Gardiner, Michael - University of Tasmania - School of Physical Sciences, Discipline of Chemistry

研究领域

The goal of our research is to obtain an improved understanding of organometallic reagents, or make new and better ones, for their contemporary applications in different arenas: catalysis, synthesis and materials. The projects involve various molecular design research strategies, either close to the 'pure' synthetic end or towards the 'application' end of the research continuum. The research plan places an importance on an integrated picture for structural investigations (solution, solid state, computed) of newly synthesised compounds leading to their better overall understanding and applied usage. Links to current projects are on the school page or can be viewed through my personal page

近期论文

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1,4-Bis(trimethylsilyl)but-2-ene-1,4-diyl Complexes of Lithium, Magnesium, Aluminum and Gallium M.G. Gardiner, C.L. Raston, F.G.N. Cloke and P.B. Hitchcock 1995 * Organometallics 14 1339-1353 Advances in the Chemistry of Lewis Base Adducts of Alane and Gallane M.G. Gardiner and C.L. Raston 1997 * Coord. Chem. 166 1-34 Polymer Supported Carbene Complexes of Palladium: Well-Defined, Air-Stable, Recyclable Catalysts for the Heck Reaction J. Schwarz, V.P.W. B? hm, M.G. Gardiner, M. Grosche, W.A. Herrmann, W. Hieringer and G. Raudaschl-Sieber 2000 * Chem. Eur. J. 6 1773-1780 Valence-Shell Charge Concentrations and Electron Delocalization in Alkyllithium Complexes: Negative Hyperconjugation and Agostic Bonding W. Scherer, P. Sirsch, D. Shorokhov, G. S. McGrady, S. A. Mason and M. G. Gardiner 2002 * Chem. Eur. J. 8 2324 'Rational Synthesis and Derivatisation of Mononuclear, Alkali Metal-Free Lanthanide(II) and (III) meso-Octaalkylporphyrinogen Complexes' J. Wang, A.K.J. Dick, M.G. Gardiner, B.F. Yates, E.J. Peacock, B.W. Skelton and A.H. White 2004 * Eur. J. Inorg. Chem. 1992-1995 'Alkali-Metal, Halide, and Lewis Base Free Monomeric Alkylsamarium(III) Porphyrinogen Complexes of High Stability' J. Wang, M.G. Gardiner, B.W. Skelton and A.H. White 2005 * Organometallics 24 815-818 'CH Activation ( -Deprotonation) of a Sm(III) Bis(trimethylsilyl)amide Complex via Macrocyclic Stabilisation of the Sodium Counter Ion' J. Wang and M.G. Gardiner 2005 * Chem. Commun. 1589-1591 'Structural studies of Group 1 metal 4-azapentalenyl complexes' M.J. Bermingham, F.G.N. Cloke, M.G. Gardiner, P.B. Hitchcock, L.E. Wise and B.F. Yates 2005 * Dalton Trans. 1157-1158 'Reversible Sm(III)/Sm(II) Redox Chemistry of an Organosamarium(III) Complex' J. Wang, R.I.J. Amos, A.S.P. Frey, M.G. Gardiner, M.L. Cole and P.C. Junk 2005 * Organometallics 24 2259-2261 M.J. Bermingham, F.G.N. Cloke, M.G. Gardiner, P.B. Hitchcock, L.E. Wise and B.F. Yates, 2005, ''Structural studies of Group 1 metal 4-azapentalenyl complexes' ', Dalton Trans., pgs. 1157-1158 J. Wang, M.G. Gardiner, B.W. Skelton and A.H. White, 2005, ''Alkali-Metal, Halide, and Lewis Base Free Monomeric Alkylsamarium(III) Porphyrinogen Complexes of High Stability'', Organometallics, 24, pgs. 815-818 J. Wang and M.G. Gardiner, 2005, ''C–H Activation ( -Deprotonation) of a Sm(III) Bis(trimethylsilyl)amide Complex via Macrocyclic Stabilisation of the Sodium Counter Ion'', Chem. Commun., pgs. 1589-1591 J. Wang, R.I.J. Amos, A.S.P. Frey, M.G. Gardiner, M.L. Cole and P.C. Junk, 2005, ''Reversible Sm(III)/Sm(II) Redox Chemistry of an Organosamarium(III) Complex'', Organometallics, 24, pgs. 2259-2261 J. Wang, A.K.J. Dick, M.G. Gardiner, B.F. Yates, E.J. Peacock, B.W. Skelton and A.H. White, 2004, ''Rational Synthesis and Derivatisation of Mononuclear, Alkali Metal-Free Lanthanide(II) and (III) meso-Octaalkylporphyrinogen Complexes'', Eur. J. Inorg. Chem., pgs. 1992-1995 W. Scherer, P. Sirsch, D. Shorokhov, G. S. McGrady, S. A. Mason and M. G. Gardiner, 2002, 'Valence-Shell Charge Concentrations and Electron Delocalization in Alkyllithium Complexes: Negative Hyperconjugation and Agostic Bonding', Chem. Eur. J., 8, pgs. 2324 J. Schwarz, V.P.W. B?hm, M.G. Gardiner, M. Grosche, W.A. Herrmann, W. Hieringer and G. Raudaschl-Sieber, 2000, 'Polymer Supported Carbene Complexes of Palladium: Well-Defined, Air-Stable, Recyclable Catalysts for the Heck Reaction', Chem. Eur. J., 6, pgs. 1773-1780