个人简介
Employment
Jul/2016– Professor
Center for Organic Chemistry (COC)
Frontier Institute of Science and Technology
Xi’an Jiaotong University, China
Sept/2014–Jul/2016 JSPS Postdoctoral Fellow
Kyoto University, Japan (Supervisor: Prof. Osuka & Yorimitsu)
Apr/2014–Aug/2016 Postdoctoral Fellow
Kyoto University, Japan (Supervisor: Prof. Osuka & Yorimitsu)
Feb/2014–Apr/2016 Research Associate
Kyoto University, Japan (Supervisor: Prof. Osuka & Yorimitsu)
Aug/2013–Jan/2014 Research Associate
Nanyang Technological University, Singapore (Supervisor: Prof. Yoshikai)
Education
Aug/2009–Mar/2014 PhD (Organic Chemistry),
Division of Chemistry and Biological Chemistry
School of Physical and Mathematical Sciences
Nanyang Technological University, Singapore (Supervisor Prof. Yoshikai)
Sept.2006–Jul. 2009 M.Sc. (Organic Chemistry),
Department of Chemistry
Fudan University, China (Supervisor: Prof. Jie Wu)
Sept. 2002–Jul. 2006 B.Sc. (Chemistry),
Department of Chemistry
Fudan University, China
研究领域
1. Design of Porphyrin-based supramolecular catalysis for C–H bond activation
2. Design of Frustrated Lewis Pairs (FLPs) catalysis for small molecular activation
近期论文
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1. α-Arylation of Aryl Sulfides with Ketimines at a low Palladium Catalyst loading. Gao, K.; Yorimitsu, H.; Osuka, A. Angew. Chem. Int. Ed. 2016, 55, 4573.
2. Cobalt-Catalyzed ortho C–H Alkylation of 2-Arylpyridines via Ring-Opening of Aziridines. Gao, K.; Paira, R.; Yoshikai, N. Adv. Synth. Catal. 2014, 356, 1486.
3. Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization. Gao, K.; Yoshikai, N. Acc. Chem. Res. 2014, 47, 1208.
4. Cobalt-Catalyzed Ortho Alkylation of Aromatic Imines with Primary and Secondary Alkyl Haldies. Gao, K.; Yoshikai, N. J. Am. Chem. Soc. 2013, 135, 9279.
5. Cobalt-Catalyzed Ortho-Arylation of Aromatic Imines with Aryl Chlorides. Gao, K.; Lee, P.-S.; Long, C.; Yoshikai, N. Org. Lett. 2012, 14, 4234.
6. Cobalt-Catalyzed Arylation of Aldimines via Directed C–H Bond Functionalization: Addition of 2-Arylpyridines and Self-Coupling of Aromatic Aldimines. Gao, K.; Yoshikai, N. Chem. Commun. 2012, 48, 4305. (Top ten most accessed article in March 2012)
7. Cobalt–Phenanthroline Catalysts for the ortho Alkylation of Aromatic Imines under Mild Reaction Conditions. Gao, K.; Yoshikai, N. Angew. Chem. Int. Ed. 2011, 50, 6888.
6. Regioselectivity-Switchable Hydroarylation of Styrenes. Gao, K.; Yoshikai, N. J. Am. Chem. Soc. 2011, 133, 400.
8. Cobalt-Catalyzed Hydroarylation of Alkynes through Chelation-Assisted C‒H Bond Activation. Gao, K.; Lee, P.-S.; Fujita, T.; Yoshikai, N. J. Am. Chem. Soc. 2010, 132, 12249. (Highlighted in Synfacts 2010, 1410)
9. Sc(OTf)3-Catalyzed or t-BuOK Promoted Tandem Reaction of 2-(2-(Alkynyl)benzylidene)malonate with Indole. Gao, K.; Wu, J. Org. Lett. 2008, 10, 2251.