个人简介
Thieme Synthesis/Synlett Journal Award, 2010
3M Nontenured Faculty Grantee, 2009
NIH Ruth L. Kirschstein NRSA Postdoctoral Fellow, 2006
ARCS Foundation Graduate Fellow, 2004
Bristol-Myers Squibb Graduate Fellow, 2001
研究领域
Organic Chemistry/Nanoscience & Materials Chemistry/Energy & Catalysis/Inorganic & Organometallic Chemistry
Research in our group focuses on the development of new synthetic methods and on finding solutions to a variety of synthesis problems. Our program in developing new methods is particularly focused on reactions we feel have the potential to change the way scientists approach the construction of organic molecules. For example, development of carbon–carbon sigma bond activation could open up unusual disconnections in retrosynthetic analysis, leading to new or more efficient syntheses of desirable molecules. We are also interested in new approaches to conjugated systems applicable in organic electronics, particularly the linear acenes including derivatives of tetracene, pentacene, and polyacene, a long-sought polymer. Our interest in synthesis extends well beyond organic electronics to encompass biologically relevant compounds. Several natural product targets of interest appear to the right.
近期论文
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Rondla, N. R.; Ogilvie, J. M.; Pan, Z.; Douglas, C. J.* “Palladium Catalyzed Intramolecular Acylcyanation of Alkenes Using α-Iminonitriles” Chem. Commun. 2014, accepted.
Pan, Z.; Pound, S. M.; Rondla, N. R.; Douglas, C. J.* “Intramolecular Aminocyanation of Alkenes by N–CN Bond Cleavage” Angew. Chem., Int. Ed. 2014, 53, 5170–5174.
Dreis, A. M.; Douglas, C. J.* “Carbon-Carbon Bond Activation with 8-Acylquinolines” Top. Curr. Chem. 2014, DOI: 10.1007.128_2013_523
Xie, W.;* Prabhumirashi, P. L.; Nakayama, Y.; McGarry, K. A.; Geier, M. L.; Uragami, Y.; Mase, K.; Douglas, C. J.; Ishii, H.; Hersam, M. C., Frisbie, C. D.* “Utilizing Carbon Nanotube Electrodes to Improve Charge Injection and Transport in Bis(trifluoromethyl)-dimethyl-rubrene (fm-rubrene) Ambipolar Single Crystal Transistors” ACS Nano 2013, 11, 10245–10256.
Mullenbach, T. K.; McGarry, K. A.; Luhman, W. A.; Douglas, C. J.;* Holmes, R. J.* “Connecting Molecular Structure and Exciton Diffusion Length in Rubrene Derivatives” Adv. Mater. 2013, 25, 3689–3693.