个人简介

Geoff Salem graduated from the University of Western Australia with a BSc (Hons) and an MSc and received his PhD from the ANU in 1983. He held Postdoctoral Fellowship positions at the University of Western Australia (1983-1985) and ANU (1985-1989) before being appointed to a lectureship in the Department of Chemistry at ANU. He was promoted to Senior Lecturer in 2001 and served as Head of the Department of Chemistry from 2003-2005. He has had a long association (ca20 years) with the chemistry Olympiad program both at the national and international levels. He was Director of the national program from 2000-2006 and served on the Steering Committee of the International Chemistry Olympiad from 2004-2006. He was promoted to Associate Professor of the Research School of Chemistry in 2008. He has been the Associate Director of Education in the RSC since 2009

研究领域

Ligand design & synthesis

My research interests are primarily concerned with the design, synthesis and resolution of multidentate ligands containing stereogenic arsenic and/or phosphorus donor atoms and the role of their transition metal based complexes as potential antitumour agents or as catalysts in asymmetric synthesis.

近期论文

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Lu, D, Sundaram, A, Coote, M et al 2015, 'Sulfur Derivatives of the Natural Polyarsenical Arsenicin A: Biologically Active, Organometallic Arsenica?’Sulfur Cages Related to the Minerals Realgar and Uzonite', Organometallics, vol. 34, no. 5, pp. 829-840. Lu, D & Salem, G 2013, 'Homochiral arsenic-/phosphorus-based ligands', Coordination Chemistry Reviews, vol. 257, no. 5-6, pp. 1026-1038. Lu, D, Coote, M, Ho, J et al 2012, 'Resolution and improved synthesis of (?±)-arsenicin A: a natural adamantane-type tetraarsenical possessing strong anti-acute promelocytic leukemia cell line activity', Organometallics, vol. 31, no. 5, pp. 1808-1816. Sundaram, A, Coote, M, Lu, D et al 2011, 'Origin of the unusual ultraviolet absorption of arsenicin A', Journal of Physical Chemistry A, vol. 115, no. 17, pp. 4530-4534. Lu, D, Rae, A, Salem, G et al 2010, 'Arsenicin A, A Natural Polyarsenical: Synthesis and Crystal Structure', Organometallics, vol. 29, no. 1, pp. 32-33. Bennett, J, Doyle, R, Lee, H et al 2010, 'Synthesis of 1,3-azaphosphol-2-ones. Crystal and molecular structures of [SP-4-2] -dichlorobis(3-phenyl-1,3-dihydrobenzo[1,3]azaphosphol-2-one-P)palladium(II) and its chloro(methyl)platinum(II) analogue', Dalton Transactions, vol. 39, no. 1, pp. 256-264. Bulbrook, M, Chu, M, Deane, K et al 2010, 'Chiral Birch reduced tertiary phosphines: precursors to asymmetric 1,2-cyclohexenebis(tertiary phosphines)', Dalton Transactions, vol. 39, no. 38, pp. 8878-8881. Jackson, C, Foo, J, Kim, H et al 2008, 'In crystallo capture of a Michaelis complex and product-binding modes of a bacterial phosphotriesterase', Journal of Molecular Biology, vol. 375, no. 5, pp. 1189-1196. Bennett, J, Doyle, R, Salem, G et al 2006, 'Synthesis of a chelating hexadentate ligand with a P3N3 donor set. Crystal and molecular structure of [OC-6-22]-[Co{(RP*,RP*,RP*)-CH3C(CH2PPhC6', Dalton Transactions, vol. 2006/38, pp. 4614-4622. Bennett, J, Rae, A, Salem, G et al 2002, 'Synthesis of bis[palladium(II)] and bis[platinum(II)] complexes containing chiral, linear, quadridentate ligands with a P2N2 donor set', Dalton Transactions, vol. N/A, no. -, pp. 234-243. Chatterjee, S, George, M, Salem, G et al 2001, 'Optically active asymmetric di(tertiary phosphines). Crystal and molecular structure of [SP-4-3-(SP,S)]-{1-[2-chlorophenyl)-methylphosphinol]-2-(dimethylphosphino)benzene-P,P}{1-[1-(dimethylamino)ethyl]naphthyl-C