个人简介

B.A., M.S., Ph.D., Columbia University IBM Postdoctoral Fellow, University of Chicago AWARDS & HONORS Camille and Henry Dreyfus Distinguished New Faculty Award, 1987 Union Carbide Innovation Recognition Award, 1992 Alfred P. Sloan Fellowship, 1992 Camille and Henry Dreyfus Teacher-Scholar Fellowship, 1992 ACS Catalysis Lectureship Award for the Advancement of Catalytic Science, 2012

研究领域

Inorganic Chemistry/Organic Chemistry

Organometallic chemistry: reactions, mechanisms, photochemistry, and catalysis The research conducted in my group is focused on the reactions between transition metal complexes and simple organic molecules, particularly hydrocarbons. Our work generally involves a mechanism-based approach to the development of catalysts.

近期论文

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"Addition of C-C and C-H Bonds by Pincer-Iridium Complexes: a Combined Experimental and Computational Study" D. A. Laviska, C. Guan, T. J. Emge, M. Wilklow-Marnell, W. W. Brennessel, W. D. Jones, K. Krogh-Jespersen, A. S. Goldman Dalton Trans. 2014, 43, 16354-16365. DOI: 10.1039/C4DT02043J "Catalytic Cleavage of Ether C–O Bonds by Pincer Iridium Catalysts" M. C. Haibach, N. Lease, and A. S. Goldman, Angew Chem. Int. Ed., 2014, 53, 10160–10163. DOI: 10.1002/anie.201402576 "Acid-catalyzed Oxidative Addition of a C-H Bond to a Square Planar d8 Iridium Complex" J. D. Hackenberg, S. Kundu, T. J. Emge, K. Krogh-Jespersen and A. S. Goldman, J. Am. Chem. Soc. 2014, 136, 8891–8894. DOI: 10.1021/ja503953v "Synthesis and Characterization of Carbazolide-based Iridium PNP Pincer Complexes. Mechanistic and Computational Investigation of Alkene Hydrogenation: Evidence for an Ir(III)/Ir(V)/Ir(III) Catalytic Cycle" C. Cheng, B. G. Kim, D. Guironnet, M. Brookhart, C. Guan, D. Y. Wang, A. S. Goldman J. Am. Chem. Soc. 2014, 136, 6672−6683. DOI: 10.1021/ja501572g "Activation of C-O and C-F Bonds by Pincer-Iridium Complexes" J. Hackenberg, K. Krogh-Jespersen and A. S. Goldman in Organometallic Chemistry and Catalysis: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book (Ed. A. J. L. Pombeiro), John Wiley & Sons, Hoboken, NJ, 2014, pp. 39-58. ISBN: 978-1-118-51014-8 "Rational Design of Highly Active "Hybrid" Phosphine-Phosphinite Pincer Iridium Catalysts for Alkane Metathesis" A. Nawara-Hultzsch, J. Hackenberg, B. Punji, C. Supplee, T. Emge, B. Bailey, R. R. Schrock, M. Brookhart, A. S. Goldman ACS Catalysis 2013, 3, 2505-2514. DOI: 10.1021/cs400624c "Olefin Hydroaryloxylation Catalyzed by Pincer-Iridium Complexes" M. C Haibach, C. Guan, D. Y. Wang, B. Li, N. Lease, A. Steffens, K Krogh-Jespersen and A S. Goldman J. Am. Chem. Soc. 2013, 135, 15062-15070. DOI: 10.1021/ja404566v "Catalytic Synthesis of n-Alkyl Arenes through Alkyl Group Cross Metathesis" G. E. Dobereiner. J. Yuan. R. R. Schrock. A. S. Goldman, J. D. Hackenberg J. Am. Chem. Soc. 2013, 135, 12572-12575. DOI: 10.1021/ja4066392 "(POP)Rh pincer hydride complexes: unusual reactivity and selectivity in oxidative addition and olefin insertion reactions" M. C. Haibach, D. Y. Wang, T. J. Emge, K. Krogh-Jespersen and A. S. Goldman Chem. Sci. 2013, 4, 3683-3692. DOI: 10.1039/C3SC50380A "Cleavage of Ether, Ester and Tosylate C(sp3)-O Bonds by an Iridium Complex, Initiated by Oxidative Addition of C-H Bonds. Experimental and Computational Studies" S. Kundu, J. Choi, D. Y. Wang, Y. Choliy, T. J. Emge, K. Krogh-Jespersen and A. S. GoldmanJ. Am. Chem. Soc. 2013, 135, 5127-5143. DOI: 10.1021/ja312464b "Alkane Dehydrogenation by C–H Activation at Iridium(III)" Kate E. Allen, D. Michael Heinekey, Alan S. Goldman, and Karen I. Goldberg. Organometallics, 2013, 32 (6), pp 1579–1582. DOI: 10.1021/om301267c Alkane Metathesis by Tandem Alkane-Dehydrogenation-Olefin Metathesis Catalyst and Related Chemistry. Michael C. Haibach, Sabuj kundu, Maurice Brookhart, and Alan S. Goldman. Acc. Chem. Res. 2012, 45 (6), 947-958. DOI: 10.1021/ar3000713 Theoretical Structure-Reactivity Study of Ethylene Insertion into Nickel-Alkyl Bonds. A kinetically significant and unanticipated role of trans influence in determining agostic bond strengths. Faraj Hasaynan, Patrick Achord, Pierre Braunstein, Hamza Javar Magnier, Karsten Krogh-Jespersen and Alan S. Goldman. Organometallics, 2012, 31 (13), 4680-4692. DOI: 10.1021/om300001n Olefin Isomerization by Iridium Pincer Catalysts. Experimental evidence for an n3-allyl pathway and an unconventional mechanism predicted by DFT calculations. Soumik Biswas, Zheng Huang, Yuriy Choliy, David Y. Wang, Maurice Brookhart, Kartsen Krogh-Jespersen, and Alan S. Goldman. J. Am. Chem. Soc. 2012, 134 (32), 13276-13295. DOI:10.1021/ja301464c "Alkane Dehydrogenation" Michael Findlater, Jongwook Choi, Alan S. Goldman, and Maurice Brookhart. In Alkane C-H Activation by Single Site Metal Catalysis, Catalysis of Metal Complexes Series, 2012, 38, 113-141. DOI: 10.1007/978-90-481-3698_4. "Net Oxidative Addition of C(sp3)−F Bonds to a Transition Metal Center via C−H Bond Addition" J. Choi, D. Y. Wang, S. Kundu, Y. Choliy, T. J. Emge, K. Krogh-Jespersen, and A. S. Goldman, Science 2011, 332, 1545-1548, DOI: 10.1126/science.1200514 "Synthesis and structural characterization of new polynuclear complexes of 1‑hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II)" R. Touzani, M. Haibach, A. J. Nawara-Hultzsch, S. E. Kadiri, T. J. Emge, and A. S. Goldman Polyhedron 2011, 30, 2530–2534. http://dx.doi.org/10.1016/j.poly.2011.06.038 "Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes" J. Choi, A. H. R. MacArthur, M. Brookhart, and A. S. Goldman Chem. Rev. 2011, 111, 1761-1779. DOI: 10.1021/cr1003503 "Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes" R. Ahuja, B. Punji, M. Findlater, C. Supplee, W. Schinski, M. Brookhart, A. S. Goldman Nature Chem. 2011, 3, 167-171. DOI: 10.1038/nchem.946