Sadow, Aaron D - IOWA State University - Department of Chemistry

个人简介

Professor Department of Chemistry, Iowa State University 2016–present Director Center for Catalysis, Iowa State University 2012–present Associate Professor Department of Chemistry, Iowa State University 2011–2016 Faculty Scientist Ames Laboratory, Iowa State University 2010–present Assistant Professor Department of Chemistry, Iowa State University 2005–2011

研究领域

Our chemistry projects are focused on catalytic chemistry, with applications ranging from energy-related conversions to green chemistry approaches for high-value chemical synthesis. Students in the Sadow group learn synthetic organometallic chemistry, catalytic methodology, and kinetics and mechanism. These skills are applied in new catalytic asymmetric hydroamination, hydrosilylation and hydroboration, polymerization, and cross-coupling reactions and new understandings of catalytic conversions.

近期论文

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Wu, X.; Tennakoon, A.; Yappert, R.; Esveld, M.; Ferrandon, M. S.; Hackler, R. A.; LaPointe, A. M.; Heyden, A.; Delferro, M.; Peters, B.; Sadow, A. D.; Huang, W., Size-Controlled Nanoparticles Embedded in a Mesoporous Architecture Leading to Efficient and Selective Hydrogenolysis of Polyolefins. J. Am. Chem. Soc. 2022, 144, 5323-5334. DOI:10.1021/jacs.1c11694 Li, Y.; Kanbur, U.; Cui, J.; Wang, G.; Kobayashi, T.; Sadow, A. D.; Qi, L. "Supported Lanthanum Borohydride Catalyzes CH Borylation Inside Zeolite Micropores" Angew. Chem. Int. Ed. 2022, Early View. DOI:10.1002/anie.202117394 Chu, Y.-Y.; Lolinco, A.; Eedugurala, N.; Ellern, A.; Windus, T. W.; Sadow, A. D. "Reversible Ligand Protonation in Non-innocent Constrained-Geometry-like Group 4 Complexes" Organometallics, 2022, 41, 141-154. DOI:10.1021/acs.organomet.1c00612 Chatterjee, P.; Wang, H.; Manzano, J. S.; Kanbur, U.; Sadow, A. D.; Slowing, I. I.*, Surface ligands enhance the catalytic activity of supported Au nanoparticles for the aerobic α-oxidation of amines to amides. Catal. Sci. Technol. 2022, 12, 1922-1933. DOI:10.1039/D1CY02121D Perras, F. A.;* Kanbur, U.; Paterson, A. L.; Chatterjee, P.; Slowing, I. I. Sadow, A. D. "Determining the Three-Dimensional Structures of Silica-Supported Metal Complexes from the Ground Up" Inorg. Chem. 2022, 61, 1067-1078. DOI:10.1021/acs.inorgchem.1c03200 Basemann, K.; Schmidt, B. M.; Sadow, A. D. "Substituent-enhanced Intermolecular Catalytic Ene-yne Metathesis for Efficient 1,3-Diene Synthesis" ACS Catal. 2022, 12, 226-235. DOI:10.1021/acscatal.1c04074 Hackler, R. A;. Vyavhare, K.; Kennedy, R. M.; Celik, G.; Kanbur, U.; Griffin, P. J.; Sadow, A. D.; Zang, G.; Elgowainy, A.; Sun, P. Poeppelmeier, K. R.; Erdemir, A.; Delferro, M.*, “Synthetic Lubricants Derived from Plastic Waste and their Tribological Performance.” ChemSusChem 2021, 14, 4181-4189. DOI:10.1002/cssc.202100912 Patnaik, S.; Kanbur, U.; Ellern, A.; Sadow, A. D., “Hydrosilane σ-Adduct Intermediates in Mechanistically Rich Zinc-Catalyzed Cross-Dehydrocoupling of Silanes and Alcohols.” Chem. Eur. J. 2021, 27, 10428-10436. DOI:10.1002/chem.202101146 Kanbur, U.; Zang, G.; Paterson, A. L.; Chatterjee, P.; Hackler, R. A.; Delferro, M.; Slowing, I. I.; Perras, F. A.; Sun, P.; Sadow A. D., “Catalytic Carbon-Carbon Bond Cleavage and Carbon-Element Bond Formation Gives New Life for Polyolefins as Biodegradable Surfactants.” Chem 2021, 7, 1347-1362. DOI:10.1016/j.chempr.2021.03.007 Boteju, K.; Venkatesh, A.; Wan, S.; Ellern, A.; Rossini, A. J.; Sadow, A. D. "Ancillary Steric Effects on the Activation of SiH Bonds in Arylsilazido Rare Earth Compounds" Organometallics, 2021, 40, 1654-1669. DOI:10.1021/acs.organomet.1c00162 Eedugurala, N.; Wang, Z.; Kanbur, U.; Ellern, A.; Pruski, M.; Sadow, A. D., “Synthesis and Characterization of Tris(oxazolinyl)borato Copper(II) and Copper(I) Complexes.” Helv. Chim. Acta 2021, 104, e2000209. DOI:10.1002/hlca.202000209 Paterson, A. L.; Liu, D.-J.; Kanbur, U.; Sadow, A. D.; Perras, F. A.*, “Observing the three-dimensional dynamics of supported metal complexes.” Inorg. Chem. Front. 2021, 3, 893-901. DOI:10.1039/D0QI01241F Tennakoon, A.; Wu, X.; Paterson, A. L.; Patnaik, S.; Pei, Y.; LaPointe, A. M.; Ammal, S. C.; Hackler, R. A.; Heyden, A.; Slowing, I. I.; Coates, G. W.; Delferro, M.; Peters, B.; Huang, W.; Sadow, A. D.; Perras, F. A., “Catalytic Upcycling of High-Density Polyethylene Via a Processive Mechanism.” Nature Catalysis 2020, 3, 893-901. DOI:10.1038/s41929-020-00519-4 Zhou, H.; Wang, H.; Perras, F. A.; Naik, P.; Pruski, M.; Sadow, A. D.; Slowing, I. I., “Two-step conversion of Kraft lignin to nylon precursors under mild conditions.” Green Chem. 2020, 22, 4676-4682. DOI:10.1039/D0GC01220C Luo, Z.; Nie, R.; Nguyen, V. T.; Biswas, A.; Behera, R. K.; Wu, X.; Kobayashi, T.; Sadow, A.; Wang, B.; Huang, W.; Qi, L.*, “Transition metal-like carbocatalyst.” Nature Communications 2020, 11, 4091. DOI:10.1038/s41467-020-17909-8 Zhou, H.; Wang, H.; Sadow, A. D.; Slowing, I. I., “Toward Hydrogen Economy: Selective Guaiacol Hydrogenolysis under Ambient Hydrogen Pressure.” Applied Catalysis B: Environmental 2020, 270, 118890-118899. DOI:10.1016/j.apcatb.2020.118890 Sadow, A. D., “Alkali and Alkaline Earth Element-Catalyzed Hydroboration Reactions.” In Early Main Group Metal Catalysis 2020, pp. 201-224. DOI:10.1002/9783527818020.ch8 Kanbur, U.; Sadow, A. D., “Rare Earth Catalyzed C–H Bond Alumination of Terminal Alkynes.” Chem. Eur. J. 2020, 26, 5479-5493. DOI:10.1002/chem.202000325 Wang, Z.; Patnaik, S.; Eedugurala, N.; Manzano, J. S.; Slowing, I. I.; Kobayashi, T.; Sadow, A. D.; Pruski, M., “Silica-supported Organolanthanum Catalysts for C–O Bond Cleavage in Epoxides.” J. Am. Chem. Soc. 2020, 142, 2935-2947. DOI:10.1021/jacs.9b11606 Celik, G.; Kennedy, R. M.; Hackler, R. A.; Ferrandon, M.; Tennakoon, A.; Patnaik, S.; LaPointe, A. M.; Ammal, S. C.; Heyden, A.; Perras, F. A.; Pruski, M.; Scott, S. L.; Poeppelmeier, K. R.; Sadow, A. D.; Delferro, M., “Upcycling Single-Use Polyethylene into High-Quality Liquid Products.” ACS Central Science 2019, 5, 1795-1803. DOI:10.1021/acscentsci.9b00722