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个人简介

教育经历 2008.92013.9厦门大学有机化学博士 2004.92008.7厦门大学化学学士 工作经历 2017.12至今大连理工大学张大煜学院特聘研究员A岗 2014.112017.12德国明斯特大学博士后 2013.92014.8厦门大学能源材料化学协同创新中心博士后

研究领域

1. 金属硼多重键的结构调控及反应性研究 通过对金属中心配体和硼部分取代基的调控,设计合成结构新颖且稳定的金属硼双重键以及三重键化合物,并研究其反应性。通过对重要中间体的分离,深入研究反应机理,开拓新反应。 2. 金属硼受阻路易斯酸碱对化学 以构筑结构为基础,研究其与不饱和有机物﹑氢气﹑一氧化碳﹑二氧化碳,氧气和氮气等的反应性,并探索其作为催化剂在有机合成中的应用(比如催化氢化反应﹑硼基化反应﹑硅烷化反应及氢胺化反应等)。在金属有机化学和硼化学上发展新概念、新反应并深入研究这些新概念、新反应与材料科学、生物科学、能源科学等交叉融合。

近期论文

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1. Tongdao Wang, Constantin G. Daniliuc, Christian Mueck-Lichtenfeld, Gerald Kehr, Gerhard Erker* Formation of Reactive p-Conjugated Frustrated N/B Pairs by Borane-Induced Propargyl Amine Rearrangement, J. Am. Chem. Soc. 2018, 140, 3635−3643. 2. Tongdao Wang, Gerald Kehr, Lei Liu, Stefan Grimme, Constantin G. Daniliuc, Gerhard Erker* Selective Oxidation of an Active Intramolecular Amine/Borane Frustrated Lewis Pair with Dioxygen, J. Am. Chem. Soc. 2016, 138, 4302−4305. 3. Tongdao Wang, Jun Zhu, Feifei Han, Chen Zhou, Hanyu Chen, Hong Zhang*, Haiping Xia* Synthesis of Five-membered Osmacycloallenes and Conversion into Six-membered Osmacycloallenes, Angew. Chem. Int. Ed. 2013, 52, 13361-13364. 4. Tongdao Wang+, Hong Zhang+, Feifei Han, Lipeng Long, Zhenyang Lin*, Haiping Xia* Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization in an Osmabenzene System, Angew. Chem. Int. Ed. 2013, 52, 9251–9255. (+contributed equally) 5. Tongdao Wang+, Hong Zhang+, Feifei Han, Ran Lin, Zhenyang Lin*, Haiping Xia* Synthesis and Characterization of a Metallapyridyne Complex, Angew. Chem. Int. Ed. 2012, 51(39): 9838-9841. (+contributed equally) 6. Tongdao Wang, Shunhua Li, Hong Zhang, Ran Lin, Feifei Han, Yumei Lin, Ting Bin Wen, Haiping Xia* Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole, Angew. Chem. Int. Ed. 2009, 48, 6453-6456. 7. Tongdao Wang, Long Wang, Constantin G. Daniliuc, Kamil Samigullin, Matthias Wagner, Gerald Kehr, Gerhard Erker* CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template, Chem. Sci. 2017, 8, 2457-2463. 8. Tongdao Wang, Feifei Han, Haiping Huang, Jinhua Li, Hong Zhang*, Jun Zhu, Zhenyang Lin*, Haiping Xia* Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation, Sci. Rep. 2015, 5, 9584. 9. Tongdao Wang, Gerald Kehr, Constantin G. Daniliuc, Gerhard Erker* Metal-Free Carbonylation Route to a Reactive Borataepoxide System, Organometallics 2018, 37, 1040-1049. 10. Tongdao Wang+, Sonja Kohrt+, Constantin G. Daniliuc, Gerald Kehr and Gerhard Erker* Borata-Wittig olefination reactions of ketones, carboxylic esters and amides with bis(pentafluorophenyl)borata-alkene reagents Org. Biomol. Chem. 2017, 15, 6223-6232.(+contributed equally) 11. Tongdao Wang, Xenia Jentgens, Constantin G. Daniliuc, Gerald Kehr, and Gerhard Erker* Tris(pentafluorophenyl)borane-Catalyzed Reaction of Phosphorus/Boron and Nitrogen/Boron Frustrated Lewis Pair Dihydrogen Activation Products with Alkenes and Alkynes, ChemCatChem 2017, 9, 651-658. 12. Tongdao Wang, Lei Liu, Stefan Grimme, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker* Cyclic Amine/Borane Lewis Pairs by the Reaction of N,NDiallylaniline with Lancaster’s H2B-C6F5 Reagent, Chem. Asian J. 2016, 11, 1394–1399. 13. Tongdao Wang+, Hong Zhang+, Feifei Han, Lipeng Long, Zhenyang Lin*, Haiping Xia* cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study, Chem. Eur. J. 2013, 19, 10982–10991. (+contributed equally) 14. Shunxi Dong, Long Wang, Tongdao Wang, Constantin G. Daniliuc, Melanie Brinkkötter, Hellmut Eckert, Gerald Kehr, Gerhard Erker* Formation and reactions of active five-membered phosphane/borane frustrated Lewis pair ring systems, Dalton Trans., 2018, DOI: 10.1039/c8dt00672e 15. Lipeng Long, Xiaoxi Zhou, Tongdao Wang, Zhixin Chen, Hong Zhang,* Haiping Xia* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine, Organometallics 2017, 36, 4184−4190. 16. Feifei Han, Jinhua Li, Hong Zhang,* Tongdao Wang, Zhenyang Lin,* Haiping Xia* Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene, Chem. Eur. J. 2015, 21, 565–567. 17. Feifei Han, Tongdao Wang, Jinhua Li, Hong Zhang*, Haiping Xia* A Novel m-Metallaphenol: Synthesis and Reactivity Studies, Chem. Eur. J. 2014, 20, 4363–4372. 18. Feifei Han, Tongdao Wang, Jinhua Li, Hong Zhang, Laiying Zhang, Xumin He*, Haiping Xia* Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex, Organometallics 2014, 33, 5301−5307. 19. Hong Zhang*, Ran Lin, Guangning Hong, Tongdao Wang, Ting Bin Wen, Haiping Xia* Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes, Chem. Eur. J. 2010, 16, 6999-7007.

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