段春迎 - 大连理工大学

个人简介

1986年、1989年吉林大学先后获学士与硕士学位，1992年南京大学获博士学位并留校任教。曾在香港中文大学和英国诺丁汉大学做访问学者。2010年获国家杰出青年基金资助。主要从事功能配位化学研究，研究内容聚焦于金属-有机限域空间的可控组装、仿生识别与不对称催化等。提出的利用构建富含酰胺基团的金属-有机笼状结构的组装策略，广泛用于多种拟酶体系的可控合成与功能强化；利用非手性单元组装的催化材料被Chem. Rev.评价为MOFs不对称催化的重要进展之一(Milestones)。同时，将染料分子组装金属-有机超分子体系的思路，应用于新型能源材料的拓展与研制。近年来，承担国家自然科学基金委员会重大、重点项目和国际合作重点项目以及科技部“973”子课题项目。在J. Am. Chem. Soc., Angew. Chem. Int. Ed., Nature Commun.等国际高水平刊物上发表SCI论文200余篇，论文被他引11000余次。获得国家自然科学二等奖 1 项，省部级一等奖 4 项。

研究领域

1. 光功能金属-有机超分子的构建和电子转移过程控制可见光激发下的电子转移过程控制和光生电子-空穴的有效分离是影响和控制光化学过程的关键。传统的分子内和分子间过程面临光致电子输运增速和电子-空穴电荷分离态的稳定的相互影响和制约。通过笼状和环状超分子体系特殊的结构限域，利用染料耦合和染料包合等方式实现光功能金属-有机限域体系的可控组装，结合限域空间对其他电子转移和能量传递过程的屏蔽，建立高效高选择性的光诱导准分子内电子转移，提升光驱动电子转移的速率和电荷分离的效率。 2. 金属-有机手性结构的精准合成与不对称催化反应的结构匹配不对称催化技术是制备以手性药物为代表的精细化工中间体的主要方法，对于多手性中心化合物，要求催化剂能同时与底物基团的多个原子相互作用形成具有合适立体构型的稳定过渡态，需要多个手性中心和高位阻的复杂手性催化剂和贵金属化合物协同催化。利用超分子限域体系的结构匹配，控制手性模板剂与构筑单元间的弱相互作用方式，建立利用潜手性配体和金属中心组装手性金属-有机限域结构的平台方法。通过限域空间对底物结构的限制和手性催化中心协同，提升不对称催化的效率和立体选择性，为发展多手性中心不对称合成的非均相催化技术，实现手性催化材料和助剂的快速方便分离与回收提供新的研究思路。 3. 多功能金属-有机限域结构的可控组装与串联反应的动力学协同多个独立催化反应的协同是由基础化工原料通过多步化学反应形成精细化工中间体等的重要课题。独立催化活性中心在复合材料中的结构耦合，独立催化反应间的动力学速率匹配以及不同亲/疏水性物种的在反应体系中的快速扩散控制在实现多步串联反应的高效协同与转化过程中至关重要。发挥金属-有机限域体系结构可控的优势，将二氧化碳吸附与环氧烷烃催化活化位点耦合于金属-有机限域空间内部。通过二氧化碳吸附、烯烃氧化、立体选择性催化等活性位点的结构匹配和反应中间体的共用，利用二氧化碳和烯烃等基础化工原料“一锅法”制备高附加值手性碳酸酯。

近期论文

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Jianwei Wei, Liang Zhao,* Yu Zhang, Gang Han, Cheng He, Chong Wang, and Chunying Duan,* Enzyme Grafting with a Cofactor-Decorated Metal–Organic Capsule for Solar-to-Chemical Conversion, J. Am. Chem. Soc., 2023, 145, 6719−6729. Zhong Wei, XuJing,* Yang Yang, Jiayou Yuan, Mingxu Liu, Cheng He, and ChunyingDuan, A Platinum(II)-Based Molecular Cage with Aggregation-Induced Emission for Enzymatic Photocyclization of Alkynylaniline, Angew. Chem. Int. Ed., 2023, 62, e202214577. Huilin Huang, Xu Jing,*Jiangtao Deng, ChanggongMeng, and ChunyingDuan*, Enzyme-Inspired Coordination Polymers for Selective Oxidization of C(sp3)−H Bonds via Multiphoton Excitation, J. Am. Chem. Soc., 2023, 145, 2170−2182. Yusheng Shi, Peiyuan Wang, Mochen Li, Tiexin Zhang*, Gang Han*, and Chunying Duan*; A Diode-Like Dye-Cu Anisotropic Junction in a Coordination Polymer as a Logic State Ratchet for Intratumor Redox Photomodulation, Angew. Chem. Int. Ed., 2023, 62, e202219172. Yang Yang, Xu Jing, Jing Zhang, Fengyu Yang, ChunyingDuan. Modifying electron injection kinetics for selective photoreduction of nitroarenes into cyclic and asymmetric azo compounds. Nature Commun., 2022, 13, 1940. Guanfeng Ji, Liang Zhao,*Jianwei Wei, JunkaiCai, Cheng He, Zenggang Du, Wei Cai, and ChunyingDuan*, A Metal–Organic Framework as a Multiphoton Excitation Regulator for the Activation of Inert C(sp3)-H Bonds and Oxygen, Angew. Chem. Int. Ed., 2022, 61, e202114490. Junkai Cai, Liang Zhao,* Cheng He, Yanan Li, and Chunying Duan,* A Host−Guest Semibiological Photosynthesis System Coupling Artiﬁcial and Natural Enzymes for Solar Alcohol Splitting, Nat. Commun., 2021, 12, 5092. Fengyang Yu, Xu Jing,* Yao Wang, Mingyang Sun, and Chunying Duan*, Hierarchically Porous Metal–Organic Framework/ MoS2 Interface for Selective Photocatalytic Conversion of CO2 with H2O into CH3COOH, Angew. Chem. Int. Ed., 2021, 60, 24849–24853. Le Zeng, Ling Huang, Zhonghe Wang, Jianwei Wei, Kai Huang, Wenhai Lin, Chunying Duan,* and Gang Han*, Self-Assembled Metal–Organic Framework Stabilized Organic Cocrystals for Biological Phototherapy, Angew. Chem. Int. Ed., 2021, 60, 23569–23573. Liang Zhao, Junkai Cai, Yanan Li, Jianwei Wei, and Chunying Duan,* A Host−Guest Approach to Combining Enzymatic and Artificial Catalysis for Catalyzing Biomimetic Monooxygenation, Nat. Commun., 2020, 11, 2903. Yusheng Shi1,3, Tiexin Zhang 1,3, Xiao-Ming Jiang2, Gang Xu 2, Cheng He1 & Chunying Duan, Synergistic photoredox and copper catalysis by diode-like coordination polymer with twisted and polar copper–dye conjugation, Nat. Commun., 2020, 11, 5384. Xuezhao Li, Jinguo Wu, Lei Wang, Cheng He,* Liyong Chen, Yang Jiao, and Chunying Duan*, Mitochondrial-DNA-Targeted IrIII-Containing Metallohelices with Tunable Photodynamic Therapy Efficacy in Cancer Cells, Angew. Chem. Int. Ed., 2020, 59, 6420–6427. Jianwei Wei, Liang Zhao,* Cheng He, Sijia Zheng, Joost N. H. Reek, and Chunying Duan*, Metal−Organic Capsules with NADH Mimics as Switchable Selectivity Regulators for Photocatalytic Transfer Hydrogenation, J. Am. Chem. Soc. 2019, 141, 12707−12716. Tiexin Zhang, Xiangyang Guo, Yusheng Shi, Cheng He, Chunying Duan*, Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions, Nat. Commun. 2018, 9, 4024. Yang Jiao, Jiqiu Yin, Haiyang He, Xiaojun Peng, Qianmiao Gao, and Chunying Duan*, Conformationally Induced Off−On Cell Membrane Chemosensor Targeting Receptor Protein-Tyrosine Kinases for in Vivo and in Vitro Fluorescence Imaging of Cancers, J. Am. Chem. Soc. 2018, 140, 5882−5885. Liang Zhao, Jianwei Wei, Jing Zhang, Cheng He,* Chunying Duan*, Encapsulation of a Quinhydrone Cofactor in the Inner Pocket of Cobalt Triangular Prisms: Combined Light-Driven Reduction of Protons and Hydrogenation of Nitrobenzene, Angew. Chem. Int. Ed., 2017, 56, 15284–15288. Xu Jing, Yang Yang, Cheng He,* Zhiduo Chang, Joost N. H. Reek,* Chunying Duan*, Control of Redox Events by Dye Encapsulation Applied to Light-Driven Splitting of Hydrogen Sulfide, Angew. Chem. Int. Ed., 2017, 56, 11759–11763. Liang Zhao, Jianwei Wei, Junhua Lu, Cheng He,* Chunying Duan*, Renewable Molecular Flasks with NADH Models: Combination of Light-Driven Proton Reduction and Biomimetic Hydrogenation of Benzoxazinones, Angew. Chem. Int. Ed., 2017, 56, 8692–8696. Bo Qi, Xiangyang Guo, Yunyi Gao, Dong Li, Jiancheng Luo, Hui Li, Seyed Ali Eghtesadi, Cheng He, Chunying Duan,* Tianbo Liu*, Strong Co-Ion Effect via Cation−π Interaction on the Self-Assembly of Metal−Organic Cationic Macrocycles, J. Am. Chem. Soc., 2017, 139, 12020−12026. Zhengqiang Xia, Cheng He, Xiaoge Wang, Chunying Duan*, Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization, Nat. Commun., 2017, 8, 361. Le Zeng, Tao Liu, Cheng He, Dongying Shi, Feili Zhang, and Chunying Duan*, Organized Aggregation Makes Insoluble Perylene Diimide Efficient for the Reduction of Aryl Halides via Consecutive Visible Light-Induced Electron-Transfer Processes, J. Am. Chem. Soc. 2016, 138, 3958−3961. Zhen Zhou, Cheng He, Jinghai Xiu, Lu Yang, and Chunying Duan*, Metal−Organic Polymers Containing Discrete Single-Walled Nanotube as a Heterogeneous Catalyst for the Cycloaddition of Carbon Dioxide to Epoxides, J. Am. Chem. Soc. 2015, 137, 15066−15069. Xu Jing, Cheng He, Yang Yang, and Chunying Duan*, A Metal−Organic Tetrahedron as a Redox Vehicle to Encapsulate Organic Dyes for Photocatalytic Proton Reduction, J. Am. Chem. Soc. 2015, 137, 3967−3974. Qiuxia Han, Bo Qi, Weimin Ren, Cheng He, Jingyang Niu and Chunying Duan, Polyoxometalate-based homochiral metal-organic frameworks for tandem asymmetric transformation of cyclic carbonates from olefins, Nat. Commun. 2015, 6 10007. Qiuxia Han, Cheng He, Min Zhao, Bo Qi, Jingyang Niu, and Chunying Duan*, Engineering Chiral Polyoxometalate Hybrid Metal−Organic Frameworks for Asymmetric Dihydroxylation of Olefins, J. Am. Chem. Soc. 2013, 135, 10186−10189. Pengyan Wu, Cheng He,* Jian Wang, Xiaojun Peng, Xuezhao Li, Yonglin An, and Chunying Duan*, Photoactive Chiral Metal−Organic Frameworks for Light-Driven Asymmetric α‑Alkylation of Aldehydes, J. Am. Chem. Soc. 2012, 134, 14991−14999. Xu Jing, Cheng He, Dapeng Dong, Linlin Yang, and Chunying Duan*, Homochiral Crystallization of Metal–Organic Silver Frameworks: Asymmetric [3+2] Cycloaddition of an Azomethine Ylide, Angew. Chem. Int. Ed. 2012, 51, 10127–10131. Jian Wang, Cheng He,* Pengyan Wu, Jing Wang, and Chunying Duan*, An Amide-Containing Metal-Organic Tetrahedron Responding to a Spin-Trapping Reaction in a Fluorescent Enhancement Manner for Biological Imaging of NO in Living Cells, J. Am. Chem. Soc. 2011, 133, 12402–12405. Dongbin Dang, Pengyan Wu, Cheng He, Zhong Xie, and Chunying Duan*, Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis, J. Am. Chem. Soc. 2010, 132, 14321–14323. Chunying Duan,* Meilin Wei, Dong Guo, Cheng He, and Qingjin Meng, Crystal Structures and Properties of Large Protonated Water Clusters Encapsulated by Metal-Organic Frameworks, J. Am. Chem. Soc. 2010, 132, 3321–3330. Guangjie He, Dong Guo, Cheng He, Xiaolin Zhang, Xiuwen Zhao, and Chunying Duan*, A Color-Tunable Europium Complex Emitting Three Primary Colors and White Light, Angew. Chem. Int. Ed. 2009, 48, 6312–6135. Cheng He, Zhihua Lin, Zheng He, Chunying Duan,* Chunhu Xu, Zheming Wang, and Chunhua Yan*, Metal-Tunable Nanocages as Artificial Chemosensors, Angew. Chem. Int. Ed. 2008, 47, 877–881.