个人简介
Brasted Award for Excellence in College Chemistry Teaching, 2011
CSE Taylor Distinguished Teaching Professor, 2008 -
Horace T. Morse - University of Minnesota Alumni Society Award for Distinguished Contributions to Undergraduate Education, 2005
Associate Fellow, Minnesota Supercomputer Institute, 2002-present
George Taylor -IT Alumni Society Distinguished Teaching Award, 1996
McKnight Land-Grant Professor, 1989-1992
研究领域
Chemical Physics/Environmental & Green Chemistry/Inorganic & Organometallic Chemistry/Experimental Physical Chemistry/
Work in our group lies on the interface between physical, inorganic, and atmospheric chemistry. Novel aspects of molecular structure, unusual types of bonding, and microsolvation as a driving force for chemical change are the central themes of our work. Whenever possible, we tackle these problems through the study of systems which are active, or believed to be active, in the Earth's atmosphere. This approach, therefore, allows us to blend basic physical and inorganic chemistry with topics of environmental importance.
近期论文
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Mackenzie, R. B., Timp, B. A., Mo, Y. & Leopold, K. R. Effects of a remote binding partner on the electric field and electric field gradient at an atom in a weakly bound trimer. J. Chem. Phys. 139, 034320 (2013).
Hunt, S. W., Shelley, D. L. & Leopold, K. R. Nuclear hyperfine structure in the donor–acceptor complexes (CH3)3N–BF3 and (CH3)3N–B(CH3)3. J. Mol. Spectrosc. 281, 9–12 (2012).
Leopold, K. R. Generalized equations for the inertial tensor of a weakly bound complex. J. Mol. Spectrosc. 278, 27–30 (2012).
Doran, J. L., Hon, B. & Leopold, K. R. Rotational spectrum and structure of the pyridine–CO2 van der Waals complex. J. Mol. Spectrosc. 1019, 191–195 (2012).
Timp, B. A., Doran, J. L., Iyer, S., Grabow, J.U. & Leopold, K. R. Microwave observation of 41K79Br and 41K81Br from laser-ablated potassium bromide. J. Mol. Spectrosc. 271, 20–24 (2012).
Sedo, G. & Leopold, K. R. Partial Proton Transfer in a Molecular Complex: Assessments From Both the Donor and Acceptor Points of View. J. Phys. Chem. A 115, 1787–1794 (2011).
Leopold, K. R. Hydrated Acid Clusters. Annu. Rev. Phys. Chem. 62, 327-349 (2011).
Sedo, G. & Leopold, K. R. Microwave spectrum of (CH3)3 CCN–SO3. J. Mol. Spectrosc. 262, 135-138 (2010).
Sedo, G., Doran, J. L. & Leopold, K. R. Partial proton transfer in the nitric acid trihydrate complex. J. Phys. Chem. A 113, 11301–11310 (2009).
Wu, S., Sedo, G. & Leopold, K. R. Microwave spectrum of the OD–OH2 complex: A strong deuterium isotope effect on angular momentum quenching in the hydroxyl moiety. J. Mol. Spectrosc. 253, 35–40 (2009).
Brauer, C.S., Sedo, G., Dahlke, E., Wu, S., Grumstrup, E.M., Leopold, K.R., Marshall, M.D., Leung, H.O., & Truhlar, D.G. Effects of 18O Isotopic Substitution on the Rotational Spectra and Potential Splitting in the OH−OH2 Complex: Improved Measurements for 16OH−16OH2 and 18OH−18OH2, New Measurements for the Mixed Isotopic Forms, and ab Initio Calculations of the 2A' − 2A" Energy Separation. J. Chem. Phys. 129, 104304-1-11 (2008).
Craddock, M. B., Brauer, C. S. & Leopold, K. R. Microwave Spectrum, Structure, and Internal Dynamics of the Nitric Acid Dihydrate Complex. J. Phys. Chem. A 112, 488–496 (2008).
Sedo, G., Schultz, J., & Leopold, K.R. Electric Dipole Moment of Sulfuric Acid from Fourier Transform Microwave Spectroscopy. J. Mol. Spectrosc. 251, 4-8 (2008).
Wu, S., Sedo, G., Grumstrup, E. M. & Leopold, K. R. Microwave spectra of O2–HF and O2–DF: Hyperfine interactions and global fitting with infrared data. J. Chem. Phys. 127, 204315–1-11 (2007).
Brauer, C. S., Craddock, M. B., Higgins, K. J. & Leopold, K. R. Microsolvation of a partially bonded complex by non-polar and weakly polar microsolvents: a microwave and ab initio study of HCN–SO3–Ar and HCN–SO3–CO. Molecular Physics 105, 613–625 (2007).
Brauer, C. S., Sedo, G. & Leopold, K. R. Dipole moment of the H2SO4-H2O complex. Geophys. Res. Lett. 33, L23805 (2006).
Brauer, C. S., Craddock, M. B., Kilian, J., Grumstrup, E. M., Orilall, M. C., Mo, Y., Gao, J., & Leopold, K.R. Amine-hydrogen halide complexes: experimental electric dipole moments and a theoretical decomposition of dipole moments and binding energies. J. Phys. Chem. A 110, 10025–10034 (2006).
Ott, M.E., Craddock, M.B., & Leopold, K.R. Nuclear Quadrupole Coupling Constants for Rare-Isotopic Forms of Nitric Acid. J. Mol. Spectrosc. 229, 286-289 (2005).
Brauer, C.S., Sedo, G., Grumstrup, E.M., Leopold, K.R. Marshall, M.D., & Leung, H.O. Effects of Partially Quenched Orbital Angular Momentum on the Microwave Spectrum and Magnetic Hyperfine Splitting in the OH-Water Complex. Chem. Phys. Lett. 401, 420-425 (2005).
Hunt, S.W., Brauer, C.S., Craddock, M.B., Higgins, K.J., Nienow, A.M., & Leopold, K.R. Microwave Observation of H3N-SO3∙∙∙H2O Using a Concentric, Dual-Injection Nozzle Source. Chem. Phys. 305, 155-164 (2004).