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研究领域

Process Safety, Fire and Explosion Safety • Fire and explosion mitigation; fire fighting foams, flammability, water mist, gaseous suppression agents, inerting, etc • Spontaneous combustion; coal, linseed oil, zinc powder, etc, also peroxide chemistry • Fire chemistry and fire toxicity; formation of toxic organic and inorganic pollutants in fires • Ammonium nitrate emulsion explosives, especially their sensitisation and mitigation of NOx formed during sensitisation and blasting, nitrosation reactions • Flammability properties of CS2, Shell UK Mitigation of CO2 Emissions • Large scale storage of CO2, especially by mineral carbonation • Biofeedstocks for chemical industry and their reactions, especially glycerol • Mitigation of emission of ventilation air methane in coal mining Environment Protection • Degradation of pesticides in the environment, especially pathways leading to formation of dioxins (PCDD/F) and other pollutants from chemical fires • Halogen chemistry, especially conversion of HFC, CFC and halons to useful products, and processing of halogenated hydrocarbons in non-equilibrium plasmas Together with Dr Mohammednoor Altarawneh, and our Postdoctoral Fellow Dr Juita, I manage the Fire Safety and Combustion Kinetics Laboratory at Murdoch University. The laboratory comprises specialised facilities to support research into process safety and environment protection, with emphasis on conversion of biomass, reaction kinetics, mitigation of toxic species forming in industrial processes and fire safety. The laboratory, established by Murdoch in 2014 with the investment of $3m, supports the work of 15 researchers. The laboratory contains space dedicated to trace analysis, thermal analyses, UV/Raman spectroscopy, cone calorimetry and general experimental areas, each supported by dedicated libraries, gas delivery systems, safety systems, fume hoods and exhaust systems, vacuum and compressed-air lines, and reversed-osmosis water. The laboratory houses sophisticated, state-of-art instrumentation, including triple quadrupole mass spectrometer (Shimadzu GCMS-TQ8040), gas chromatograph (Agilent 7890B Series GC with flame ionisation and electron capture detectors) coupled to a thermal desorption unit (Markes 2 Unity) and to Fourier transform infrared spectrometer (Agilent 670 FTIR with dual MIR/NIR source and MCT detector) via a GC-FTIR transfer assembly, micro gas chromatograph (490 Micro GC with three GC channels), PerkinElmer thermogravimetric-differential scanning calorimetry with dedicated Fourier transform infrared spectrometer (STA 8000 TG/DSC-FTIR), UV-Vis Spectrometer (Agilent Cary 5000), Bruker electron paramagnetic resonance spectrometer (EMX Plus with a dedicated high temperature cavity), stopped flow with a fast UV-VIS spectrophotometer (BioLogic SFM300/QS with MOS200/M spectrophotometer), and a range of supplementary instruments, such as ASE-150 accelerated solvent extractor, soxhlet extractor or rotary evaporator. Alongside experiments, the researchers associated with the laboratory have access to PC-installed Cosilab, Material Studio 8.0, Chemkin-Pro and Pawsey/NCI supercomputer-installed Gaussian09, VASP, DMol3 and ADF software packages for quantum-chemical and reaction-kinetics calculations.

近期论文

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143. Stec AA, Readman J, Blomqvist P, Gylestam D, Karlsson D, Wojtalewicz D, Dlugogorski BZ “Analysis of toxic effluents released from PVC carpet under different fire conditions”, Chemosphere 90, 65-71 (2013) [A in ERA 2010] 144. Altarawneh M, Dlugogorski BZ, Kennedy EM, Mackie JC “Rate constants for reactions of ethylbenzene with hydroperoxyl radical”, Combustion and Flame 160(1), 9-16 (2013) [A* in ERA 2010] 145. Balucan R, Dlugogorski BZ “Thermal activation of antigorite for mineralisation of CO2” Environmental Science and Technology 47, 182-190 (2013) [A* in ERA 2010] 146. Oskierski HC, Bailey JG, Kennedy EM, Jacobsen G, Ashley PM, Dlugogorski BZ, “Formation of weathering-derived magnesite deposits in the New England Orogen, New South Wales, Australia: Implications from mineralogy, geochemistry and genesis of the Attunga Magnesite Deposit”, Mineralium Deposita, 48(4), 525-541 (2013) [A in ERA 2010] 147. Summoogum SL, Wojtalewicz D, Altarawneh M, Mackie JC, Kennedy EM, Dlugogorski BZ “Formation of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F) by precursor pathways in oxidation of pesticide alpha-cypermethrin”, Proceedings of the Combustion Institute 34, 3499-3507 (2013) [A in ERA 2010] 148. Altarawneh M, Dlugogorski BZ, Kennedy EM, Mackie JC “Theoretical investigation into the low-temperature oxidation of ethylbenzene”, Proceedings of the Combustion Institute 34, 315-323 (2013) [A in ERA 2010] 149. Gaikwad V, Kennedy EM, Mackie JC, Holdsworth C, Molloy S, Kundu S, Dlugogorski BZ “Non-oxidative conversion of 1,2-dichloroethane in a non-thermal plasma and characterisation of the polymer formed”, Plasma Processes and Polymers 10(2), 141-149 (2013) [A in ERA 2010] 150. Altarawneh M, Dlugogorski BZ “A mechanistic and kinetic study on the formation of PBDD/Fs from PBDEs”, Environmental Science and Technology 47, 5118-5127 (2013) [A* in ERA 2010] 151. Ahmad K, Mowla O, Kennedy E, Dlugogorski B and Mackie J, Stockenhuber M “A melamine-modified β-zeolite with enhanced CO2 capture properties”, Energy Technology 1, 345-349 2013 (2013) [new Wiley journal not in ERA 2010] 152. Venpin WKPF, Kennedy EM, Mackie, Dlugogorski BZ, “Comparative study of the physicochemical properties of ortho-substituted aromatic nitroso compounds”, Journal of Chemical and Engineering Data 58(4) 1005-1010 (2013) [A* in ERA 2010] 153. Balucan RD, Dlugogorski BZ, Kennedy EM, Belova IV, Murch E, “Energy cost of heat activating serpentinites for CO2 storage by mineralisation”, International Journal of Greenhouse Gas Control 17, 225-239 (2013) [B in ERA 2010, Journal Impact Factor 5.1] 154. Venpin WKPF, Kennedy EM, Mackie JC, Dlugogorski BZ, “Trapping of nitric oxide, generated during sensitisation of ammonium nitrate emulsion explosive, by aromatic nitroso sulfonates”, Industrial and Engineering Chemistry Research 52(31), 10561-10568 (2013) [A in ERA 2010] 155. Juita, Dlugogorski BZ, Kennedy EM and Mackie JC, “Roles of peroxides and unsaturation in spontaneous heating of linseed oil”, Fire Safety Journal 61, 108-115 (2013) [A in ERA 2010] 156. Oskierski HC, Dlugogorski BZ and Jacobsen G, “Sequestration of atmospheric CO2 in a weathering-derived, serpentinite-hosted magnesite deposit: 14C tracing of carbon sources and age constraints for a refined genetic model”, Geochimica et Cosmochimica Acta 122, 226-246 (2013) [A* in ERA 2010] 157. Mosallanejad S, Dlugogorski BZ, Kennedy EM and Stockenhuber M, HCl Adsorption on Copper Modified ZSM-5, FTIR and DFT Study, Journal of Physical Chemistry C 117(38), 19365-19372 (2013) [A* in ERA 2010] 158. Dar T, Altarawneh M, Dlugogorski BZ, “Quantum chemical study on formation of PCDT/TA from 2-chlorothiophenol precursor”, Environmental Science and Technology, 47(19), 11040-11047 (2013 [A* in ERA 2010] 159. Oskierski HC, Dlugogorski BZ, Jacobsen G, “Sequestration of atmospheric CO2 in chrysotile mine tailings of the Woodsreef Asbestos Mine, Australia: Quantitative mineralogy, isotopic fingerprinting and carbonation rates”, Chemical Geology, 358, 156-169 (2013) [A* in ERA 2010] 2014 160. Dlugogorski BZ, Balucan R “Dehydroxylation of Serpentine Minerals: Implications for Mineral Carbonation”, Renewable & Sustainable Energy Reviews 31C, 353-367 (2014) [no ERA 2010 ranking, Journal Impact Factor = 5.63] 161. Ghoorah M, Dlugogorski BZ, Balucan R, Kennedy E “Selection of acid for weak acid processing of wollastonite for mineralisation of CO2”, Fuel 122, 277-286 (2014) [A* in ERA 2010] 162. Sanchez G, Friggieri J, Keast C, Drewery M, Dlugogorski BZ, Kennedy E and Stockenhuber M “The effect of catalyst modification on the conversion of glycerol to allyl alcohol”, Applied Catalysis B: Environmental 152-153, 117-128 (2014) [A in ERA 2010]

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