研究领域
Our research interests relate to the field of materials chemistry with particular specialisation in the area of crystalline nanoporous materials. Such materials are utilized on a world wide scale in a diverse array of areas including heterogeneous catalysis, ion-exchange, gas and liquid separation processes, nuclear waste remediation, optoelectronics and drug delivery.
The core of our research takes place in the Centre for Nanoporous Materials and recently, the main focus of the group has been directed towards metal organic frameworks - the newest family of nanoporous material that is receiving global research attention. These hybrid materials consist of frameworks constructed from metal cations and organic linker groups and are of particular interest because within one material the benefits of both types of chemistry are present - the metal cations impart their own particular magnetic, electronic and catalytic properties, while the organic sections enable the functionality and the overall framework architecture of the material to be rationally designed.
The major research themes involving metal organic frameworks include: (1) crystal growth (2) synthesis and design of new materials (3) properties and application.
近期论文
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Chompoonoot Nanthamathee, Sanliang Ling, Ben Slater, Martin P. Attfield. Contradistinct Thermoresponsive Behavior of Isostructural MIL-53 Type Metal–Organic Frameworks by Modifying the Framework Inorganic Anion. Chemistry of Materials. 2015; 27(1): 85-95. eScholarID:250715 | DOI:10.1021/cm503311x
Rachel L. Smith, Pavla Eliášová, Michal Mazur, Martin P. Attfield, Jiří Čejka, Michael W. Anderson. Atomic Force Microscopy of Novel Zeolitic Materials Prepared by Top-Down Synthesis and ADOR Mechanism. 2014; 20(33): 10446-10450. eScholarID:250713 | DOI:10.1002/chem.201402887
Pablo Cubillas, Kimberley Etherington, Michael W. Anderson, Martin P. Attfield. Crystal growth of MOF-5 using secondary building units studied by in situ atomic force microscopy. CrystEngComm. 2014; 16(42): 9834-9841. eScholarID:250714 | DOI:10.1039/C4CE01710B
Cubillas, Pablo; Anderson, Michael W.; Attfield, Martin P. : Influence of Isomorphous Substituting Cobalt Ions on the Crystal Growth of the MOF-5 Framework Determined by Atomic Force Microscopy of Growing Core-Shell Crystals. Crystal Growth & Design. 2013 October; 13(10): 4526-4532. eScholarID:215401 | DOI:10.1021/cg401001f
Moh, Pak Y.; Brenda, Magdalena; Anderson, Michael W.; Attfield, Martin P. Crystallisation of solvothermally synthesised ZIF-8 investigated at the bulk, single crystal and surface level. CrystEngComm. 2013; 15(45): 9672-9678. eScholarID:215407 | DOI:10.1039/c3ce40943k
Bushell, AF; Attfield, MP; Mason, CR; Budd, PM; Yampolskii, Y; Starannikova, L; Rebrov, A; Bazzarelli, F; Bernardo, P; Jansen, JC; Lanc, M; Friess, K; Shantarovich, V; Gustov, V; Isaeva, V. Gas permeation parameters of mixed matrix membranes based on the polymer of intrinsic microporosity PIM-1 and the zeolitic imidazolate framework ZIF-8. JOURNAL OF MEMBRANE SCIENCE. 2013 January; 427: 48-62. eScholarID:193958
Dr. Pablo Cubillas, Prof. Michael W. Anderson and Dr. Martin P. Attfield. Materials Discovery and Crystal Growth of Zeolite A Type Zeolitic–Imidazolate Frameworks Revealed by Atomic Force Microscopy. Chemistry - A European Journal. 2013; 19: eScholarID:194165 | DOI:10.1002/chem.201300778
Bushell, AF; Budd, PM; Attfield, MP; Jones, JTA; Hasell, T; Cooper, AI; Bernardo, P; Bazzarelli, F; Clarizia, G; Jansen, JC. Nanoporous Organic Polymer/Cage Composite Membranes. Angewandte Chemie International Edition. 2013 January; 52(4): 1253-1256. eScholarID:193961 | DOI:10.1002/anie.201206339
Pablo Cubillas, Michael W. Anderson, Martin P. Attfield. Crystal Growth Mechanisms and Morphological Control of the Prototypical Metal Organic Framework, MOF-5, Revealed by Atomic Force Microscopy. Chemistry - A European Journal. 2012; eScholarID:170615 | DOI:10.1002/chem.201202261
Attfield, Martin P.; Cubillas, Pablo. Crystal growth of nanoporous metal organic frameworks. DALTON TRANSACTIONS. 2012; 41(14): 3869-3878. eScholarID:170489 | DOI:10.1039/c2dt12006b
Holden, MA ; Cubillas, P; Attfield, MP; Gebbie, JT; Anderson, MW. Growth Mechanism of Microporous Zincophosphate Sodalite Revealed by In Situ Atomic Force Microscopy. Journal of the American Chemical Society. 2012 August; 134(31): 13066-13073. eScholarID:170493 | DOI:10.1021/ja303814p
Attfield, MP; Mendieta-Tan, C; Telchadder, RN; Roberts, MA. Synthesis, crystal structure and properties of a novel framework aluminium diphosphonate. RSC ADVANCES. 2012; 2(27): 10291-10297. eScholarID:193962
P. Y. Moh, P. Cubillas, M. W. Anderson and M. P. Attfield. Revelation of the Molecular Assembly of the Nanoporous Metal Organic Framework ZIF-8. Journal of the American Chemical Society. 2011 August; 133(34): 13304-13307. eScholarID:138448 | DOI:10.1021/ja205900f
M. P. Attfield, Z. Yuan, H. G. Harvey, W. Clegg. Structural variety within gallium diphosphonates affected by the organic linker length. Inorganic Chemistry. 2010; 49(6): 2656-2666. eScholarID:78698 | DOI:10.1021/ic901651d