研究领域

Inorganic Chemistry

Research in the group focuses on the synthesis and study of novel solids which exhibit unusual electronic and magnetic behaviour. A particular area of interest is the utilization of unusual synthetic techniques and conditions to increase the degree of control and selectivity exhibited by solid state reactions.

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(72) Reductive lithium insertion into B-cation deficient niobium perovskite oxides. A. Perejon and M. A. Hayward Dalton Transactions, (accepted) Download Ca2Cr0.5Ga1.5O5 – An extremely redox-stable brownmillerite phase. K. Luo, M. Amano Patino and M. A. Hayward Journal of Solid State Chemisty, 222 (2015) 71. Download Cation exchange in a 3D perovskite – synthesis of Ni0.5TaO3. M. Amano Patino, T. Smith, W. Zhang, P. S. Halasyamani and M. A. Hayward Inorganic Chemistry, 53 (2014) 8020. Download Strontium vanadium oxide-hydrides: ‘square-planar’ two-electron phases. F. Denis Romero, A. Leach, J. S. Möller, F. Foronda, S. J. Blundell and M. A. Hayward Angewandte Chemie, 53 (2014) 7556. Download Topochemical reactions of layered transition-metal oxides. M. A. Hayward Semiconductor Science and Technology, 29 (2014) 64010. Download Stoichiometry dependent Co3+ spin-state in LaxSr2-xCoGaO5+d brownmillerite phases. K. Luo and M. A. Hayward Dalton Transactions, 43 (2014) 1571. Download Synthesis and selective topochemical fluorination of the cation and anion-vacancy ordered phases Ba2YCoO5 and Ba3YCo2O7.5. K. Luo, T. T. Tran, P. S. Halasyamani and M. A. Hayward Inorganic Chemistry, 52 (2013) 13762. Download Topochemical reduction of the Ruddlesden-Popper phases Sr2Fe0.5Ru0.5O4 and Sr3(Fe0.5Ru0.5)2O7 F. Denis Romero, D. Gianolio, G. Cibin, P. A. Bingham, J-C. d’Hollander, S. D. Forder and M. A. Hayward Inorganic Chemistry, 52 (2013) 10920. Download Soft chemistry synthesis of oxides. M. A. Hayward Comprehensive Inorganic Chemistry II, Eds. J. Reedijk and K. R. Poeppelmeier, Elsevier (Oxford), Vol. 2 (2013) 417. Download Ba2YFeO5.5 – A ferromagnetic pyroelectric phase prepared by topochemical oxidation K. Luo, R. D. Johnson, T. T. Tran, P. S. Halasyamani, P. G. Radaelli and M. A. Hayward Chemistry of Materials, 25 (2013) 1800. Download Topochemical fluorination of Sr3(M0.5Ru0.5)2O7 (M = Ti, Mn, Fe) n = 2 Ruddlesden-Popper phases F. Denis Romero, P. A. Bingham, S. D. Forder and M. A. Hayward Inorganic Chemistry, 52 (2013) 3388. Download SrFe0.5Ru0.5O2: Square-planar Ru2+ in an extended oxide F. Denis Romero, S. J. Burr, J. E. McGrady, D. Gianolio, G. Cibin and M. A. Hayward Journal of the American Chemical Society, 135 (2013) 1838. Download The synthesis and characterisation of LaCa2Fe2GaO8 K. Luo and M. A. Hayward Journal of Solid State Chemistry, 198 (2013) 203. Download Complex cation order in anion-deficient BanYFen-1O2.5n perovskite phases K. Luo and M. A. Hayward Inorganic Chemistry, 51 (2012) 12281. Download The structure and magnetism of Sr3Co2O4Cl2 – An electronically driven lattice distortion in an oxychloride containing square planar CoII centers F. Denis Romero, L. Coyle and M. A. Hayward Journal of the American Chemical Society, 134 (2012) 15946. Download The structure and magnetism of the topotactically reduced oxychloride Sr4Mn3O6.5Cl2 F. Denis Romero and M. A. Hayward Inorganic Chemistry, 51 (2012) 5325. Download The structures and magnetism of La1-xSrxMnO3-(0.5+x)/2 (0.67 < x < 1) phases E. Dixon, J. Hadermann and M. A. Hayward Chemistry of Materials, 24 (2012) 1486. Download Reverse Monte Carlo study of apical Cu-O bond distortions in YBa2Cu3O6.93 C. A. Young, E. Dixon, M. G. Tucker, D. A. Keen, M. A. Hayward and A. L. Goodwin Zeitschrift fuer Kristallographie, 227 (2012) 280. Download Mn(I) in an extended oxide - The synthesis and characterization of La1-xCaxMnO2+d (0.6 < x < 1) E. Dixon, J. Hadermann, S. Ramos, A. L. Goodwin and M. A. Hayward Journal of the American Chemical Society, 133 (2011) 18397. Download ‘A’ cation polarity control in ACuTe2O7 (A = Sr2+, Ba2+, or Pb2+) J. Yeon, S-H Kim, M. A. Hayward and P. S. Halasyamani. Inorganic Chemistry, 50 (2011) 8663. Download Suppression of magnetic order in Sr3Fe2O4Cl2 by Fe-site substitution by cobalt E. Dixon and M. A. Hayward Inorganic Chemistry, 50 (2011) 7250. Download The synthesis and complex anion-vacancy ordered structure of La0.33Sr0.67MnO2.42 E. Dixon, J. Hadermann and M. A. Hayward Journal of Solid State Chemistry, 184 (2011) 1791. Download