Kingston, Jesudoss - IOWA State University

个人简介

Jesudoss Kingston, lecturer, received his B.S. and M.S. from The American College, Madurai, Tamilnadu, India (1988-1993) and Ph.D. in organosilicon chemistry from the Indian Institute of Technology Madras, Chennai, India in 1999. He spent two year as a postdoctoral fellow at the Ben Gurion University of the Negev, Israel under the guidance of Prof. Daniel Kost focusing mainly on the stereodynamics and reactivity of penta- and hexa-coordinated organosilicon compounds. Following another two years of postdoctoral work at the University of Kentucky with Prof. Folami Ladipo in the area of well-defined low-valent organotitanium compounds, he accepted the postdoctoral fellowship from Iowa State University to work in the research group of Prof. John G. Verkade, the University Professor at the chemistry department where he developed the chemistry of proazaphosphatranes and their novel ionic derivatives for catalyzing organic transformations. Dr. Kingston has joined the Department of Chemistry as a lecturer since Fall 2007. His professional memberships includes American Chemical Society and Sigma-Xi. Not Accepting Students

研究领域

General Chemistry/Organometallics - Synthesis and Catalysis

近期论文

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Synthesis and characterization of R2PN=P(iBuNCH2CH2)3N: A new bulky electron-rich phosphine for efficient Pd-assisted Suzuki-Mityaura cross-coupling reactions. Jesudoss V. Kingston, John G. Verkade Journal of Organic Chemistry, 2007, 72, 2816. 3/2 Order chain kinetics involving a postulated dicationic intermediate in the isomerization of a P-isocyano to P-cyano azaphosphatrane monocation. Jesudoss V. Kingston, John G. Verkade, James H. Espenson Journal of the American Chemical Society, 2005,127, 15006. P[N(iBu)CH2CH2]3N: A versatile non-ionic base for the synthesis of higher coordinate silicates. Jesudoss V. Kingston, John, G. Verkade Inorganic Chemistry Communications, 2005, 8, 643. A stable structurally characterized phosphorus-bound isocyanide and its thermal and catalyzed isomerization to the corresponding cyanide. Jesudoss V. Kingston, Arkady Ellern, John, G. Verkade Angewandte Chemie International Edition, 2005, 44, 4960. Reductive coupling of [(RO)2Ti(L2)2] complexes containing a chelating bis(aryloxide ligand with ketones (L2 = bpy, dmbpy or phen). clear="none"/> David Owiny, Jesudoss V. Kingston, Mark Maynor, Sean Parkin, Jeff W. Kampf, Folami T. Ladipo Organometallics, 2005, 24, 3995. Dianionic silicate derivatives of transition metals: synthesis by a facile ion exchange route, characterization and thermolysis studies. P. Bindu, J.V. Kingston, M.N. Sudheendra Rao Polyhedron, 2004, 23, 679. Novel pentacoordinate siliconium complexes stabilized by oxygen and nitrogen donors: Highly sensitive and unusual equilibrium between ionic penta- and neutral hexacoordinate compounds. Inna Kalikhman, Vijeyakumar Kingston, Sonia Krivonos, Daniel Kost Organosilicon chemistry V, From Molecules to Materials, Eds.: N. Auner and J. Weis., VCH-Wiley, Weinheim, September 2003, 55. Binuclear ethylene bridged silicon chelates: Equilibrium between neutral hexacoordinate and ionic pentacoordinate siliconium complexes. Inna Kalikhman, Vijeyakumar Kingston, Daniel Kost Organoslilicon chemistry V, From Molelcules to Materials, Eds.: N. Auner and J. Weis., VCH-Wiley, Weinheim, September 2003, 61. Synthesis and reactivity of [(DMSC)Ti(2-OCAr2)L2] complexes (DMSC = Dimethylsilyl-bridged p-tert-butylcalix[4]arene dianion, Ar = Aryl Group, and L2 = Delocalized diimine). Jesudoss V. Kingston, Vallipuram Sarveswaran, Sean Parkin, Folami T. Ladipo Organometallics, 2003, 22, 136. Mechanistic insight into fragmentation reactions of titanapinacolate complexes. Jesudoss V. Kingston, Oleg V. Ozerov, Sean Parkin, Carolyn P. Brock, Folami T. Ladipo Journal of the American Chemical Society, 2002, 124, 12217. Donor-stabilized silyl cations. 5. Comparison between mono- and binuclear siliconium chelates. Inna Kalikhman, Vijeyakumar Kingston, Boris Gostevskii, Vadim Pestunovich, Dietmar Stalke, Bernard Walfort, Daniel Kost Organometallics, 2002, 21, 4468. Donor-stabilized silyl cations. 3. Ionic dissociation of hexacoordinate silicon complexes to pentacoordinate siliconium salts driven by ion solvation. Daniel Kost, Vijeyakumar Kingston, Boris Gostevskii, Arkady Ellern, Dietmar Stalke, Bernard Walfort, Inna Kalikhman Organometallics, 2002, 21, 2293. Low-temperature ionization of neutral hexacoordinate to ionic pentacoordinate silicon complexes: Unusual temperature, solvent and substituent effects. Daniel Kost, Inna Kalikhman, Vijeyakumar Kingston, Boris Gostevskii. Journal of Physical Organic Chemistry, 2002, 15, 831. Neutral hexacoordinate silicon tris-chelates: Structure and stereodynamics. Inna Kalikhman, Vijeyakumar Kingston, Olga Girshberg, Daniel Kost Organometallics, 2001, 20, 4713. Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation-recombination of the Si-Cl bond. Vijeyakumar Kingston, Boris Gostevskii, Inna Kalikhman, Daniel Kost Journal of Chemical Society, Chemical Communications, 2001, 14, 1272. Synthesis and characterization of tris(catecholato) silicates, [(C6H4O2)3Si]2 with different counter cations - First pyrolysis study and X-ray structure of [{(CH3)2CH}2NH2 ]2-[(C6H4O2)3Si].2CH3CN.H 2O. J.V. Kingston, Babu Vargheese, M.N. Sudheendra Rao Main Group Chem., 2000, 3, 79-90. High yield synthesis of cyclic phosphites, phosphates, sulphites and sulphates of catechol and glycol mediated by hypervalent silicon centers. J.V. Kingston, M.N. Sudheendra Rao Tetrahedron Letters, 1997, 38, 4841.