个人简介

Anthony Hill graduated from the University of Auckland with a MSc (Hons) and received his DrRerNat from the Universit?t Bayreuth. He has since held positions at the University of Bristol (1986-1988), the University of Warwick (1988-1991) and Imperial College (1992-2000) before being appointed Professor at the Research School of Chemistry.

研究领域

Synthetic organometallic & coordination chemistry

Our work covers a diversity of challenges in coordination and organometallic chemistry. Particular foci include unsaturated ligands involving metal–carbon multiple bonding and the interface of transition and main group chemistries. In attempting to understand and ideally control the reactivity of such systems, the nature of the metal centre is of paramount importance; this may be tuned through variations in oxidation state, d-configuration and, most importantly, the nature of the co-ligands. Accordingly, considerable effort is directed towards the synthesis of new co-ligands which themselves do not necessarily take part in the transformations of other ligands but may moderate these indirectly.

近期论文

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Dixon, L, Hill, A, Sinha, A et al 2014, 'N-Heterocyclic silyl pincer ligands', Organometallics, vol. 33, no. 3, pp. 653-658. Hill, A & McQueen, C 2014, 'Arrested B-H activation en route to installation of a PBP pincer ligand on ruthenium and osmium', Organometallics, vol. 33, no. 8, pp. 1977-1985. Hill, A & McQueen, C 2014, 'Dihydroperimidine-derived PNP pincer complexes as intermediates en route to N-heterocyclic carbene pincer complexes', Organometallics, vol. 33, no. 8, pp. 1909-1912. Cade, I, Colebatch, A, Hill, A et al 2014, 'Allenylphosphonium complexes of rhodium and iridium', Organometallics, vol. 33, no. 12, pp. 3198-3204. Young, R, Hill, A, Cavigliasso, G et al 2013, '[(??-C){Re(CO)2(?·-C5H5)}2]: A surprisingly simple bimetallic carbido complex', Angewandte Chemie International Edition, vol. 52, no. 13, pp. 3699-3702. Borren, E, Hill, A, Shang, R et al 2013, 'A golden ring: molecular gold carbido complexes', Journal of the American Chemical Society, vol. 135, no. 13, pp. 4942-4945. Colebatch, A, Cade, I, Hill, A et al 2013, '?·2-Allenyl- and ?·2-Alkynylphosphonium Complexes of Platinum', Organometallics, vol. 32, no. 17, pp. 4766-4774. Hill, A & Fink, M, eds, 2013, Advances in Organometallic Chemistry, Vol. 61, Elsevier Inc., Oxford. Hill, A & Fink, M, eds, 2012, Advances in Organometallic Chemistry, Vol. 60, Elsevier Inc., Oxford. Hill, A & McQueen, C 2012, 'Novel carbon monochalcogenide coordination mode: [Rh2{??-SeCMo(CO)2(Tp)}2(?·4-cod)2] (Tp = hydrotris(3,5-dimethylpyrazol-1-yl)borate; cod = cyclo-octa-1,5-diene)', Organometallics, vol. 31, no. 6, pp. 2482-2485. Cade, I & Hill, A 2012, '1,1-Bis(N-methylimidazole)-2-(trimethylsilyl)-1-boracyclohexa-1,4-diene chloride: a stable intermediate or tangent en route to 1-(N-methylimidazole)borabenzene?', Journal of the American Chemical Society, vol. 31, no. 5, pp. 2112-2115. Maitlis, P & Hill, A 2012, 'F. Gordon A. Stone: the chemist's chemist', Organometallics, vol. 31, no. 7, pp. 2489-2506. Hill, A, Sharma, M & Willis, A 2012, 'Heterodinuclear bridging carbido and phosphoniocarbyne complexes', Organometallics, vol. 31, no. 7, pp. 2538-2542. Young, R, Lawes, D, Hill, A et al 2012, 'Observation of a Tungsten Alkane ??-Complex Showing Selective Binding of Methyl Groups Using FTIR and NMR Spectroscopies', Journal of the American Chemical Society, vol. 134, no. 20, pp. 8294a??8297. Hill, A & Shang, R 2012, 'Boratocarbyne complexes: Li[Mo{a??CB(OMe)3}(CO)2{HB(pzMe2)3}] and [K(18-crown-6)][Mo(a??CBF2OMe)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl)', Organometallics, vol. 31, no. 13, pp. 4635-4638. Willis, A, Hill, A, Vafazadeh, R et al 2012, 'Synthesis and structural studies of mono- and dinuclear Cu(II) complexes with an ONO donor Schiff base ligand: Self-assembly and sulfato-bridged', Polyhedron, vol. 48, no. 1, pp. 51-57. Hill, A & McQueen, C 2012, 'Dihydroperimidine-derived N-heterocyclic pincer carbene complexes via double C-H activation', Organometallics, vol. 31, no. 23, pp. 8051-8054. Farmer, J, Man, W, Fox, M et al 2012, 'Syntheses, structures and redox properties of tris(pyrazolyl)borate-capped ruthenium vinyl complexes', Journal of Organometallic Chemistry, vol. 721-722, pp. 173-185. Cordiner, R, Hill, A, Shang, R et al 2011, 'Group 14 substituted carbyne complexes - an almost complete set: [Mo(a‰?CAPh3)(CO)2(Tp)] (Tp = hydrotris(dimethylpyrazolyl)borate; A = Si, Ge, Sn, Pb but A a‰ C).', Organometallics, vol. 30, no. 1, pp. 139-144. Hill, A & Fink, M, eds, 2011, Advances in Organometallic Chemistry, Vol. 59, Elsevier Inc., Oxford.