Yamaguchi, Junichiro - Waseda University - Department of Applied Chemistry

个人简介

Education 2002 B.S. Tokyo University of Science, Japan (Professor Yujiro Hayashi) 2004 M.S. Tokyo University of Science, Japan (Professor Yujiro Hayashi) 2005 Exchange Student, The Scripps Research Institute, USA (Professor K. C. Nicolaou) 2007 Dr. of Eng. Tokyo University of Science, Japan (Professor Yujiro Hayashi) Academic Careers 2007 Postdoctoral Researcher, The Scripps Research Institute, USA (with Professor. Phil S. Baran) 2008 Assistant Professor, Graduate School of Science, Nagoya University, Japan (with Professor Kenichiro Itami) 2012 Associate Professor, Nagoya University, Japan 2016 Associate Professor ( PI), Waseda University, Japan 2018 Professor, Waseda University, Japan

研究领域

Stretching the limits in building molecules/destroying molecules/creating game-changing molecules. A molecule—which is the smallest fundamental unit of matter that exhibits the properties of the substance—can be structurally combined in an infinite number of ways. Building a multitude of such molecules while exploring new chemical space is not only “fun” but also opens up “new possibilities” to serve the chemical, as well as the global, community. The discipline that can realize the creation of new molecules is synthetic chemistry. In order to contribute to the continued development of synthetic chemistry, our research goals are three-fold: building molecules/destroying molecules/creating game-changing molecules. To tackle these fundamental pursuits in synthetic chemistry, we aim to become masters in the art of molecular construction by using unique synthetic strategies and catalyst designs.

近期论文

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Fluorination –A Decade of Progress (2010-2020) Suto, S.; Yamaguchi, J. J. Synth. Org. Chem. Jpn 2021, 79, 910-967. Convergent Azaspirocyclization of Bromoarenes with NTosylhydrazones by a Palladium Catalyst Yanagimoto, A.; Uwabe, Y.; Wu, Q.; Muto, K.; Yamaguchi, J. ACS Catal. 2021,11, 10429-10435. Ni-Catalyzed Aryl Sulfide Synthesis through an Aryl Exchange Reaction Isshiki, R.; Kurosawa, M. B.; Muto, K.; Yamaguchi, J. J. Am. Chem. Soc. 2021, 143, 10333–10340. Development of Pd-Catalyzed Denitrative Couplings Asahara, K.; Kashihara, M.; Muto, K.; Nakao, Y.; Yamaguchi, J. J. Synth. Org. Chem. Jpn. 2021, 79, 11–21. Decarbonylative Synthesis of Aryl Nitriles from Aromatic Esters and Organocyanides by a Nickel Catalyst Iizumi, K.; Kurosawa, M. B.; Isshiki, R.; Muto, K.; Yamaguchi, J. Synlett 2021,32, 1555–1559. Synthesis of Decaarylanthracene with Nine Different Substituents Asako, T.; Suzuki, S.; Tanaka, S.; Ota, E.; Yamaguchi, J.ChemRxiv. 2020, preprint DOI chemrxiv.12410093 A unique small molecule pair controls the plant circadian clock Uehara, T. N.; Takao, S.; Matsuo, H.; Saito, A.N.; Ota, E.; Ono, A.; Itami, K.; Kinoshita, T.; Yamaguchi, J.; Nakamichi, N.BioRxiv. 2020, preprint DOI 10.1101/2020.05.25.113746 Catalytic Three-component C–C Bond Forming Dearomatization of Bromoarenes with Malonates and Diazo Compounds Kato, H.; Musha, I.; Komatsuda, M.; Muto, K.; Yamaguchi, J.Chem. Sci. 2020, Accepted Manuscript.DOI 10.1039/D0SC02881A Ester Dance Reaction on the Aromatic Ring Matsushita, K.; Takise, R.; Muto, K.; Yamaguchi, J.Sci. Adv. 2020, 6, eaba7614.DOI 10.1126/sciadv.aba7614 σ-Bond Hydroboration of Cyclopropanes Kondo H.; Miyamura, S.; Matsushita, K.; Kato, H.; Kobayashi, C.: Arifin; Itami, K.; Yokogawa, D.; Yamaguchi, J.J. Am. Chem. Soc. 2020, 142, 11306–11313.DOI 10.1021/jacs.0c05213 Synthesis of A Pentaarylcarbazole: Installation of Different Aryl Groups on Benzenoid Moiety Tanaka, S.; Asako, T.; Ota, E.; Yamaguchi, J.Chem Lett. 2020, 49, 918–920.DOI 10.1246/cl.200302 Solvent Selection Scheme Using Machine Learning Based on Physicochemical Description of Solvent Molecules: Application to Cyclic Organometallic Reaction Fujinami, M.; Maekawara, H.; Isshiki, R.; Seino, J.; Yamaguchi, J.; Nakai, H.Bull. Chem. Soc. Jpn 2020, 93, 841–845.DOI10.1246/bcsj.20200045 Catalytic Deoxygenative Coupling of Aromatic Esters with Organophosphorus Compounds Kurosawa, M. B.; Isshiki, R.; Muto, K.; Yamaguchi, J.J. Am. Chem. Soc. 2020, 142, 7386–7392.DOI 10.1021/jacs.0c02839 Pd-Catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allyltributylstannane Kayashima, Y.; Komatsuda, M.; K.; Muto, K.; Yamaguchi, J.Chem Lett. 2020, 49, 836–839.DOI 10.1246/cl.200216 Dearomative Allylation of Naphthyl Cyanohydrins by Palladium Catalysis: Catalyst-Enhanced Site Selectivity Yanagimoto, A.; Komatsuda, M.; Muto, K.; Yamaguchi, J.Org. Lett. 2020, 22, 3423–3427.DOI 10.1021/acs.orglett.0c00897 Palladium-Catalyzed Mizoroki–Heck Reaction of Nitroarenes and Styrene Derivatives Okita, T.; Asahara, K. K.; Muto, K.; Yamaguchi, J.Org. Lett. 2020, 22, 3205–3208.DOI 10.1021/acs.orglett.0c00983 Ester Transfer Reaction of Aromatic Esters with Haloarenes and Arenols by a Nickel Catalyst Isshiki, R.; Inayama, N.; Muto, K.; Yamaguchi, J.ACS Catal. 2020, 10, 3490-3494. Asymmetric Synthesis of a 5,7-Fused Ring System Enabled by an Intramolecular Buchner Reaction with Chiral Rhodium Catalyst Hoshi, T.; Ota, E.; Inokuma, Y.; Yamaguchi, J.Org. Lett.. 2019, 21, 10081–10084. Pd-Catalyzed Alkenyl Thioether Synthesis from Thioesters and N-Tosylhydrazones Ishitobi, K.; Muto, K.; Yamaguchi, J.ACS Catal. 2019, 9, 11685-11690.DOI10.1021/acscatal.9b04212 Pd-Catalyzed Dearomative Three-Component Reaction of Bromoarenes with Diazo Compounds and Allylborates Komatsuda, M.; Kato, H.; Muto, K.; Yamaguchi, J.ACS Catal. 2019, 9, 8991–8995.DOI 10.1021/acscatal.9b03461