研究领域

Functional Inorganic Materials

The research activities of Maksym Kovalenko cover various aspects of chemical synthesis, surface functionalization, self-assembly and applications of colloidal nanostructures. His goals are to develop novel functional materials for energy supplying and energy storing purposes. The scope of studied nanomaterials range from metals and semiconductors to magnetic metal oxides.

近期论文

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M. Walter, R. Erni and M. V. Kovalenko. Inexpensive Antimony Nanocrystals and Their Composites with Red Phosphorus as High-Performance Anode Materials for Na-ion Batteries. Scientific Reports, 2015, 5 : 8418. L. Protesescu, S. Yakunin, M.I. Bodnarchuk, F. Krieg, R. Caputo, C. Holman Hendon, R.X. Yang, A. Walsh, and M.V. Kovalenko. Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X=Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut. Nano Letters, 2015, Accepted. PDF M.V. Kovalenko, L. Manna, A. Cabot, Z. Hens, D.V. Talapin, C.R. Kagan, V.I. Klimov, A.L. Rogach, P. Reiss, D.J. Milliron, P. Guyot-Sionnnest, G. Konstantatos, W.J. Parak, T. Hyeon, B.A. Korgel, C.B. Murray and W. Heiss. Prospects of Nanoscience with Nanocrystals. ACS Nano, 2015, 9, 1012–1057. L. Protesescu, M. Nachtegaal, O. Voznyy, O. Borovinskaya, A.J. Rossini, L. Emsley, C. Coperet, D. Günther, E.H. Sargent, and M.V. Kovalenko. Atomistic description of thiostannate-capped CdSe nanocrystals: retention of four-coordinate SnS4 motif and preservation of Cd-rich stoichiometry. J. Am. Chem. Soc., 2015, 137, 1862–1874. M. He, L. Protesescu, R. Caputo, F. Krumeich, and M. V. Kovalenko. A General Synthesis Strategy for Monodisperse Metallic and Metalloid Nanoparticles (In, Ga, Bi, Sb, Zn, Cu, Sn and their alloys) via In-Situ Formed Metal-Long-Chain-Amides. Chem. Mater., 2015, 27, 635-647. M. He, M. Walter, K.V. Kravchyk, R. Erni, R. Widmer, and M. V. Kovalenko. Monodisperse SnSb Nanocrystals for Li-ion and Na-ion Battery Anodes: Synergy and Dissonance Between Sn and Sb. Nanoscale, 2015, 7, 455-459. M. J. Speirs, D. M. Balazs, Hong-Hua Fang, Lai-Hung Lai, L. Protesescu, M. Kovalenko and M. Antonietta Loi. Origin of the increased open circuit voltage in PbS-CdS core-shell quantum dot solar cells. J. Mater. Chem. A, 2015, 3, 1450-1457. S. Yakunin, D.N. Dirin, L. Protesescu, M. Sytnyk, S. Tollabimazraehno, M. Humer, F. Hackl, T. Fromherz, M. I. Bodnarchuk, Maksym V. Kovalenko, and Wolfgang Heiss. High Infrared Photoconductivity in Films of Arsenic-Sulfide-Encapsulated Lead-Sulfide Nanocrystals. ACS Nano, 2014, 8, 12883–12894. M. F. Oszajca, M. I. Bodnarchuk, and M. V. Kovalenko. Precisely Engineered Colloidal Nanoparticles and Nanocrystals for Li-Ion and Na-Ion Batteries: Model Systems or Practical Solutions? Chem. Mater., 2014, 26, 5422–5432. J. Huang, W. Liu, D. S. Dolzhnikov, L. Protesescu, M. V. Kovalenko, B. Koo, S. Chattopadhyay, E. V. Shevchenko, and D. V. Talapin. Surface Functionalization of Semiconductor and Oxide Nanocrystals with Small Inorganic Oxoanions (PO43-, MoO42-) and Polyoxometalate Ligands. ACS Nano, 2014, 8, 9388–9402. M. Yarema, M. Wörle, M. D Rossell, R. Erni, R. Caputo, L. Protesescu, K. V. Kravchyk, D. N. Dirin, K Lienau, F. von Rohr, A. Schilling, M. Nachtegaal, and M. V. Kovalenko. Monodisperse Colloidal Gallium Nanoparticles: Synthesis, Low Temperature Crystallization, Surface Plasmon Resonance and Li-Ion Storage. J. Am. Chem. Soc., 2014, 136, 12422–12430. P. Moroz, G. Liyanage, N. Kholmicheva, S. Yakunin, P. Uprety, E. Bastola, U. Rijal, B. Mellott, K. Subedi, L. Sun, M. V. Kovalenko, and M. Zamkov. Infrared Emitting PbS Nanocrystal Solids through Matrix Encapsulation. Chem. Mater., 2014, 26, 4256–4264. D. N. Dirin, S. Dreyfuss, M. I. Bodnarchuk, G. Nedelcu, P. Papagiorgis, G. Itskos, and M. V. Kovalenko. Lead halide perovskites and other metal halide complexes as inorganic capping ligands for colloidal nanocrystals. J. Am. Chem. Soc., 2014, 136, 6550–6553. I. Lignos, L. Protesescu, S. Stavrakis, L. Piveteau, M. J. Speirs, M. A. Loi, M. V. Kovalenko, and A. J. deMello. Facile Droplet-based Microfluidic Synthesis of Monodis-perse IV-VI Semiconductor Nanocrystals with Coupled In-Line NIR Fluorescence Detection. Chem. Mater., 2014, 26, 2975–2982. M. J. Speirs, B. G. H. M. Groeneveld, L. Protesescu, C. Piliego, M. Kovalenko and M. A. Loi. Hybrid inorganic-organic tandem solar cells for broad absorption of the solar spectrum. Phys. Chem. Chem. Phys., 2014, 16, 7672-7676. L. H. Lai, W. Gomulya, L. Protesescu, M. Kovalenko and M. A. Loi. High performance photoelectrochemical hydrogen generation and solar cells with a double type II heterojunction. Phys. Chem. Chem. Phys., 2014, 16, 7531-7537. L. Protesescu, A. J. Rossini, D. Kriegner, M. Valla, A. de Kargommeaux, M. Walter, K. V. Kravchyk, M. Nachtegaal, J. Stangl, B. Malaman, P. Reiss, A. Lesage, L. Emsley, C. Coperet, and Maksym V. Kovalenko. Unraveling the Core-Shell Structure of Ligand-Capped Sn/SnOx Nanoparticles by Surface Enhanced Nuclear Magnetic Resonance, Mössbauer and X-Ray Absorption Spectroscopies. ACS Nano, 2014, 8, 2639–2648. M. I. Bodnarchuk, K. V. Kravchyk, F. Krumeich, S. Wang, and M. V. Kovalenko. Colloidal Tin-Germanium Nanorods and Their Li-ion Storage Properties. ACS Nano, 2014, 8, 2360–2368. M. He , K.V. Kravchyk , M. Walter, and M. V. Kovalenko. Monodisperse Antimony Nanocrystals for High-Rate Li-ion and Na-ion Battery Anodes: Nano vs. Bulk. Nano Letters, 2014, 14, 1255-1262. Highlights: ETH News, 2014, March 18 ("Antimony nanocrystals for batteries" by Peter Rüegg); Nano Today, 2014, May 16 ("Antimony promises alternative battery anodes" by Cordelia Seally). D. Tsokkou, P. Papagiorgis, L. Protesescu, M.V. Kovalenko, S.A. Choulis, C. Christofides, G. Itskos, A. Othonos. Photophysics of PbS Quantum Dot Films Capped with Arsenic Sulfide Ligands. Advanced Energy Materials, 2014, 4, 1301547.