个人简介

Prof. Grützmacher was born on March 24, 1959 in Hamburg, Germany. He studied chemistry at the University of Göttingen, (PhD in 1986 with Professor Dr. H.W. Roesky). Subsequently, he spent one post-doc year with Dr. G. Bertrand at the C.N.R.S. in Toulouse. After his habilitation in 1992 at the University of Heidelberg he joined the University of Freiburg as Professor for inorganic chemistry. In 1995 he was appointed as Associate Professor of inorganic chemistry at the ETH where he was promoted to a full professorship in 2001. His research work has received recognition through an ADUC Prize in 1991, a Karl Winnacker Grant in 1992, a Heisenberg Grant from the German Research Society in 1992, the Karl Freudenberg Award from the Academy of Sciences at Heidelberg in 1992, and the Carl Duisberg Commemorative Award of the Society of German Chemists in 1993.

研究领域

Main group elements & Organometallic Chemistry

Since 1995, Hansjörg Grützmacher has been Associate Professor and since 2001 full Professor at the Laboratory of Inorganic Chemistry at ETH Zurich. The research of Hansjörg Grützmacher and his group focuses on the synthesis of molecules which have exceptional functionalities. Currently three main research topics are manifested in the group: a) The synthesis of complexes with transition metals in unusual low formal oxidation states in the hope that these may serve one day as catalysts for light-driven bond coupling reactions, b) synthesis of persistent phosphanyl radicals, R2P·, which shall find especially important applications as contrast agents, molecular markers and reporters for molecular movements (spin labels), and c) the development of new synthetic methods in main group element chemistry with emphasis on organo phosphorus chemistry and the application of these compounds in coating processes (the latter topic is directed by Dr. Joëlle Levalois-Grützmacher). The experimental efforts of the group are accompanied by the application and expansion of theoretical bonding concepts.

近期论文

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Shuyu Liang, Patrick Hemberger, N. Matthias Neisius, Andras Bodi, Hansjörg Grützmacher, Joelle Levalois-Grützmacher, and Sabyasachi Gaan, Chem. Eur. J., 2014, 20, online, link Elucidating the Thermal Decomposition of Dimethyl Methylphosphonate by Vacuum Ultraviolet (VUV) Photoionization: Pathways to the PO Radical, a Key Species in Flame-Retardant Mechanisms Georgina Müller, Michal Zalibera, Georg Gescheidt, Amos Rosenthal, Gustavo Santiso-Quinones, Kurt Dietliker and Hansjörg Grützmacher, Macromol. Rapid Commun., 2015, , online, link Simple One-Pot Syntheses of Water-Soluble Bis(acyl)phosphane Oxide Photoinitiators and Their Application in Surfactant-Free Emulsion Polymerization Crispin Lichtenberg, Liliana Viciu, Mario Adelhardt, Jörg Sutter, Karsten Meyer, Bas de Bruin, and Hansjörg Grützmacher, Angew. Chem. Int Ed., 2015, , DOI ANIE 201411365, link Low-Valent Iron(I) Amido Olefin Complexes as Promotors for Dehydrogenation Reactions, Zhongshu Li, Xiaodan Chen, Maike Bergeler, Markus Reiher, Cheng-Yong Su, and Hansjörg Grützmacher, Dalton Trans., 2015, , DOI DT-ART-2014-12-004012, link A Stable Phosphanyl Phosphaketene and Its Reactivity Monica Trincado, Amos J. Rosenthal, Matthias Vogt, H. Grützmacher, Eur. J. Inorg. Chem., 2014 10, 1599-1604, link, η2-Coordination of a Phosphaalkyne to an Amino Olefin Nickel Complex and Regioselective Catalyzed Cyclooligomerization to Dewar 1,3,5-Triphosphabenzene M. Zalibera, P.-N. Stébé, K. Dietliker, H. Grützmacher, M. Spichty, and Georg Gescheidt, Eur. J. Org. Chem., 2014, 2, 331-337 link, The Redox Chemistry of Mono- and Bis(acyl)phosphane Oxides Dominikus Heift, Zoltàn Benkö, and Hansjörg Grützmacher, Dalton Trans., 2014, 43, 831-840 link, Coulomb repulsion versus cycloaddition: formation of anionic four-membered rings from sodium phosphaethynolate, Na(OCP) Xiaodan Chen, Simone Alidori, Florian Frank Puschmann, Gustavo Santiso-Quinones, Zoltán Benkö, Zhongshu Li, Gerd Becker, Hans-Friedrich Grützmacher, and Hansjörg Grützmacher, Ang. Chem. Int. Ed., 2014, 53, 1641-1645, link, Ang. Chem., 2014, 126, 1667-1671, link, Sodium Phosphaethynolate as a Building Block for Heterocycles ron M. Tondreau, Zoltán Benkö, Jeffrey R. Harmer, Hansjörg Grützmacher, Chem. Sciences, 2014, 5, 1545-1554, link, Sodium Phosphaethynolate, Na(OCP), as "P" Transfer Reagent for the Synthesis of N-Heterocyclic Carbene Supported P3 and PAsP Radicals Dominikus Heift, Zoltán Benkö, Hansjörg Grützmacher, Dalton Trans., 2014, 43, 5920-5928, link, Is the phosphaethynolate anion, (OCP)-, an ambident nucleophile? A spectroscopic and computational study Dominikus Heift, Zoltan Benkö, Hansjörg Grützmacher, Angew. Chem., 2014, 126 (26), 6875-6879, link Angew. Chem. Int. Ed., 2014, 53, 6757-6761, link Redox Triggered Reversible Interconversion of a Monocyclic and Bicyclic Phosphorus Heterocycle Monica Trincado, Dipshikha Banerjee, Hansjörg Grützmacher, Energy Environ Sci., 2014, 7, 2464-2503, link, Molecular catalysts for hydrogen production from alcohols Dominikus Heift, Zoltán Benkö, Hansjörg Grützmacher, Chem. Eur. J., 2014, 20, 11326-11330, link, Phosphaketenes as Building Blocks for the Synthesis of Triphospha Heterocycles Marco Bellini, Manuela Bevilacqua, Jonathan Filippi, Alessandro Lavacchi, Andrea Marchionni, Hamish A. Miller, Werner Oberhauser, Franceso Vizza, Samuel P. Annen, and Hansjörg Grützmacher, ChemSusChem, 2014, 7, 2432-2435, link ChemSusChem., 2014, cover picture link, Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells Shuyu Liang, Patrick Hemberger, N. Matthias Neisius, Andras Bodi, Hansjörg Grützmacher, Joelle Levalois-Grützmacher, and Sabyasachi Gaan, Chem. Eur. J., 2014, 20, online, link Elucidating the Thermal Decomposition of Dimethyl Methylphosphonate by Vacuum Ultraviolet (VUV) Photoionization: Pathways to the PO Radical, a Key Species in Flame-Retardant Mechanisms Georgina Müller, Michal Zalibera, Georg Gescheidt, Amos Rosenthal, Gustavo Santiso-Quinones, Kurt Dietliker and Hansjörg Grützmacher, Macromol. Rapid Commun., 2015, , online, link Simple One-Pot Syntheses of Water-Soluble Bis(acyl)phosphane Oxide Photoinitiators and Their Application in Surfactant-Free Emulsion Polymerization Amos J. Rosenthal, Matthias Vogt, Bas de Bruin, Hansjörg Grützmacher, Eur. J. Inorg. Chem., 2013, 5831-5835 link, A Diolefin Diamide Rhodium(I) Complex and Its One-Electron Oxidation Resulting in a Two-Center, Three-Electron Rh-N Bond Dr. Gustavo Santiso-Quinones, Rafael E. Rodriguez-Lugo, Crystal Structure Communications, 2013, C69, 859-861 link, A mixed chloride/trifluoromethanesulfonate ligand species in a ruthenium(II) complex Rafael E. Rodriguez-Lugo, Dr. Monica Trincado, M. Vogt, F. Tewes, Dr. G. Santiso-Quinones, H. Grützmacher, Nature Chemistry, 2013, 5, 342-347 link, A Homogeneous Transition Metal Complex for the Clean Hydrogen Production from Methanol/Water Mixtures Elisabetta Piras, Bernhard Powietzka, Frederik Wurst, Doreen Neumann-Walter, Hansjörg Grützmacher, Thomas Otto, Thomas Zevaco, Olaf Walter, Catalysis Letters, 2013, 143, 673-680 link, Highly Active Hydroformylation Catalysts: Synthesis, Characterisation and Catalytic Performance Gustavo Santiso-Quinones, Rafael Rodriguez-Lugo, Vittorio Sacchetti, and Hansjörg Grützmacher, Acta Cryst., 2013, C69, 1421-1426 link, RuII-hydride-trop complexes: X-ray single-crystal determination and quantum-chemical calculations