023, 14, 2386. "Reactive high-spin iron(IV)-oxo sites through dioxygen activation in a metal–organic framework" Hou, K.; Börgel, J.; Jiang, H. Z. H.; Kwon, H.; Zhuang, H.; Rohde, R.; Taylor, J. W.; Chakarawet, K.; SantaLucia, D. J.; Dun, C.; Paley, M. V.; Turkiewicz, A. B.; Park, J. G.; Mao, H.; Zhu, Z.; Alp, E. E.; Zhao, J.; Hu, M.; Lavina, B.; Peredkov, S.; Lv, X.; Oktawiec, J.; Meihaus, K. R.; Pantazi, D. A.; Vandone, M.; Colombo, V.; Bill, E.; Urban, J. J.; Britt, R. D.; Grandjean, F.; Long, G. J.; DeBeer, S.; Neese, F.; Reimer, J. A.; Long, J. R. Science 2023, 382, 547-553. "Reversible Thermal Conductivity Switching Using Flexible Metal–Organic Frameworks" Babaei, H.; Meihaus, K. R.; Long, J. R. Chem. Mater. 2023, 35, . "A Ligand Insertion Mechanism for Cooperative Ammonia Capture in Metal–Organic Frameworks" Snyder, B. E. R.; Turkiewicz, A. B.; Velasquez, E.; Dods, M. N.; Paley, M. V.; Long, J. R. Nature 2023, 613, 287–291. "One-Dimensional Alignment of Defects in a Flexible Metal-Organic Framework" Fu, Y; Forse, A. C.; Kang, Z.; Cliffe, M. J.; Cao, W.; Yin, J. Gao, L.; Pang, Z.; He, T.; Chen, Q.; Wang, Q.; Long, J. R.; Reimer, J. A.; Kong, X. Sci. Adv. 2023, 9, . "Selective Scandium Ion Capture via Coordination Templating in a Covalent Organic Framework" Yuan, Y; Yang, Y.; Meihaus, K. R.; Zhang, S.; Ge, X.; Zhang, W.; Faller, R.; Long, J. R.; Zhu, G. Nat. Chem. 2023, 15, 1599–1606. "Prediction of Multiple Hydrogen Ligation at a Vanadium(II) Site in a Metal-Organic Framework" Chakraborty, R.; Carsch, K.; Jaramillo, D. E.; Yabuuchi, Y.; Furukawa, H.; Long, J. R.; Head-Gordon, M. P. J. Chem. Phys. Lett. 2022, 13, 10471–10478. "Divalent Lanthanide Metallocene Complexes with a Linear Coordination Geometry and Pronounced 6s-5d Orbital Mixing" McClain, K. R.; Gould, C. A.; Marchiori, D. A.; Kwon, H.; Nguyen, T. T.; Rosenkoetter, K. E.; Kuzmina, D.; Tuna, F.; Britt, R. D.; Long, J. R.; Harvey, B. G. J. Am. Chem. Soc. 2022, 144, 22193–22201. "Probing Growth of Metal–Organic Frameworks with X-Ray Scattering and Vibrational Spectroscopy" Lu, W.; Zhang, E.; Qian, J.; Weeraratna, C.; Jackson, M. N.; Zhu, C.; Long, J. R.; Ahmed, M. Phys. Chem. Chem. Phys. 2022, 26102–26110. "Evaluation of the Stability of Diamine-Appended Mg2(dobpdc) Frameworks to Sulfur Dioxide" Parker, S. T.; Smith, A.; Forse, A. C.; Liao, W.-C.; Brown-Altvater, F.; Siegelman, R. L.; Kim, E. J.; Zill, N. A.; Zhang, W.; Neaton, J. B.; Reimer, J. A.; Long, J. R. J. Am. Chem. Soc. 2022, 144, 19849–19860. "A Cooperative Adsorbent for the Switch-Like Capture of Carbon Dioxide from Crude Natural Gas" Siegelman, R. L.; Thompson, J. A.; Mason, J. A.; McDonald, T. M.; Long, J. R. Chem. Sci. 2022, 13, 11772–11784. "Metal–Organic Frameworks as O2-Selective Adsorbents for Air Separations" Jaramillo, D. E.; Jaffe, A.; Snyder, B. E. R.; Smith, A.; Taw, E.; Rohde, R.; Dods, M. N.; De Snoo, W.; Meihaus, K. R.; Harris, T. D.; Neaton, J. B.; Long, J. R. Chem. Sci. 2022, 13, 10216–10237. "From an Antiferromagnetic Insulator to a Fermi Liquid in the Versatile Coordination Solids MCl2(pyrazine)2 (M = Ti, V)" Perlepe, P.; Oyarzabal, I.; Voigt, L.; Kubus, M.; Woodruff, D. N.; Reyes-Lillo, S. E.; Aubrey, M. L.; Negrier, P.; Wilhem, F.; Rogalev, A.; Neaton, J. B.; Long, J. R.; Mathonière, C.; Vignolle, B.; Pedersen, K. S.; Clérac, R. Nat. Commun. 2022. "Prospects for Simultaneously Capturing Carbon Dioxide and Harvesting Water from Air" Dods, M. N.; Weston, S. C.; Long, J. R. Adv. Mater. 2022, 2204277. "Cost and Potential of Metal–Organic Frameworks for Hydrogen Backup Power Supply" Peng, P.; Anastasopoulou, A.; Brooks, K.; Furukawa, H.; Bowden, M.; Long, J. R.; Autrey, T.; Breunig, H. Nat. Energy 2022. "Ultrahard Magnetism from Mixed-Valence Dilanthanide Complexes with Metal-Metal Bonding" Gould, C. A.; McClain, R. A.; Reta, D.; Kragskow, J. G. C.; Marchiori, D. A.; Lachman, E.; Analytis, J. G.; Britt, R. D.; Chilton, N. F.; Harvey, B. G.; Long, J. R. Science 2022, 375, 198–202. "Influence of the Primary and Secondary Coordination Spheres on Nitric Oxide Adsorption and Reactivity in Cobalt(II)–Triazolate Frameworks" Oktawiec, J.; Jiang, H. Z. H.; Turkiewicz, A. B.; Long, J. R. Chem. Sci. 2021, 12, 14590–14598. "Strong Magnetocrystalline Anisotropy Arising from Metal–Ligand Covalency in a Metal–Organic Candidate for 2D Magnetic Order" Wang, Y.; Ziebel, M. E.; Sun, L.; Gish, J. T.; Pearson, T. J.; Lu, X.-Z.; Thorarinsdottir, A. E.; Hersam, M. C.; Long, J. R.; Freedman, D. E.; Rondinelli, J. M.; Puggioni, D.; Harris, T. D. Chem. Mater. 2021, 33, 8712–8721. "Overcoming Metastable CO2 Adsorption in a Bulky Diamine-Appended Metal–Organic Framework" Dinakar, B.; Forse, A. C.; Jiang, H. Z. H.; Zhu, Z.; Lee, J.-H.; Kim, E. J.; Parker, S. T.; Pollak, C. J.; Siegelman, R. L.; Milner, P. J.; Reimer, J. A.; Long, J. R. J. Am. Chem. Soc. 2021, 143, 15258-15270. "Observation of an Intermediate to H2 Binding in a Metal–Organic Framework" Barnett, B. R; Evans, H. A.; Su, G. M.; Jiang, H. Z. H.; Chakraborty, R.; Banyeretse, D.; Hartman, T. J.; Martinez, M. B.; Trump, B. A.; Tarver, J. D.; Dods, M. N.; Drisdell, W. S.; Hurst, K. E.; Gennett, T.; FitzGerald, S. A.; Brown, C. M.; Head-Gordon, M.; Long. J. R. J. Am. Chem. Soc. 2021, 143, 14884–14894. "Strong Ferromagnetic Exchange Coupling and Single-Molecule Magnetism in MoS43−-Bridged Dilanthanide Complexes" Darago, L. E.; Boshart, M. D.; Nguyen, B. D.; Perlt, E.; Ziller, J. W.; Lukens, W.; Evans, W. J.; Long, J. R. J. Am. Chem. Soc. 2021, 143, 8465–8475. "Effect of Spin-Orbit Coupling on Phonon-Mediated Magnetic Relaxation in a Series of Zero-Valent Vanadium, Niobium, and Tantalum Isocyanide Complexes" Chakarawet, K.; Ellis, J. E.; Lukens, W. W., Jr.; Young, V. G., Jr.; Chatterjee, R.; Long, J. R. Inorg. Chem. 2021, 60, 16103–16110. "Templated Growth of a Spin-Frustrated Cluster Fragment of MnBr2 in a Metal–Organic Framework" Turkiewicz, A. B.; Tomlinson, W.; Gonzalez, M. I.; Hooper, J.; Long, J. R. Inorg. Chem. 2021, 60, 16103–16110. "A Hard Permanent Magnet through Molecular Design" Murphy, R. A.; Long, J. R.; Harris, T. D. Commun. Chem. 2021, 4, 70. "Ambient-Temperature Hydrogen Storage via Vanadium(II)-Dihydrogen Complexation in a Metal–Organic Framework" Jaramillo, D. E.; Jiang, H. Z. H.; Evans, H. A.; Chakraborty, R.; Furukawa, H.; Brown, C. M.; Head-Gordon, M.; Long, J. R. J. Am. Chem. Soc. 2021, 143, 6248–6256. "Growth Modulation as a Means of Controlling Anisotropic Crystal Morphology and Molecular Diffusion in Co2(dobdc)" Colwell, K. A.; Jackson, M. N.; Torres-Gavosto, R. M.; Jawahery, S.; Vlaisavljevich, B.; Falkowski, J. M.; Smit, B.; Weston, S. C.; Long, J. R. J. Am. Chem. Soc. 2021, 143 (13), 5044-5052. "Exchange Bias in a Layered Metal–Organic Topological Spin Glass" Murphy, R. A.; Darago, L. E.; Ziebel, M. E.; Peterson, E.; Zaia, E. W.; Mara, M. W.; Lussier, D.; Shuh, D. K.; Urban, J. J.; Neaton, J. B.; Long, J. R. ACS Cent. Sci. 2021, 7. "Ion-Capture Electrodialysis Using Multifunctional Adsorptive Membranes" Uliana, A. A.; Bui, N. T.; Kamcev, J.; Taylor, M. K.; Urban, J. J.; Long, J. R. Science 2021, 372, 296-299. "Fluoroarene Separations in Metal–Organic Frameworks with Two Proximal Mg2+ Coordination Sites." Zick, M. E.; Lee, J.-H.; Gonzalez, M. I.; Velasquez, E. O.; Uliana, A. A.; Kim, J.; Long, J. R.; Milner, P. J. J. Am. Chem. Soc. 2021, 143 (4), 1948–1958. "Deep CCS: Moving Beyond 90% Carbon Dioxide Capture" Dods, M. N.; Kim, E. J.; Long, J. R.; Weston, S. C. Energy Sci. Tech 2021, 55, 8524–8324. "Isotherm, Kinetic, and Process Modeling and Techno-Economic Analysis of a Fixed Bed Temperature Swing Adsorption Process for a Diamine-Appended Metal–Organic Framework" Hughes, R.; Kotamreddy, G.; Ostace, A.; Bhattacharyya, D.; Siegelman, R. L.; Parker, S. T.; Didas, S. A.; Long, J. R.; Omell, B.; Matuszewski, M. Energy Fuels 2021, 35 (7), 6040–6055. "Backbonding Contributions to Small Molecule Chemisorption in a Metal–Organic Framework with Open Copper(I) Centers" Su, G. M.; Wang, H.; Barnett, B. R.; Long, J. R.; Prendergast, D.; Drisdell, W. S. Chem. Sci. 2021, 12, 2156–2164. "Technoeconomic Analysis of Metal–Organic Frameworks for Bulk Hydrogen Transportation" Anastasopoulou, A.; Furukawa, H.; Barnett, B. R.; Jiang, H. Z. H.; Long, J. R.; Breunig, H. M. Energy Environ. Sci. 2021, 14 (3), 1083–1094. "Isolation of a Triplet Benzene Dianion" Gould, C. A.; Marbey, J.; Vieru, V.; Marchiori, D. A.; Britt, R. D.; Chibotaru, L.; Hill, S.; Long. J. R. Nat. Chem. 2021, 13, 1001-1005. "Magnetic Ordering via Itinerant Ferromagnetism in a Metal–Organic Framework" Park, J. G.; Collins, B. A.; Darago, L. E.; Runčevski, T.; Ziebel, M. E.; Aubrey, M. L.; Jiang, H. Z. H.; Velasquez, E.; Green, M. A.; Goodpaster, J. D.; Long, J. R. Nat. Chem. 2021, 13, 594–598. "Hysteresis Curves Reveal Microscopic Origin of Cooperative CO2 Adsorption in Diamine-Appended Metal-Organic Frameworks" Edison, J. R.; Siegelman, R. L.; Preisler, Z.; Kundu, J.; Long, J. R.; Whitelam, S. J. Chem. Phys. 2021, 154, 214704. "Dependence of Linker Length and Composition on Ionic Conductivity and Lithium Deposition in Single-Ion Conducting Network Polymers" Aubrey, M. L.; Axelson, J. C.; Engler, K. E.; Long, J. R. Macromolecules 2021.