个人简介

Marie Cifuentes is the group leader of the Functional organometallic materials research group. Her research interests are centered on molecular organometallic materials chemistry; synthesis, structure, reactivity, electrochemistry and nonlinear optical properties of organometallic and related organic molecules. She is a Chief Investigator in the Australia-China Joint Research Centre for Functional Molecular Materials, and has recieved the RACI Organometallic Award (2006), as well as the Gritton Fellowship by the University of Sydney (1999), an ARC Australian Postdoctoral Fellowship (1996), and two ARC Australian Research Fellowships (2002, 2010).

研究领域

Functional organometallic materials

The aim of our research is the preparation of new types of potentially useful molecular materials. Understanding how chemical structure can control molecular properties is the key step, and this necessitates coupling chemical synthesis to a range of physical properties studies. Research in the group involves organometallic, organic, coordination complex and polymer synthesis, spectroscopy, various electrochemical and spectroelectrochemical techniques, molecular modelling, electron microscopy and X-ray structural studies, and a wide range of nonlinear optical studies using high-power lasers.

近期论文

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Zhang, J, Jia, D, Humphrey, M et al 2016, 'Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties', Chemical Communications, vol. 52, no. 19, pp. 3797-3800. Fu, J, Morshedi, M, Moxey, G et al 2016, 'Dynamic Permutational Isomerism in a closo-Cluster', Chemistry, A European Journal, vol. 22, pp. 5128-5132. Wang, A, Wang, Y, Yu, W et al 2016, 'TiO2-multi-walled carbon nanotube nanocomposites: Hydrothermal synthesis and temporally-dependent optical properties', RSC Advances, vol. 6, no. 24, pp. 20120-20127. Wang, A, Song, J, Jia, D et al 2016, 'Functionalization of reduced graphene oxide with axially-coordinated metal-porphyrins: Facile syntheses and temporally-dependent nonlinear optical properties', Inorganic Chemistry, vol. 3, no. 2, pp. 296-305. Wang, A, Song, J, Huang, Z et al 2016, 'Multi-walled carbon nanotubes covalently functionalized by axially coordinated metal-porphyrins: Facile syntheses and temporally dependent optical performance', Nano Research, vol. 9, no. 2, pp. 458-472. Fu, J, Moxey, G, Morshedi, M et al 2016, 'Mixed-metal cluster chemistry. 37. Syntheses, structural, spectroscopic, electrochemical, and optical power limiting studies of tetranuclear molybdenum-iridium clusters', Journal of Organometallic Chemistry, vol. 812, pp. 135-144. Zhang, J, Wang, C, Wang, Y et al 2015, 'Single cyanide-bridged Mo(W)/S/Cu cluster-based coordination polymers: Reactant- and stoichiometry-dependent syntheses, effective photocatalytic properties', Journal of Solid State Chemistry, vol. 231, pp. 230-238. Zhao, H, Simpson, P, Barlow, A et al 2015, 'Syntheses, Spectroscopic, Electrochemical, and Third-Order Nonlinear Optical Studies of a Hybrid Tris{ruthenium(alkynyl)/(2-phenylpyridine)}iridium Complex', Chemistry, A European Journal, vol. 21, no. 33, pp. 11843-11854. Merhi, A, Grelaud, G, Ripoche, N et al 2015, 'A zinc(II) tetraphenylporphyrin peripherally functionalized with redox-active "trans-[(?· 5-C5H5)Fe(?· 5-C5H4)Ca‰?C](?o2-dppe)2Ru(Ca‰?C)-" substituents: linear e', Polyhedron, vol. 86, pp. 64-70. Wang, A, Wang, Y, Xiao, Z et al 2015, 'A 1,3-dipolar cycloaddition protocol to porphyrinfunctionalized reduced graphene oxide with a push-pull motif', Nano Research, vol. 8, no. 3, pp. 870-886. Lau, K, Barlow, A, Moxey, G et al 2015, 'Large electric-field-induced strain in centrosymmetric crystals of a dipolar ruthenium alkynyl complex', Physical Chemistry Chemical Physics, vol. 17, no. 16, pp. 10781-10785. Merhi, A, Grelaud, G, Green, K et al 2015, 'A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchee" with large cubic NLO properties', Dalton Transactions, vol. 44, no. 17, pp. 7748-7751. Li, J, Jia, D, Meng, S et al 2015, 'Tetrazine Chromophore-Based Metal-Organic Frameworks with Unusual Configurations: Synthetic, Structural, Theoretical, Fluorescent, and Nonlinear Optical Studies', Chemistry, A European Journal, vol. 21, no. 21, pp. 7914-7926. Wang, A, Yu, W, Fang, Y et al 2015, 'Facile hydrothermal synthesis and optical limiting properties of TiO2-reduced graphene oxide nanocomposites', Carbon, vol. 89, pp. 130-141. Simpson, P, Randles, M, Gupta, V et al 2015, 'Phosphine, isocyanide, and alkyne reactivity at pentanuclear molybdenum/tungsten-iridium clusters', Dalton Transactions, vol. 44, no. 16, pp. 7292-7304. Fu, J, Moxey, G, Cifuentes, M et al 2015, 'Mixed-metal cluster chemistry. 35. Syntheses and structural studies of Mo3Ir3(??3-O)(??-CO)3(CO)8(?·5-C5H5)3, Mo4Ir4(??-CO)4, Journal of Organometallic Chemistry, pp. 1-5. Fu, J, Randles, M, Criddle, A et al 2015, 'Syntheses of Ir4(CO)6(?·5-C5Me4H)2 and Ir7(??3-CO)3(CO)12(?·5-C5Me5) from Pentametallic Molybdenum-Iridium Cluste', European Journal of Inorganic Chemistry, vol. 2015, no. 15, pp. 2587-2591. Chen, Z, Jeffery, C, Morshedi, M et al 2015, 'Syntheses, Electrochemical, Linear Optical, and Cubic Nonlinear Optical Properties of Ruthenium-Alkynyl-Functionalized Oligo(phenylenevinylene) Stars', ChemPlusChem, vol. 80, no. 8, pp. 1329-1340. Malvolti, F, Rouxel, C, Triadon, A et al 2015, '2,7-Fluorenediyl-Bridged Complexes Containing Electroactive "fe(?5-C5Me5)(?2-dppe)C=C-" End Groups: Molecular Wires and Remarkable Nonlinear Electrochromes', Organometallics, vol. 34, no. 22, pp. 5418-5437. Wang, A, Fang, Y, Yu, W et al 2014, 'Allyloxyporphyrin-functionalized multiwalled carbon nanotubes: Synthesis by radical polymerization and enhanced optical-limiting properties', Chemistry - An Asian Journal, vol. 9, no. 2, pp. 639-648.