个人简介

2011-present Assistant Professor, University of Notre Dame 2008-2011 Postdoctoral Fellow, California Institute of Technology 2009 Ph.D. in Chemistry, University of Chicago 2003 M.S. in Chemistry, The University of Chicago 2000 B. S. in Chemical Engineering, University Politehnica of Bucharest, Romania Award: 2008-2011 BP Postdoctoral Fellowship 2002-2004 McCormick Graduate Fellowship

研究领域

Inorganic Chemistry

The Iluc research group focuses on the activation and functionalization of inert molecules, with an emphasis on C–H bonds. These are imperative scientific problems since less expensive and more readily available feedstocks could be employed to meet some of today's energy demands.The approach used by the Iluc group is the design of metal complexes that take advantage of latent reactivity: either electrophilic metal centers protected by weak interactions with a supporting ligand or that arising from metal-ligand cooperation. The group will span synthesis, characterization, and mechanistic studies with an emphasis on the understanding of reactivity and design of new catalytic cycles.

近期论文

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Frustrated Lewis Pair-Like Reactions of Nucleophilic Palladium Carbenes with B(C6F5)3 Peng Cui, Cezar C. Comanescu and Vlad M. Iluc Chemical Communications - March 3, 2015 Chem. Commun. 2015, 51, 6206-6209. Ag(I) and Tl(I) Precursors as Transfer Agents of a Pyrrole-based Pincer Ligand to Late Transition Metals Julie A. Kessler and Vlad M. Iluc Inorganic Chemistry - November 11, 2014 Inorg. Chem. 2014, 53 (23), 12360-12371. Synthesis and Reactivity of a Nucleophilic Palladium(II) Carbene Cezar C. Comanescu and Vlad M. Iluc Organometallics - October 07, 2014 Organometallics 2014, 33 (21), 6059–6064. Flexible Coordination of Diphosphine Ligands Leading to cis and trans Pd(0), Pd(II), and Rh(I) Complexes Cezar C. Comanescu and Vlad M. Iluc Inorganic Chemistry - August 07, 2014 Inorg. Chem. 2014, 53 (16), 8517-8528. Coordination of a Hemilabile Pincer Ligand with an Olefinic Backbone to Mid-to-Late Transition Metals Brittany J. Barrett and Vlad M. Iluc Inorganic Chemistry - June 24, 2014 Inorg. Chem. 2014, 53 (14), 7248-7259. Group 10 Metal Complexes Supported by a Pincer Ligand with an Olefinic Backbone Brittany J. Barrett and Vlad M. Iluc Organometallics - May 13, 2014 Organometallics 2014, 33 (10), 2565-2574. Undergraduate, Graduate, and Postdoctoral Work Mindiola, Daniel J.; Waterman, Rory; Iluc, Vlad M.; Cundary, Thomas R.; Hillhouse, Gregory L. "Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand." Inorganic Chemistry 2014, 53(24), 13227-13238. Iluc, Vlad M.; Hillhouse, Gregory L. "Three-Coordinate Nickel Carbene Complexes and Their One-Electron Oxidation Products" Journal of the American Chemical Society 2014, 136(17), 6479-6488. Laskowski, Carl A.; Bungum, Donald J.; Baldwin Steven M.; Del Ciello, Sarah A.; Iluc, Vlad M.; Hillhouse, Gregory L. "Synthesis and Reactivity of Two-Coordinate Ni(I) Alkyl and Aryl Complexes" Journal of the American Chemical Society 2013, 135(49), 18272-18275. Iluc, Vlad M.; Fedorov, Alexey; Grubbs, Robert H. "H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex" Organometallics 2012, 31(1), 39-41. Iluc, Vlad M.; Miller, Alexander J. M.; Anderson, John S.; Monreal, Marsia J.; Mehn, Mark P.; Hillhouse, Gregory L. "Synthesis and Characterization of Three-Coordinate Ni(III)-Imide Complexes" Journal of the American Chemical Society 2011, 133(33), 13055–13063. Iluc, Vlad M.; Hillhouse, Gregory L. "Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands" Journal of the American Chemical Society 2010, 132(43), 15148–15150. Anderson, John S.; Iluc, Vlad M.; Hillhouse, Gregory L. "Reactions of CO2 and CS2 with 1,2-Bis(di-tert-butyl-phosphino)-ethane complexes of Nickel(0) and Nickel(I)" Inorganic Chemistry 2010, 49(21), 10203–10207. Iluc, Vlad M.; Hillhouse, Gregory L. "Arrested 1,2-Hydrogen Migration from Silicon to Nickel upon Oxidation of a Three-Coordinate Ni(I) Silyl Complex" Journal of the American Chemical Society 2010, 132(34), 11890-11892. Iluc, Vlad M.; Laskowski, Carl A.; Brozek, Carl K. Harrold, Nicole D.; Hillhouse, Gregory L. "Monomeric and Dimeric Disulfide Complexes of Nickel(II)" Inorganic Chemistry 2010, 49(15), 6817-6819. Iluc, Vlad M.; Laskowski, Carl A.; Hillhouse, Gregory L. Synthesis of Bis(phosphine) and N-Heterocyclic Carbene Supported α-Diazoalkyl Complexes of Copper(I)" Organometallics 2009, 28(20), 6135-6138. Iluc, Vlad M.; Hillhouse, Gregory L. "Snapshots of the oxidative-addition process of silanes to nickel(0)" Tetrahedron 2006, 62(32), 7577-7582. Iluc, Vlad M.; Miller, Alexander J. M.; Hillhouse, Gregory L. "Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel" Chemical Communications 2005, 40, 5091-5093. Guran, Cornelia; Barboiu, Mihai; Diaconescu, Paula; Iluc, Vlad; Stan, Claudiu "Mono and polynuclear complexes of Cr(III) with dichloro-tetramorpholino-cyclotriphosphazatriene" Revue Roumaine de Chimie 2000, 44(9), 917-921. Guran, Cornelia; Diaconescu, Paula; Barboiu, Mihai; Iluc, Vlad; Stan, Claudiu "Heteropolynuclear complex precursors used in mixed oxide synthesis" British Ceramic Proceedings 2000, 61, 33-39.