Arnold, John - University of California, Berkeley

个人简介

B.Sc. Applied Chemistry, Salford University, 1982 Ph.D. Inorganic Chemistry, University of California, San Diego, 1986 Thesis advisor: T. D. Tilley Postdoctoral Fellow, Imperial College, London with Professor Sir Geoffrey Wilkinson, FRS, 1987-88 Royal Society Research Fellow, Imperial College, 1988-89 Assistant Professor of Chemistry, University of California, Berkeley, 1989-95 Associate Professor of Chemistry, University of California, Berkeley, 1995-2000 Professor of Chemistry, University of California, Berkeley, 2000 Faculty Scientist, Lawrence Berkeley National Laboratory, Chemical Sciences Division Associate Editor for the Americas, Dalton Transactions 2002-present Director, Berkeley Center for Green Chemistry 2009-present

研究领域

Green Chemistry/Inorganic & Organometallic/Materials/Polymers & Nanoscience

近期论文

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"Structural and Electronic Noninnocence of α-Diimine Ligands on Niobium for Reductive C–Cl Bond Activation and Catalytic Radical Addition Reactions." Haruka Nishiyama, Hideaki Ikeda†, Teruhiko Sait, Benjamin Kriegel, Hayato Tsurugi, John Arnold, and Kazushi Mashima. J. Am. Chem. Soc., 2017, DOI: 10.1021/jacs.7b02710. "A Thorium Chalcogenolate Series Generated by Atom Insertion into Thorium–Carbon Bonds." Nicholas S. Settineri , Mary E. Garner , and John Arnold, J.Am. Chem. Soc., 2017, DOI: 10.1021/jacs.7b02356 "Tools for Green Molecular Design to Reduce Toxicological Risk." David Faulkner, Leah K. Rubin Shen, Vanessa Y. De La Rosad , Dale E. Johnson , Rachel Hemingway , Richard V. Williams, Philip N. Judson , John Arnold and Chris D. Vulpe. Computational Systems Pharmacology and Toxicology, 2017, 31, 36-59. "Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes" Benjamin M. Kriegel, Lara C. E. Naested, Grégory Nocton, K. V. Lakshmi⊥, Trevor D. Lohrey, Robert G. Bergman, and John Arnold. Inorg. Chem. 2017, DOI: 10.1021/acs.inorgchem.6b02735. "Synthesis and reactivity of tantalum corrole complexes." Jessica A Ziegler, Heather L Buckley and John Arnold, Dalton Transactions, 2017, 46, 780 - 785. “A Homoleptic Uranium(III) Tris(aryl) Complex” Michael A. Boreen, Bernard F. Parker, Trevor D. Lohrey, and John Arnold, J. Am Chem. Soc., 2016, 138, 15865–15868 "Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium β-Diketiminate Complex." Trevor D. Lohrey, Robert G. Bergman*, and John Arnold*, Inorg. Chem., 2016, 55, 11993–12000. “Control of Clustering Behavior in Anionic Lanthanide(III) Corrole Complexes: From Oligomers to Monomers” Keith C. Armstrong, Stephan Hohloch, Trevor D. Lohrey, Ryan A. Zarkesh, John Arnold, and Mitchell R. Anstey. Dalton Trans. 2016, 45, 18653-18660. "Carbon–Nitrogen Bond Cleavage by a Thorium-NHC-bpy Complex." Mary E. Garner, Stephan Hohloch, Dr. Laurent Maron, John Arnold. Angew. Chemie, Intl. Ed. 2016, 44, 13993-13996. "A New Supporting Ligand in Actinide Chemistry Leads to Reactive Bis(NHC)borate-Supported Thorium Complexes" Mary E. Garner, Stephan Hohloch, Laurent Maron, and John Arnold. Organometallics, 2016, 35, 2915-2922. “Unusual κ1 Coordination of a β-Diketiminate Ligand in Niobium Complexes.” Jessica A. Ziegler, Robert G. Bergman, and John Arnold,Dalton Trans. 2016, 45, 12661 - 12668. On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds. Clément Camp and John Arnold, Dalton Transactions, 2016, 45, 14462-14498. β-diketiminate ligands in group 5 metal chemistry. Stephan Hohloch, Benjamin M. Kriegel, Robert G. Bergman, and John Arnold. Dalton Trans. 2016, 45, 15725-15745. Activation of Heteroallenes by Coordinatively Unsaturated Nickel(II) Alkyl Complexes Supported by the Hydrotris(3-phenyl-5-methyl)pyrazolyl Borate (TpPh,Me) Ligand. Mark Abubekerov, Léonard Y. M. Eymann, Thomas L. Gianetti, John Arnold, Dalton Trans. 2016, 45, 14581-14590. Photo-activation of d0 niobium imido azides: en route to nitrido complexes. Clément Camp, Lauren N. Grant,Robert G. Bergman, and John Arnold. Chem. Comm., 2016, 52, 5538-5541. A Peptoid-Based Combinatorial and Computational Approach to Developing Ligands for Uranyl Sequestration from Seawater. Bernard F. Parker, Abigail S. Knight, Sinisa Vukovic, John Arnold, and Matthew B. Francis. Ind. Eng. Chem. Res., 2016, 55, doi.org/10.1021/acs.iecr.5b03500. Structural and spectroscopic studies of a rare non-oxido V(V) complex crystallized from aqueous solution. Christina J. Leggett, Bernard F. Parker, Simon J. Teat, Zhicheng Zhang, Phuong D. Dau, Wayne Lukens, Sonja M. Peterson, Allan Jay P. Cardenas, Marvin G. Warner, John K. Gibson, John Arnold, and Linfeng Rao. Chem. Sci., 2016, 7, 2775 -2786. Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes. Benjamin M. Kriegel, Robert G. Bergman, and John Arnold. J. Am. Chem. Soc., 2016, 138, 52-55. N-N Bond Cleavage in a Nitrous Oxide-NHC Adduct Promoted by a PNP Pincer Cobalt(I) Complex. Clément Camp, Lara C. E. Naested, Kay Severin, and John Arnold. Special issue of Polyhedron in honor of Malcolm Chisholm. 2016, doi:10.1016/j.poly.2015.09.001 Formation of a Niobium-Aluminum Heterobimetallic Complex via Supporting Ligand Exchange. Lauren N. Grant, Benjamin M. Kriegel, and John Arnold. Special undergraduate research issue of Polyhedron. 2015, 10.1016/j.poly.2015.09.066 Theory and X-ray absorption spectroscopy for aluminum coordination complexes – Al K-edge studies of charge and bonding in (BDI)Al, (BDI)AlR2, and (BDI)AlX2 complexes. Alison B. Altman, C. Das Pemmaraju, John Arnold, Stefan G. Minasian, David Prendergast, David K. Shuh, Tolek Tyliszczak. J. Am. Chem. Soc., 2015, 137, 10304–10316. C-F sp2 bond functionalization mediated by niobium complexes. Michael Nechayev, Thomas Gianetti, Robert G Bergman and John Arnold, Dalton Trans., Special Fluorine issue, 2015, 44, 19494 - 19500. Uranium and Thorium Complexes of the Phosphaethynolate Ion. Clément Camp, Nicholas Settineri, Julia Lefèvre, Andrew R. Jupp, José Goicoechea, Laurent Maron, and John Arnold. Chem. Sci., 2015, 6, 6379 - 6384. Preparation and characterization of a tungsten(V) corrole dichloride complex. Padilla, R; Buckley, H.B.; Ward, A.L.; Arnold, J.J. Porph. Phthal. invited contribution, 2015, 19, 150-153.