Szabó, Kálmán J - Stockholm University - Department of Organic Chemistry

个人简介

Kálmán J. Szabó is professor at the Department of Organic Chemistry at the Arrhenius Laboratory, Stockholm University from 2003. In 2016 Prof. Szabó was elected to member of the Royal Swedish Academy of Sciences (class for chemistry). Szabó obtained his PhD at Lund University, Sweden, with Professor Salo Gronowitz in 1993, and did his postdoctoral research with Professor Dieter Cremer. His major research interest involves various aspects of organic synthesis, organometallic chemistry and homogenous catalysis. Prof. Szabó has developed synthetically useful transition metal catalyzed transformations based on palladium, iridium, copper and titan complexes.

研究领域

His group extensively studied application of palladium, iridium and copper catalysts in selective organic transformations including asymmetric catalysis with a particular attention to C-C, C-B, C-CF3/C-F and C-Si formation reactions. In the last years Prof. Szabó’s research interest turned in the direction of C-H activation reactions and possibilities to employ higher oxidation states of transition metals, such as Pd(IV), Cu(III) for selective transformation of alkenes.

近期论文

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H.-P. Deng, D. Wang, K. J. Szabó*: Direct Allylation of Quinones with Allylboronates. J. Org. Chem. 2015, 80, 3343-3348. T. S. N. Zhao, J. Zhao, K. J. Szabó*: Stereoselective Synthesis of 1,4-Diols by a Tandem Allylboration–Allenylboration Sequence. Org. Lett. 2015, 17, 2290-2293. W. Yuan, K. J. Szabó*: Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent. Angew. Chem. Int. Ed. 2015, 15, 8533-8537. R. Alam, T. Vollgraff, L. Eriksson, K. J. Szabó*: Synthesis of Adjacent Quaternary Stereocenters by Catalytic Asymmetric Allylboration. J. Am. Chem. Soc. 2015, 137, 11262-11265. A. Das, D. Wang, M.-C. Belhomme, K. J. Szabó*: Copper-Catalyzed Cross-Coupling of Allylboronic Acids with a-Diazoketones. Org. Lett. 2015, 17, 4754-4757. ACS Editors Choice 9/16/15 Y. Zhao, K. J. Szabó*: Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine and Oxetane Substrates. Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates. Angew. Chem. Int. Ed. 2016, 55, 1502-1506. Y. Yang, K. J. Szabó*: Synthesis of Allenes by Catalytic Coupling of Propargyl Carbonates with Aryl Iodides in the Presence of Diboron Species. J. Org. Chem. 2016, 81, 250-255. N. O. Ilchenko, M. A. Cortés, K. J. Szabó*: Palladium Catalyzed Iodofluorination of Alkenes using Fluoro-Iodoxole Reagent. ACS Catal. 2016, 6, 447-450. N. Miralles, R. Alam, K. J. Szabó*, E. Fernández*:Transition-Metal-Free Borylation of Allylic and Propargylic Alcohols. Angew. Chem. Int. Ed. 2016, 55, 4303-4307. W. Yuan, L. Eriksson, K. J. Szabó*: Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-methylation of Diazocarbonyl Compounds.Angew. Chem. Int. Ed. 2016, 55, 8410-8415. M.-C. Belhomme, D. Wang, K. J. Szabó*: Formation of C(sp3)-C(sp3) bonds by Palladium Catalyzed Cross-coupling of α-Diazoketones and Allylboronic Acids Org. Lett. 2016, 18, 2503-2506. W. Yuan, K. J. Szabó*: Rhodium-Catalyzed Oxy-Aminofluorination of Diazoketones with Tetrahydrofurans and NFSI. ACS Catal. 2016, 6, 6687-6691. N. O. Ilchenko, M. Hedberg, K. J. Szabó*: Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine Reagents. An Efficient Method for 1,3-Oxyfluorination and 1,3-Difluorination. Chem. Sci. 2016. R. Alam, C. Diner, S. Jonker, K. J. Szabo*: Catalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids. Stereodivergent Synthesis up to Three Contiguous Stereocenters. Angew. Chem. Int. Ed. 2016, 55, 14417-14421. Highlited in Chemistry Views and Chemistry World. A. Bermejo Gomez, M. Cortes, M. Lübcke, M. Johansson, C. Halldin, K. J. Szabo,* M. Schou*: Efficient DBU accelerated synthesis of 18F-labelled trifluoroacetamides.Chem. Commun.2016.