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Electrochemistry, sensors, room temperature ionic liquids, gas detection, solid/liquid interface, liquid/liquid interface, nanomaterials, functionalizing surfaces

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Lee, J., G. Du Plessis, D. W. Arrigan, and D. S. Silvester. 2015.“Towards improving the robustness of electrochemical gas sensors: Impact of PMMA addition on the sensing of oxygen in an ionic liquid.”Analytical Methods 7 (17): 7327-7335. Alvaez De Eulate, E., D. S. Silvester, and D. W. Arrigan. 2015.“Void-Assisted Ion-Paired Proton Transfer at Water-Ionic Liquid Interfaces.”Angewandte Chemie - International Edition 54 (49): 14903-14906. Murugappan, K., and D. S. Silvester. 2015.“Sensors for Highly Toxic Gases: Methylamine and Hydrogen Chloride Detection at Low Concentrations in an Ionic Liquid on Pt Screen Printed Electrodes.”Sensors 15 (10): 26866-26876. Murugappan, K., D. S. Silvester, D. S. Chaudhary, and D. W. Arrigan. 2014.“Electrochemical Characterization of an Oleyl-coated Magnetite Nanoparticle-Modified Electrode.”ChemElectroChem 1: 1211-1218. Murugappan, K., C. Kang, and D. S. Silvester. 2014.“Electrochemical Oxidation and Sensing of Methylamine Gas in Room Temperature Ionic Liquids.”The Journal of Physical Chemistry C 118: 19232-19237. Wright, P. J., S. Muzzioli, B. W. Skelton, P. Raiteri, J. Lee, G. A. Koutsantonis, D. S. Silvester, S. Stagni, and M. Massi. 2013.“One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix3arene with aqua emission and reversible three-electron oxidation.”Dalton Transactions 42 (23): 8188-8191. Sairi, M., J. Strutwolf, R. A. Mitchell, D. S. Silvester, and D. W. Arrigan. 2013.“Chronoamperometric response at nanoscale liquid–liquid interface arrays.”Electrochimica Acta 101: 177-185. Lee, J., K. Murugappan, D. W. Arrigan, and D. S. Silvester. 2013.“Oxygen Reduction Voltammetry on Platinum Macrodisk and Screen-Printed Electrodes in Ionic Liquids: Reaction of the Electrogenerated Superoxide Species with Compounds Used in the Paste of Pt Screen-Printed Electrodes?.”Electrochimica Acta 101: 158-168. Wright, P. J., M. G. Affleck, S. Muzzioli, B. W. Skelton, P. Raiteri, D. S. Silvester, S. Stagni, and M. Massi. 2013.“Ligand-induced structural, photophysical, and electrochemical variations in tricarbonyl rhenium(I) tetrazolato complexes.”Organometallics 32 (13): 3728-3737. Alvarez de Eulate, E., D. S. Silvester, and D. W. Arrigan. 2012.“Behavior of Lysozyme at the Electrified Water/Room Temperature Ionic Liquid Interface.”Chemistry - An Asian Journal 7: 2559-2561. Silvester, D. S., S. Uprety, P. J. Wright, M. Massi, S. Stagni, and S. Muzzioli. 2012.“Redox Properties of a Rhenium Tetrazolato Complex in Room Temperature Ionic Liquids: Assessing the Applicability of the Stokes-Einstein Equation for a Metal Complex in Ionic Liquids.”Journal of Physical Chemistry C 116 (13): 7327-7333. Wright, P. J., S. Muzzioli, M. V. Werrett, P. Raiteri, B. W. Skelton, D. S. Silvester, S. Stagni, and M. Massi. 2012.“Synthesis, photophysical and electrochemical investigation of dinuclear tetrazolato-bridged rhenium complexes.”Organometallics 31: 7566-7578. Silvester, D. S. 2011.“Recent advances in the use of ionic liquids for electrochemical sensing.”Analyst 136: 4871-4882. Silvester, D. S., and D. W. Arrigan. 2011.“Array of water|room temperature ionic liquid micro-interfaces.”Electrochemistry Communications 13: 477-479. Murugappan, K., J. Lee, and D. S. Silvester. 2011.“Comparative study of screen printed electrodes for ammonia gas sensing in ionic liquids.”Electrochemistry Communications 13: 1435-1438. Silvester, D. S., E. Grygolowicz-Pawlak, and E. Bakker. 2010.“Potentiometric determination of coextraction constants of potassium salts in ion-selective electrodes utilizing a nitrobenzene liquid membrane phase.”Analytica Chimica Acta 683: 92-95. Veder, J., K. Patel, G. J. Clarke, E. Grygolowicz-Pawlak, D. S. Silvester, R. De Marco, E. Pretsch, and E. Bakker. 2010.“Synchrotron Radiation/Fourier Transform-Infrared Microspectroscopy Study of Undesirable Water Inclusions in Solid-Contact Polymeric Ion-Selective Electrodes.”Analytical Chemistry 82: 6203-6207. Barrosse-Antle, L. E., A. M. Bond, R. G. Compton, A. M. O'Mahony, E. I. Rogers, and D. S. Silvester. 2010.“Voltammetry in Room Temperature Ionic Liquids: Comparisons and Contrasts with Conventional Electrochemical Solvents.”Chemistry - An Asian Journal 5: 202-230. Silvester, D. S., E. Grygolowicz-Pawlak, and E. Bakker. 2010.“Assessing ion-exchange properties and purity of lipophilic electrolytes by potentiometry and spectrophotometry.”Electrochemistry Communications 12: 110-113. He, W., D. S. Silvester, I. Streeter, L. Aldous, C. Hardacre, and R. G. Compton. 2009.“Measuring the solubility of benzoic acid in room temperature ionic liquids using chronoamperometric techniques.”Journal of Physical Organic Chemistry 22: 69-76.

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