个人简介
Current – Lecturer, Queensland University of Technology
2009-2011 – Postdoctoral research at the University of Edinburgh
2007-2009 – Postdoctoral research at the University of Oxford
2004-2007 – PhD in Chemistry at the University of New England
2000-2002 – B. Science (Adv) with 1st Class Honours at the University of New England
研究领域
Supramolecular chemistry
Organic synthesis
Molecular recognition
This concept of creating molecular electronic devices has resulted in the development and rapid advance of the field of supramolecular chemistry. Synthetic developments using fundamental concepts such as preorganisation, molecular recognition, self-assembly and template-directed synthesis has resulted in a dramatic increase in the quantity and variety of supramolecular systems that can be made with the potential for functioning as molecular devices.
Our work looks at using interlocked architectures as the basis for the development of
Sensors : which can encapsulate and sense environmentally or medicinally important anions;
Switches or shuttles : in which the orientation or properties of an interlocked system can be changed through the application of external stimuli; and
Solid tethered supramolecular systems : to determine the impact of surface confinement on the dynamic molecules and ultimately move towards systems with more practical applications
近期论文
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Li Y, Mullen K, Sardinha J, Felix V, Beer PD, (2011) Clipping and stoppering anion templated synthesis of a [2]rotazane host system, Dalton Transactions p12180-12190
Altieri A, Aucagne V, Carrillo R, Clarkson GJ, D'Souza DM, Dunnett JA, Leigh DA, Mullen K, (2011) Sulfur-containing amide-based [2]rotaxanes and molecular shuttles, Chemical Science p1922-1928
Ahmed R, Altieri A, D'Souza DM, Leigh DA, Mullen K, Papmeyer M, Slawin AM, Wong JK, Woollins J, (2011) Phosphorus-based functional groups as hydrogen bonding templates for rotaxane formation, Journal of the American Chemical Society p12304-12310
D'Souza DM, Leigh DA, Mottier L, Mullen K, Paolucci F, Teat SJ, Zhang S, (2010) Nitrone [2]rotaxanes: Simultaneous chemical protection and electrochemical activation of a functional group, Journal of the American Chemical Society p9465-9470
Li Y, Mullen K, Claridge TD, Costa PJ, Felix V, Beer PD, (2009) Sulfate anion templated synthesis of a triply interlocked capsule, Chemical Communications p7134-7136
Mullen K, Mercurio J, Serpell CJ, Beer PD, (2009) Exploiting the 1,2,3-triazolium motif in anion-templated formation of a bromide-selective rotaxane host assembly, Angewandte Chemie (International Edition) p4781-4784
Mullen K, Beer PD, (2009) Sulfate anion templation of macrocycles, capsules, interpenetrated and interlocked structures, Chemical Society Reviews p1701-1713
Brown A, Mullen K, Ryu J, Chmielewski MJ, Santos SM, Felix V, Thompson AL, Warren JE, Pascu SI, Beer PD, (2009) Interlocked host anion recognition by an indolocarbazole-containing [2]rotaxane, Journal of the American Chemical Society p4937-4952
Zhao L, Davis JJ, Mullen K, Chmielewski MJ, Jacobs RM, Brown A, Beer PD, (2009) Anion templated formation of pseudorotaxane and rotaxane monolayers on gold from neutral components, Langmuir: the ACS journal of surfaces and colloids p2935-2940
Mullen K, Johnstone KD, Webb M, Bampos N, Sanders JK, Gunter MJ, (2008) Monitoring the thermodynamically-controlled formation of diimide-based resin-attached rotaxanes by gel-phase HR MAS 1H NMR spectroscopy, Organic and Biomolecular Chemistry p278-286