Messerle, Barbara - Macquarie University - Department of Chemistry and Biomolecular Sciences

个人简介

Ph.D. University of Sydney 1987. Postdoctoral Fellow ETH Zürich, Switzerland 1987-1989, Gritton Research Fellow, University of Sydney 1990-1991; ARC Queen Elizabeth II Fellow 1992-1997, and ARC Senior Research Fellow 1997-1998, at the University of Sydney. At UNSW: ARC Senior Research Fellow 1999-2002, Senior Lecturer 2002-2003, Associate Professor 2004-2007, Professor 2008- 2014. At Macquarie University: Executive Dean, Science and Engineering and Professor, 2015-

研究领域

Organometallics and Catalysis Enhancing the economic viability and energy efficiency of chemical transformations is of fundamental importance in the chemicals industry today. Organometallic catalysts are an important means of providing new and highly efficient routes for chemical processes, and the development of new transition metal catalysts for promoting the synthesis of key compounds is a major goal in the development of synthetic routes with minimum energy use. Our research program has made contributions to the design of new metal complexes for promoting key chemical reactions, and to the development of new methodologies for catalysed synthetic routes including the fundamentally important C-X bond forming reactions and multistep reactions. The work has provided new insights into highly accessible and efficient metal catalysts, including multimetallic systems. The work will ultimately improve the viability of the synthesis of important biologically active molecules and pharmaceuticals in the fine chemicals industry. In promoting the development of advanced NMR techniques in organometallic chemistry, our research has led to wider insights into catalyst structure and function.

近期论文

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Andrey Tregubov, D. Barney Walker, Khuong Vuong, Justin Gooding and Barbara A. Messerle. “The Advantages of Covalently Attaching Organometallic Catalysts to a Carbon Black Support: Recyclable Rh(I) Complexes That Deliver Enhanced Conversion and Product Selectivity.” Dalton Trans., 2015Ahead of Print, DOI: 10.1039/C5DT00409H. Giulia Mancano, Michael J. Page, Mohan Bhadbhade, and Barbara A. Messerle, “Hemilabile and Bimetallic Coordination in Rh and Ir Complexes of NCN Pincer Ligands” Inorganic Chemistry, 2014, 53, 10159-10170. Andrey A. Tregubov, Rasmus Linser, Khuong Q. Vuong, Aditiya Rawal, John D. Gehman and B. A. Messerle, “Solid-State NMR Structure Characterization of a 13CO-Labeled Ir(I) Complex with a P,N-Donor Ligand Including Ultrafast MAS Methods” Inorganic Chemistry, 2014, 53, 7146-7153. Khuong Vuong, Chin Min-Wong, Mohan Bhadbhade and Barbara A. Messerle, “Bi- and tri-metallic Rh and Ir complexes containing click derived bis- and tris-(pyrazolyl-1,2,3-triazolyl) N–N′ donor ligands and their application as catalysts for the dihydroalkoxylation of alkynes”Dalton, 2014, 43, 7540-7553. Andrey A. Tregubov, Khuong Q. Vuong, Erwann Luais, J. Justin Gooding, and Barbara A. Messerle* Rh(I) Complexes Bearing N,N and N,P Ligands Anchored on Glassy Carbon Electrodes: towards Recyclable Hydroamination Catalysts, Journal of the American Chemical Society, 2013, 135, 16429-16437. Sandra W. S. Choy, Michael J. Page, Mohan Bhadbhade and Barbara A. Messerle*, Cooperative Catalysis: Large Rate Enhancements with Bimetallic Rhodium Complexes, Organometallics, 2013, 32(17), 4726-4729. Chin-Min Wong, Khuong Q. Vuong, Mark R. D. Gatus,Carol Hua, Mohan Bhadbhadeand Barbara A. Messerle*Catalysed Tandem C-N/C-C Bond Formation for the Synthesis of Tricyclic Indoles using Ir(III) Pyrazolyl-1,2,3-Triazolyl Complexes, Organometallics, 2012, 31 (21), 7500–7510,. Carol Hua, Khuong Q. Vuong, Mohan Bhadbhade and Barbara A. Messerle New Rhodium(I) and Iridium(I) Complexes Containing Mixed Pyrazolyl-1,2,3-Triazolyl Ligands as Catalysts for Hydroamination, Organometallics, 2012, 31 (5),1790–1800