研究领域

Physical

At present I divide my time equally between the Department and Selwyn College, where I am the Senior Tutor. In the Department my main role is as the Director of Teaching, having overall responsibility for the delivery of the undergraduate chemistry course. My own teaching is mainly in the area of introductory physical and theoretical chemistry e.g. thermodynamics, high-resolution spectroscopy, and applications of elementary group theory. My research interests have been in the area of high-resolution nuclear magnetic resonance (NMR) spectroscopy, particularly in the development and application of new techniques. Some of our publications and associated software, as well as lecture notes from various NMR summer schools, are available on the group web server www-keeler.ch.cam.ac.uk . I am Editor-in-Chief of of the journal Magnetic Resonance in Chemistry, and immediate past-Chairman of the Royal Society of Chemistry's NMR Discussion Group. Please note that at present I am not recruiting any post doctoral workers, PhD students or summer visitors. I have authored three text books, two on general chemistry and one on NMR.

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Two-dimensional J-spectra with absorption-mode lineshapes. J. Magn. Reson., 189, 293-299 (2007). Broadband proton-decoupled proton spectra. Magn. Reson. Chem., 45, 296-316 (2007). Development of a method for the measurement of long-range C-H coupling constants from HMBC spectra. J. Magn. Reson., 166, 53-68 (2004). Elimination of Zero-Quantum Interference in Two-Dimensional NMR Spectra. Angew. Chem., Int. Ed. Engl., 42, 3938-3941 (2003). Single-Scan Longitudinal Relaxation Measurements in High-Resolution NMR Spectroscopy. J. Magn. Reson.. 164, 321-328 (2003). A fast method for the measurement of diffusion coefficients: one-dimensional DOSY. Magn. Reson. Chem. 41, 441-447 (2003). Temperature accuracy and temperature gradients in solution-state NMR spectrometers. J. Magn. Reson. 159, 55-61 (2002). One-Dimensional DOSY. J. Magn. Reson. 153, 103-112 (2001). Measurement of Convection and Temperature Profiles in Liquid Samples. J. Magn. Reson. 139, 334 (1999). One-dimensional NOE experiments using pulsed field gradients, J. Magn. Reson. 125, 302 (1997). An approach to the structure determination of larger proteins using triple resonance NMR experiments in conjunction with random fractional deuteration, J. Am Chem. Soc. 118, 407 (1996). A convenient and accurate method for the measurements of the values of spin-spin coupling constants, J. Magn. Reson. Ser. A 112, 43 (1995). Spin topology from 'Taylored' TOCSY, J. Magn. Reson. Ser. A 114, 188 (1995).