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研究领域

Controlled radical polymerization allows a control of polymer and nanoparticle architecture that was previously only dreamt of. Reversible addition fragmentation chain transfer (RAFT) is the most versatile of the currently available controlled radical processes. We exploit this new capability in our research to design and synthesize polymer particles and composite nanoparticles for a wide range of applications. 1. Disperse phase polymerization: RAFT controlled radical polymerization Emulsion polymerization kinetics and mechanisms Preparation of composite nanoparticles. 2. Biomedical applications of magnetic nanoparticles: Hyperthermia treatment of cancer Targeted drug delivery Medical Imaging. 3. Stabilization and rheological control of concentrated emulsions. 4. Improving the efficacy and performance of agrochemical actives. 5. Conducting collaborative projects with industry. 6. Ionic liquid ferrofluids for aerospace applications.

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Scarratt, L., Hoatson, B., Wood, E., Hawkett, B., Neto, C. (2016). Durable superhydrophobic surfaces via spontaneous wrinkling of Teflon AF. ACS Applied Materials and Interfaces, 8(10), 6743-6750. [More Information] Poon, C., Tang, O., Chen, X., Pham, B., Gody, G., Pollock, C., Hawkett, B., Perrier, S. (2016). Preparation of inert polystyrene latex particles as microRNA delivery vectors by surfactant-free RAFT emulsion polymerization. Biomacromolecules, 17(3), 965-973. [More Information] Telford, A., Easton, C., Hawkett, B., Neto, C. (2016). Waterborne, all-polymeric, colloidal 'raspberry' particles with controllable hydrophobicity and water droplet adhesion properties. Thin Solid Films, 603, 69-74. [More Information] Polikarpov, M., Cherepanov, V., Chuev, M., Gabbasov, R., Mischenko, I., Jain, N., Jones, S., Hawkett, B., Panchenko, V. (2015). Mössbauer evaluation of the interparticle magnetic interactions within the magnetic hyperthermia beads. Journal of Magnetism and Magnetic Materials, 380, 347-352. [More Information] Huynh, V., Nguyen, D., Such, C., Hawkett, B. (2015). Polymer coating of graphene oxide via reversible addition-fragmentation chain transfer mediated emulsion polymerization. Journal of Polymer Science, Part A: Polymer Chemistry, 53(12), 1413-1421. [More Information] Priyananda, P., Djerdjev, A., Gore, J., Neto, C., Beattie, J., Hawkett, B. (2015). Premature detonation of an NH4NO3 emulsion in reactive ground. Journal of Hazardous Materials, 283, 314-320. [More Information] Pham, B., Such, C., Hawkett, B. (2015). Synthesis of polymeric janus nanoparticles and their application in surfactant-free emulsion polymerizations. Polymer Chemistry, 6(3), 426-435. [More Information] Pham, B., Jain, N., Kuchel, P., Chapman, B., Bickley, S., Jones, S., Hawkett, B. (2015). The interaction of sterically stabilized magnetic nanoparticles with fresh human red blood cells. International Journal of Nanomedicine, 10(1), 6645-6655. [More Information] Jain, N., Liu, C., Hawkett, B., Warr, G., Hamilton, W. (2014). Application of small-angle neutron scattering to the study of forces between magnetically chained monodisperse ferrofluid emulsion droplets. Journal of Applied Crystallography, 47(1), 41-52. [More Information] Ghasemi, S., Darestani Farahani, M., Abdollahi, Z., Hawkett, B., Gomes, V. (2014). Electrical impedance spectroscopy for determining critical micelle concentration of ionic emulsifiers. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 441, 195-203. [More Information] King, L., Meyer, E., Hopkins, M., Hawkett, B., Jain, N. (2014). Self-Assembling Array of Magnetoelectrostatic Jets from the Surface of a Superparamagnetic Ionic Liquid. Langmuir: the ACS journal of surfaces and colloids, 30(47), 14143-14150. [More Information] Eamegdool, S., Weible, M., Pham, B., Hawkett, B., Grieve, S., Chan-Ling, T. (2014). Ultrasmall superparamagnetic iron oxide nanoparticle prelabelling of human neural precursor cells. Biomaterials, 35(21), 5549-5564. [More Information] Telford, A., Pham, B., Neto, C., Hawkett, B. (2013). Micron-sized polystyrene particles by surfactant-free emulsion polymerization in air: Synthesis and mechanism. Journal of Polymer Science, Part A: Polymer Chemistry, 51(19), 3997-4002. [More Information] Telford, A., Hawkett, B., Such, C., Neto, C. (2013). Mimicking the wettability of the rose petal using self-assembly of waterborne polymer particles. Chemistry of Materials, 25(17), 3472-3479. [More Information] Heinen (O'Donnell), J., Blom, A., Hawkett, B., Warr, G. (2013). Phase behavior of amphiphilic diblock co-oligomers with nonionic and ionic hydrophilic groups. The Journal of Physical Chemistry Part B, 117(10), 3005-3018. [More Information] Nguyen, D., Such, C., Hawkett, B. (2013). Polymer coating of carboxylic acid functionalized multiwalled carbon nanotubes via reversible addition-fragmentation chain transfer mediated emulsion polymerization. Journal of Polymer Science, Part A: Polymer Chemistry, 51(2), 250-257. [More Information] Bryce, N., Pham, B., Fong, N., Jain, N., Pan, E., Whan, R., Hambley, T., Hawkett, B. (2013). The composition and end-group functionality of sterically stabilized nanoparticles enhances the effectiveness of co-administered cytotoxins. Biomaterials Science, 1(12), 1260-1272. [More Information] Siauw, M., Fitzgerald, P., Hawkett, B., Perrier, S. (2013). Thermoresponsive behavior of amphiphilic diblock co-oligomers of ethylene glycol and styrene in aqueous solution. Soft Matter, 9(29), 7007-7015. [More Information] Nguyen, D., Such, C., Hawkett, B. (2012). Polymer-TiO 2 composite nanorattles via RAFT-mediated emulsion polymerization. Journal of Polymer Science, Part A: Polymer Chemistry, 50(2), 346-352. [More Information] Siauw, M., Hawkett, B., Perrier, S. (2012). Short chain amphiphilic diblock co-oligomers via RAFT polymerization. Journal of Polymer Science, Part A: Polymer Chemistry, 50(1), 187-198. [More Information]

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