个人简介
Prof. Md. K. Nazeeruddin received M.Sc. and Ph. D. in inorganic chemistry from Osmania University, Hyderabad, India. He joined as a Lecturer in Deccan College of Engineering and Technology, Osmania University in 1986, and subsequently, moved to Central Salt and Marine Chemicals Research Institute, Bhavnagar, as a Research Associate. He was awarded the Government of India’s fellowship in 1987 to study abroad. After one year postdoctoral stay with Prof. Graetzel at Swiss federal institute of technology Lausanne (EPFL), he joined the same institute as a Senior Scientist.
In 2014, EPFL awarded him the title of Professor. His current research at EPFL focuses on Dye Sensitized Solar Cells, Perovskite Solar Cells, CO2 reduction, Hydrogen production, and Light-emitting diodes. He has published more than 480 peer-reviewed papers, ten book chapters, and he is inventor/co-inventor of over 50 patents. The high impact of his work has been recognized by invitations to speak at over 100 international conferences, including the MRS Fall (USA, 2006) and Spring 2011 Meetings, GORDON conference (2014), and has been nominated to the OLLA International Scientific Advisory Board. He appeared in the ISI listing of most cited chemists, and has more than 39'000 citations with an h-index of 93. He is teaching "Functional Materials" course at EPFL, and Korea University; directing, and managing several industrial, national, and European Union projects. He was awarded EPFL Excellence prize in 1998 and 2006, Brazilian FAPESP Fellowship in 1999, Japanese Government Science & Technology Agency Fellowship, in 1998, Government of India National Fellowship in 1987-1988. Recently he has been appointed as World Class University (WCU) professor by the Korea University, Jochiwon, Korea (http://dses.korea.ac.kr/eng/sub01_06_2.htm) and Adjunct Professor by the King Abdulaziz University, Jeddah, Saudi Arabia.
Education:
Doctor of Philosophy (Ph.D), Inorganic Chemistry, 1986, Osmania University, Hyderabad, India.
Master of Science (M.Sc), Inorganic Chemistry, 1980, Osmania University, Hyderabad, India. Passed with first class and distinction.
Bachelor of Science (B.Sc), Chemistry and Biology 1978, Osmania University, Hyderabad, India. Passed with first class and distinction.
Awards:
EPFL award for Excellence, 2006
Brazilian FAPESP Fellowship Award, 1999
Japanese Government Science & Technology Agency Fellowship, 1998
EPFL award for Excellence, 1998
Government of India National Scholar award, 1987-1988
CSIR, Senior research Fellowship, 1983-1986
CSIR, Junior research Fellowship, 1980-1983
研究领域
The groups’ focus is Molecular Engineering of Functional Materials for Photovolatic and Light emitting applications. In the field of molecular-based photovoltaic devices, dye-sensitized solar cells (DSCs) have reached an efficiency of over 13%. This efficiency level, coupled with the use of inexpensive materials and processing has stimulated momentum to industrialize this technology. In these cells, the sensitizer, located at the junction between electron and hole transporting phases, absorbs sunlight and injects an electron and a hole into the n- and p-type materials, respectively. The former is an inorganic n-type wide bandgap oxide semiconductor (typically TiO2 anatase) and the latter is a liquid electrolyte or p-type hole transporter. The generated free charge carriers, travel through the nanostructured oxide to be collected as current at the external contacts. The significant advantage of DSCs is that they achieve the separation of light harvesting, and charge carrier transport, thus the maximum power point is virtually independent of light level therefore useful in all climate conditions. The general losses in dye-sensitized solar cells are due to the lack of sensitizer absorption in the near IR region, and the loss-in-potential from the optical band gap to the open-circuit voltage. The goal of the group is to engineer at molecular level novel panchromatic sensitizers and functionalized hole-transporting materials to achieve power conversion efficiency over 18%.
Recently organohalide lead perovskites have revolutionised the scenario of emerging photovoltaic (PV) technologies, with recently certified efficiency of 20.1% based on a perovskite solar cell. Such high efficiency is largely due to panchromatic absorption (down to ca. 800 nm), high absorption coefficient (1.4*104 cm-1 at 550 nm), low exciton binding energy (25 meV in MAPbI3), large mobility (66 cm2/Vs for MAPbI3), ambipolar charge transport, and large electron and hole diffusion lengths (175 um). The group is aiming to enhance power conversion efficiency of perovskite solar cells beyond 20%, and stability using functionalized electron and hole transporting materials. Our approach unfolds in three strategies: i) Interface engineering of new electron transporting materials; ii) Design and develop molecularly engineered novel family of large band gap hole transporting materials; and iii) Optimize the perovskite deposition techniques. The perovskite solar cell technology has been already proven to be remarkably efficient and has scope to compete with the very best crystalline semiconductor and thin film photovoltaic systems while offering the very lowest potential cost for materials and solution processed manufacturing. The groups’ ambitious goal of reaching power conversion efficiency 23% under 100 mW cm−2 will be realized by developing novel materials.
近期论文
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P. Gratia / M. K. Nazeeruddin; M. Graetzel (Dir.) : Compositional Characterization of Organo-Lead tri-Halide Perovskite Solar Cells. Lausanne, EPFL, 2018. DOI : 10.5075/epfl-thesis-8410.
S. Aghazada / M. K. Nazeeruddin; M. Graetzel (Dir.) : Cyclometalated Ruthenium Complexes for Dye-Sensitized Solar Cells. Lausanne, EPFL, 2018. DOI : 10.5075/epfl-thesis-8298.
K. Rakstys / M. K. Nazeeruddin; M. Graetzel (Dir.) : Molecularly Engineered Hole Transporting Materials for High Performance Perovskite Solar Cells. EPFL, 2018. DOI : 10.5075/epfl-thesis-8264.
S. Aghazada; Y. Ren; P. Wang; M. K. Nazeeruddin : Effect of Donor Groups on the Performance of Cyclometalated Ruthenium Sensitizers in Dye-Sensitized Solar Cells; Inorganic Chemistry. 2017. DOI : 10.1021/acs.inorgchem.7b02164.
Z. Ahmad; M. A. Najeeb; R. A. Shakoor; A. Alashraf; S. A. Al-Muhtaseb et al. : Instability in CH3NH3PbI3 perovskite solar cells due to elemental migration and chemical composition changes; Scientific Reports. 2017. DOI : 10.1038/s41598-017-15841-4.
S. Ameen; M. Nazim; M. S. Akhtar; M. K. Nazeeruddin; H.-S. Shin : A novel perovskite solar cell design using aligned TiO2 nano-bundles grown on a sputtered Ti layer and a benzothiadiazole-based, dopant-free hole-transporting material; Nanoscale. 2017. DOI : 10.1039/c7nr06424a.
A. K. Chandiran; S. M. Zakeeruddin; R. Humphry-Baker; M. K. Nazeeruddin; M. Graetzel et al. : Investigation on the Interface Modification of TiO2 Surfaces by Functional Co-Adsorbents for High-Efficiency Dye-Sensitized Solar Cells; Chemphyschem. 2017. DOI : 10.1002/cphc.201700486.
M. Salado; M. Asuncion Fernandez; J. P. Holgado; S. Kazim; M. K. Nazeeruddin et al. : Towards Extending Solar Cell Lifetimes: Addition of a Fluorous Cation to Triple Cation-Based Perovskite Films. 2017. Symposium on Halide Perovskites for Optoelectronics Applications as part of the International Conference on Materials for Advanced Technologies (ICMAT), Singapore, SINGAPORE, 2017. p. 3846-3853. DOI : 10.1002/cssc.201700797.
K. Rakstys; S. Paek; G. Grancini; P. Gao; V. Jankauskas et al. : Low-Cost Perovskite Solar Cells Employing Dimethoxydiphenylamine-Substituted Bistricyclic Aromatic Enes as Hole Transport Materials. 2017. Symposium on Halide Perovskites for Optoelectronics Applications as part of the International Conference on Materials for Advanced Technologies (ICMAT), Singapore, SINGAPORE, 2017. p. 3825-3832. DOI : 10.1002/cssc.201700974.
A. I. Rafieh; P. Ekanayake; I. H. Abdullah; H. Nakajima; C. M. Lim et al. : Doping and energy band modulation of nanoporous electrodes for enhancing power conversion efficiency of dye-sensitized solar cells; Materials Research Bulletin. 2017. DOI : 10.1016/j.materresbull.2017.08.027.
G. Grancini; D. Viola; Y. Lee; M. Saliba; S. Paek et al. : Femtosecond Charge-Injection Dynamics at Hybrid Perovskite Interfaces; Chemphyschem. 2017. DOI : 10.1002/cphc.201700492.
Y. Zhang; Z. Fei; P. Gao; Y. Lee; F. F. Tirani et al. : A Strategy to Produce High Efficiency, High Stability Perovskite Solar Cells Using Functionalized Ionic Liquid-Dopants; Advanced Materials. 2017. DOI : 10.1002/adma.201702157.
J. Fernandez-Ariza; M. Urbani; M. Graetzel; M. Salome Rodriguez-Morgade; M. K. Nazeeruddin et al. : An Unsymmetrical, Push-Pull Porphyrazine for Dye-Sensitized Solar Cells; Chemphotochem. 2017. DOI : 10.1002/cptc.201600004.
G. Seo; D. Lee; S. Heo; M. Seol; Y. Lee et al. : Microscopic Analysis of Inherent Void Passivation in Perovskite Solar Cells; Acs Energy Letters. 2017. DOI : 10.1021/acsenergylett.7b00484.
J. Suanzes Pita; M. Urbani; G. Bottari; M. Ince; S. A. Kumar et al. : Pyridyl- and Picolinic Acid Substituted Zinc(II) Phthalocyanines for Dye-Sensitized Solar Cells; Chempluschem. 2017. DOI : 10.1002/cplu.201700048.
S. Aghazada; I. Zimmermann; V. Scutelnic; M. K. Nazeeruddin : Synthesis and Photophysical Characterization of Cyclometalated Ruthenium Complexes with N-Heterocyclic Carbene Ligands; Organometallics. 2017. DOI : 10.1021/acs.organomet.7b00354.
A. E. Lewis; Y. Zhang; P. Gao; M. K. Nazeeruddin : Unveiling the Concentration-Dependent Grain Growth of Perovskite Films from One- and Two-Step Deposition Methods: Implications for Photovoltaic Application; Acs Applied Materials & Interfaces. 2017. DOI : 10.1021/acsami.7b05892.
S. Paek; P. Qin; Y. Lee; K. T. Cho; P. Gao et al. : Dopant-Free Hole-Transporting Materials for Stable and Efficient Perovskite Solar Cells; Advanced Materials. 2017. DOI : 10.1002/adma.201606555.
M. K. Nazeeruddin; M. Graetzel; I. Zimmermann; C. Roldán Carmona; P. Gratia et al. ; Charge transporting material for optoelectronic and/or photoelectrochemical devices. WO2017098455 ; EP3178823 . 2017.
I. Jones; G. Durand; M. K. Nazeeruddin; M. I. Dar; M. Graetzel et al. ; A wire shaped coaxial photovoltaic solar cell. WO2017081531 ; EP3168877 . 2017.
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