研究领域
Allan's Research is specifically concerned with fundamental organometallic chemistry involving projects of direct relevance to the roles of organometallic compounds in organic synthesis and catalysis, with a particular emphasis on complexes containing metal to carbon sigma-bonds, usually involving palladium or platinum. Studies have included the development of the first organopalladium complexes with oxidation state +IV for palladium, and mechanistic studies of carbon...carbon and carbon...heteroatom bond formation at a palladium(IV) centre, and is currently concentrated on computational studies of mechanism in organometallic chemistry in catalysis
近期论文
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2016 Ariafard A, Ghari H, Khaledi Y, Bagi AH, Wierenga TS, et al., 'Theoretical investigation into the mechanism of cyanomethylation of aldehydes catalyzed by a nickel pincer complex in the absence of base additives', ACS Catalysis, 6, (1) pp. 60-68. ISSN 2155-5435 (2016) [Refereed Article]DOI: 10.1021/acscatal.5b01642 [eCite] [Details]Citations: Web of Science - 1Co-authors: Ariafard A; Wierenga TS; Gardiner MG
2015 Canty AJ, Ariafard A, Yates BF, Sanford MS, 'Computational study of intramolecular arene palladation at a palladium(IV) center', Organometallics, 34, (6) pp. 1085-1090. ISSN 0276-7333 (2015) [Refereed Article]DOI: 10.1021/om5013049 [eCite] [Details]Citations: Scopus - 5Web of Science - 5Co-authors: Ariafard A; Yates BF
2015 Vikse KL, Zavras A, Thomas TH, Ariafard A, Khairallah GN, et al., 'Prying open a reactive site for allylic arylation by phosphine-ligated geminally diaurated aryl complexes', Organometallics, 34, (13) pp. 3255-3263. ISSN 0276-7333 (2015) [Refereed Article]DOI: 10.1021/acs.organomet.5b00287 [eCite] [Details]Citations: Scopus - 1Web of Science - 1Co-authors: Ariafard A; Yates BF