Lu, Connie C - University of Minnesota Twin Cities

个人简介

B.S. Massachusetts Institute of Technology, 2000 Ph.D. California Institute of Technology, 2006 Post Doctorate Max Planck Institute for Bioinorganic Chemistry, 2009 Honors and Awards Gerhard and Lisolette Closs Memorial Lecture, University of Chicago, 2016 Kavli Fellow, 2013 Alfred P. Sloan Research Fellow, 2013-2015 National Science Foundation CAREER Award, 2013 Ernst Haage Prize, 2008 Alexander von Humboldt Post-doctoral Fellowship, 2007-2008 Department of Defense Pre-doctoral Fellowship, 2001-2004 Alpha Chi Sigma Award, 2000 Phi Beta Kappa, 2000

研究领域

The Lu group creates and studies metal-metal bonding between two first-row transition metals and between a transition metal and a main group metal. Synergistic combinations of different metals can generate hybrid "metals" that exhibit original properties and/or unique reactivities. We are broadly interested in developing these bimetallic complexes for small-molecule catalysis (e.g. dinitrogen to amine), where using non-precious metals is sensible from economical and sustainability standpoints.

近期论文

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Vollmer, M. V.†; Xie, J.†; Cammarota, R. C.; Young, Jr, V. G.; Bill, E.*; Gagliardi, L.*; Lu, C. C.* “Formal Nickelate(−I) Complexes Supported by Group 13 Ions: Where are the Valence Electrons?” Angew. Chem. Int. Ed. Engl. 2018, in press. Ye, J.*; Cammarota, R. C.; Xie, J.; Vollmer, M. V.; Truhlar, D. G.; Cramer, C. J.; Lu, C. C.*; Gagliardi, L.* “Rationalizing the Reactivity of Bimetallic Molecular Catalysts for CO2 Hydrogenation.” ACS Catal. 2018, 8, 4955-4968. Nickel-gallium catalyst Webber, T. E.; Liu, W.-G.; Desai, S. P.; Lu, C. C., Truhlar, D. G.; Penn, R. L.* “Role of a Modulator in the Synthesis of Phase-Pure NU-1000.” ACS Appl. Mater. Interfaces, 2017, 9, 39342–39346. Cammarota, R. C.; Vollmer, M. V.; Xie, J.; Ye, J.; Linehan, J. C.; Burgess, S. A.; Appel, A. M.; Gagliardi, L.; Lu, C. C.* “A Bimetallic Nickel-Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride.” J. Am. Chem. Soc., 2017, 139, 14244-14250. Vollmer, M. V.; Xie, J.; Lu, C. C.* “ Stable Dihydrogen Complexes of Cobalt(-I) Suggest an Inverse trans-Influence of Lewis Acidic Group 13 Metalloligands.” J. Am. Chem. Soc. 2017, 139, 6570-6573. Desai, S. P.†; Malonzo, C. D.†; Webber, T.; Duan, J.; Thompson, A. B.; Tereniak, S. J.; DeStefano, M. R.; Buru, C. T.; Li, Z.; Penn, R. L.; Farha, O. K.; Hupp, J. T.; Stein, A.*; Lu, C. C.* “Assembly of Dicobalt and Cobalt-Aluminum Oxide Clusters on Metal-Organic Framework and Nanocast Silica Supports.” Farad. Discuss. 2017, 201, 287-302. Moore, J. T.; Smith, N. E.; Lu, C. C.* “Structure and Dynamic NMR Behavior of Rhodium Complexes Supported by Lewis Acidic Group 13 Metallatranes.” Dalton Trans. 2017, 46, 5689-5701 Miller, D. L.; Siedschlag, R. B.; Clouston, L. J.; Young, V.G., Jr.; Chen, Y.-S.; Bill, E.*; Gagliardi, L.*; Lu, C. C.* “Redox Pairs of Diiron and Iron-Cobalt Complexes with High-Spin Ground States.” Inorg. Chem. 2016, 55, 9725-9735 Thompson, A. B.; Pahls, D. R.; Bernales, V.; Gallington, L. C.; Malonzo, C. D.; Webber, T.; Tereniak, S. J.; Wang, T. C.; Desai, S. P.; Li, Z.; Kim, I. S.; Gagliardi, L.; Penn, R. L.; Chapman, K. W.; Stein, A.; Farha, O. K.; Hupp, J. T.; Martinson, A. B. F.; Lu, C. C.* “Installing Heterobimetallic Cobalt-Aluminum Single-Sites on a Metal Organic Framework Support.” Chem. Mater. 2016, 28, 6753-6762 Cammarota, R. C.*; Clouston, L. J.; Lu, C. C.* “Leveraging Molecular Metal-Support Interactions for H2 and N2 Activation.” Coord. Chem. Rev. 2017, 334, 100-111. bonding interactions Malonzo, C. D.; Shaker, S. M.; Ren, L.; Prinslow, S. D.; Platero-Prats, A. E.; Gallington, L. C.; Borycz, J.; Thompson, A. B.; Wang, T. C.; Farha, O. K.; Hupp, J. T.; Lu, C. C.; Chapman, K. W.; Myers, J. C.; Penn, R. L.; Gagliardi, L.; Tsapatsis, M.; Stein, A.* “Thermal Stabilization of Metal–Organic Framework-Derived Single-Site Catalytic Clusters through Nanocasting.” J. Am. Chem. Soc. 2016, 138, 2739-2748. Clouston, L. J.; Bernales, V.; Cammarota, R. C.; Carlson, R. K.; Bill, E.; Gagliardi, L.*; Lu, C. C.* “Heterobimetallic Complexes that Bond Vanadium to Iron, Cobalt, and Nickel.” Inorg. Chem. 2015, 54, 11669-11679. Eisenhart, R. J.; Carlson, R. K.; Clouston, L. J.; Young, V. G., Jr.; Cheng, Y.-S.; Bill, E.*; Gagliardi, L.*; Lu, C. C.* “Influence of Copper Oxidation State on the Bonding and Electronic Structure of Cobalt-Copper Complexes.” Inorg. Chem. 2015, 54, 11330-11338 Co-Cu bonds and spin states Eisenhart, R. J.; Clouston, L. J.; Lu, C. C.* “Configuring Bonds Between First-Row Transition Metals.” Acc. Chem. Res. 2015, 48, 2885-2894. Cammarota, R. C.; Lu, C. C.* “Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation.” J. Am. Chem. Soc. 2015, 137, 12486-12489 Carlson, R. K.; Odoh, S. O.; Tereniak, S. J.; Lu, C. C.; Gagliardi, L. “Can Multiconfigurational Self-Consistent Field Theory and Density Functional Theory Correctly Predict the Ground State of Metal-Metal Bonded Complexes?” J. Chem. Theory Comput. 2015, 11, 4093-4101. Eisenhart, R. J.†; Rudd, P. A.†; Planas, N.; Boyce, D. W.; Carlson, R. K.; Tolman, W. B.; Bill, E.*; Gagliardi, L.*; Lu, C. C.* “Pushing the limits of delta bonding in metal-chromium complexes with redox changes and metal swapping.” Inorg. Chem. 2015, 54, 7579-7592. Clouston, L. J.; Bernales, V.; Carlson, R. K.; Gagliardi, L.*; Lu, C. C.* “Bimetallic Cobalt-Dinitrogen Complexes: Impact of the Supporting Metal on N2 Activation.” Inorg. Chem. 2015, 54, 9263-9270 Siedschlag, R. B.; Bernales, V.; Vogiatzis, K. D.; Planas, N.; Clouston, L. J.; Bill, E.; Gagliardi, L.*; Lu, C. C.* “Catalytic Silylation of Dinitrogen with a Dicobalt Complex.” J. Am. Chem. Soc. 2015, 137, 4638-4641 Eisenhart, R. J.; Carlson, R. K.; Boyle, K. M.; Gagliardi, L.; Lu, C. C.* “Synthesis and Redox Reactivity of a Phosphine-ligated Dichromium Paddlewheel.” Inorg. Chim. Acta 2015, 424, 336-344.