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研究领域

Solid-state oxide chemistry Magnetism Ionic conductivity Neutron scattering Phase transitions Modulated structures The goal of our research is the discovery, characterisation and optimisation of functional solid-state materials. We take a “crystal chemical” approach whereby we try to relate the crystal structure of a material to its chemical composition on the one hand, and to its physical properties on the other. Structural characterisation therefore plays a central role, and we make particularly heavy use of neutron, synchrotron X-ray and electron diffraction as well as complementary techniques such as spectroscopy and high-resolution electron microscopy. Structural information is used to guide our exploratory synthetic studies and to interpret our physical property measurements. Most of our current projects fall into one of the following categories: solid-state ionic conductors for fuel cell and battery applications; frustrated and low-dimensional magnetism; diffuse scattering and nanoscale structure in functional materials such as ferroelectrics; naturally layered multi-functional materials, especially magnetoresistors and multiferroics; and the crystallography and physical properties (such as thermoelectricity or non-linear optics) of modulated structures in up to six-dimensional superspace. We have a comprehensive set of facilities for materials synthesis and characterisation, including Australia’s first IR floating-zone image furnace for the synthesis of centimetre-scale single crystals of high melting-point (up to 2200 ºC) oxides, nitrides and intermetallics. We have two new X-ray powder diffractometers with excellent in situ (controlled temperature and atmosphere) capabilities and a Physical Properties Measurement System, all of which are dedicated to materials chemistry research in the School. At ANSTO we have access to a wide range of physical property characterisation facilities in the Institute for Materials Engineering. Most significantly, we make extensive use of the neutron scattering facilities at the new OPAL research reactor, notably: the single-crystal quasi-Laue diffractometer KOALA; the powder diffractometers WOMBAT and ECHIDNA; and the inelastic scattering instruments TAIPAN, SIKA and PELICAN. The ready availability of these world class facilities in Sydney, along with the X-ray scattering facilities at the Australian Synchrotron in Melbourne, allows us to pursue almost any problem in modern materials science.

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Liu, S., Avdeev, M., Liu, Y., Johnson, M., Ling, C. (2016). A new n = 4 layered Ruddlesden-Popper phase K2.5Bi2.5Ti4O13 showing stoichiometric hydration. Inorganic Chemistry, 55(4), 1403-1411. [More Information] Blanchard, P., Chapman, K., Heald, S., Zbiri, M., Johnson, M., Kennedy, B., Ling, C. (2016). Direct observation of pressure-driven valence electron transfer in Ba₃BiRu₂O₉, Ba₃Bilr₂O₉, and Ba₄Bilr₃O1₂. Inorganic Chemistry, 55(11), 5649-5654. [More Information] Dwibedi, D., Ling, C., Araujo, R., Chakraborty, S., Duraisamy, S., Munichandraiah, N., Ahuja, R., Barpanda, P. (2016). Ionothermal synthesis of high-voltage Alluaudite Na2+2xFe2-x(SO4)3 sodium insertion compound: Structural, electronic, and magnetic insights. ACS Applied Materials and Interfaces, 8(11), 6982-6991. [More Information] Tian, R., Kearley, G., Yu, D., Ling, C., Pham, A., Embs, J., Shoko, E., Li, S. (2016). Phononic structure engineering: the realization of Einstein rattling in calcium cobaltate for the suppression of thermal conductivity. Open Access Scientific Reports, 6(30530), 1-10. [More Information] Liu, W., Gonzalez, B., Dunstan, M., Sultan, D., Pavan, A., Ling, C., Grey, C., Dennis, J. (2016). Structural evolution in synthetic, Ca-based sorbents for carbon capture. Chemical Engineering Science, 139, 15-26. [More Information] Allison, M., Avdeev, M., Schmid, S., Liu, S., Sohnel, T., Ling, C. (2016). Synthesis, structure and geometrically frustrated magnetism of the layered oxide-stannide compounds Fe(Fe3-xMnx)Si2Sn7O16. Dalton Transactions, 45(23), 9689-9694. [More Information] Wang, C., Avdeev, M., Kennedy, B., Kupers, M., Ling, C. (2016). YCa3(CrO)3(BO3)4: A Cr3+ kagome lattice compound showing no magnetic order down to 2 K. Inorganic Chemistry, 55(15), 7535-7541. [More Information] Wong, Y., Avdeev, M., Ling, C. (2016). Zig-zag magnetic ordering in honeycomb-layered Na3Co2SbO6. Journal of Solid State Chemistry, 243, 18-22. [More Information] Berlie, A., Kearley, G., Liu, Y., Yu, D., Mole, R., Ling, C., Withers, R. (2015). Energy and temperature dependence of rigid unit modes in AlPO4-5. Physical Chemistry Chemical Physics, 17(33), 21547-21554. [More Information] Liu, S., Blanchard, P., Zhang, Z., Kennedy, B., Ling, C. (2015). Long- and short-range structure studies of KBT-KBZ solid-solutions using synchrotron radiation. Dalton Transactions, 44(23), 10681-10688. [More Information] Auckett, J., McIntyre, G., Avdeev, M., De Bruyn, H., Tan, T., Li, S., Ling, C. (2015). Neutron Laue diffraction study of the complex low-temperature magnetic behaviour of brownmillerite-type Ca2Fe2O5. Journal of Applied Crystallography, 48(1), 273-279. [More Information] Yahia, H., Shikano, M., Gaudin, E., Avdeev, M., Ling, C. (2015). Single crystal and magnetic structures of maricite-type AgMnVO4. Journal of Solid State Chemistry, 221, 306-310. [More Information] Choi, S., Ling, C. (2015). The AONSA Prize 2015. Neutron News, 26(1), 40. [More Information] Wind, J., Auckett, J., Withers, R., Piltz, R., Maljuk, A., Ling, C. (2015). Type II Bi1-xWxO1.5+1.5x: a (3 + 3)-dimensional commensurate modulation that stabilizes the fast-ion conducting delta phase of bismuth oxide. Acta Crystallographica Section B: Structural Science, B71(6), 679-687. [More Information] Blanchard, P., Reynolds, E., Kennedy, B., Ling, C., Zhang, Z., Thorogood, G., Cowie, B., Thomsen, L. (2014). An unconventional method for measuring the Tc L3-edge of technetium compounds. Journal of Synchrotron Radiation, 21(6), 1275-1281. [More Information] Auckett, J., Ling, C. (2014). Comment on "structural and Mössbauer study of the brownmillerite oxides LaSrMn2-xFexO5 (0 less than or equal to x less than or equal to 0.5)". Journal of Alloys and Compounds, 610, 212-213. [More Information] Aughterson, R., Lumpkin, G., de los Reyes, M., Sharma, N., Ling, C., Gault, B., Smith, K., Avdeev, M., Cairney, J. (2014). Crystal structures of orthorhombic, hexagonal, and cubic compounds of the Sm(x)Yb(2-x)TiO5 series. Journal of Solid State Chemistry, 213, 182-192. [More Information] Zhou, Q., Blanchard, P., Kennedy, B., Ling, C., Liu, S., Avdeev, M., Aitken, J., Tadich, A., Brand, H. (2014). Diffraction and spectroscopic study of pyrochlores Bi(2-x)Fe(1+x)SbO7. Journal of Alloys and Compounds, 589, 425-430. [More Information] Blanchard, P., Huang, Z., Kennedy, B., Liu, S., Miiller, W., Reynolds, E., Zhou, Q., Avdeev, M., Zhang, Z., Aitken, J., Ling, C., et al (2014). Key Role of Bismuth in the Magnetoelastic Transitions of Ba3Bilr2O9 and Ba3BiRu2O9 as Revealed by Chemical Doping. Inorganic Chemistry, 53(2), 952-960. [More Information] Barpanda, P., Oyama, G., Ling, C., Yamada, A. (2014). Krohnkite-Type Na2Fe(SO4)2.2H2O as a Novel 3.25 V Insertion Compound for Na-Ion Batteries. Chemistry of Materials, 26(3), 1297-1299. [More Information]

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