个人简介

1980 - 1985 Chemiestudium, Universität Leipzig (Diplom 1985) 1985 - 1988 Doktorarbeit, Universität Leipzig (R. Kirmse/E. Hoyer; Electron Nuclear Double Resonance, ENDOR, und Electron Spin Echo Envelope Modulation, ESEEM, von Übergangsmetall-Komplexen) 1988 - 1990 Wissenschaftlicher Assistent, Fakultät für Chemie, Universität Leipzig 1990 - 1993 Universität Fribourg (Schweiz, A. von Zelewsky) 1993 - 1994 Eidgenössische Technische Hochschule, ETH Zürich (Schweiz, A. Baiker) 1994 - 1996 Liebig-Stipendiat (Fonds der Chemischen Industrie), Fritz Haber Institut der Max-Planck-Gesellschaft, Berlin (R. Schlögl) 1996 Habilitation, Technische Universität Berlin seit 1996 Professor für Anorganische Chemie (C3), Fakultät für Chemie, Technische Universität München. 1999 - 2002 kommissarischer Leiter des Instituts für Radiochemie der TU München. 2005-2007 Studiendekan der Fakultät für Chemie der TU München 2008 Otto- Moensted- Gastprofessur an der Technical University of Denmark, Kopenhagen (DTU)

研究领域

Inorganic and Analytic Chemistry

The work focuses on the preparation, structural characterization and catalytic properties of transition metal compounds on surfaces of solids. The synthesis of solids and the modification of their surfaces centres on the development of materials with new properties and of new heterogeneous catalysts e.g. for fine chemical syntheses

近期论文

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Abatement of NO Using Rhodium Catalysts Supported on Carbon Nanotubes: Carbon as Support Material and Reducing Agent H.Beyer; K. Chatziapostolou; K. Koehler, Topics in Catalysis ,2009, 52(13-20), 1752 Increased Conversion in the Heck Reaction Under Irradiation with Light M. A. Fredricks.; K. Koehler, Catalysis Letters,2009,, 133(1-2), 23 Amination of aryl chlorides and fluorides toward the synthesis of aromatic amines by palladium-catalyzed route or transition metal free way: Scopes and limitations W. Kleist; S. Proeckl; M. Drees; K. Koehler; L.Djakovitch, Journal of Molecular Catalysis A: Chemical ,2009, 303(1-2), 15 Pd/MOx materials synthesized by sol-gel coprecipitation as catalysts for carbon-carbon coupling reactions of aryl bromides and chlorides W. Kleist; J.-K. Lee; K. Koehler, European Journal of Inorganic Chemistry,2009,(2), 261 Supported palladium catalysts for Suzuki reactions: structure-property relationships, optimized reaction protocol and control of palladium leaching. K.Koehler; R.Heidenreich ; S. S.Soomro; S.Proeckl, Advanced Synthesis & Catalysis ,2008, 350(18), 2930 Solvent-ligated copper(II) complexes for the homopolymerization of 2-methylpropene Y.Li; L.Voon; H.Yeong; A.Hijazi.; N. Radhakrishnan; K. Koehler; B. Voit; O. Nuyken; F.Kuehn, Chemistry--A European Journal ,2008, 14(26), 7997 Amination reactions T.Mallat; A.Baiker; W. Kleist; K. Koehler, Handbook of Heterogeneous Catalysis (2nd Edition), 2008, 7,3548 Selective catalytic reduction of NO by C3H8 over CoOx/Al2O3: An investigation of structure-activity relationships Ch.He; M. Paulus; W. Chu; J. Find; J. Nickl; K.Koehler, Catalysis Today ,2008, 131(1-4), 305 Heck Reactions of Aryl Chlorides Catalyzed by Ligand Free Palladium Salts W.Kleist,S.Pröckl, K.Köhler, Catal. Lett. 2008,128,197. Genesis of Coordinatively Unsaturated Palladium Complexes Dissolved from Solid Precursors during Heck Coupling Reactions and Their Role as Catalytically Active Species K. Köhler, W. Kleist, S. S. Pröckl, Inorg. Chem., 2007, 46, 1876. A Simple Aqueous Phase Synthesis of High Surface Area Aluminum Fluoride and its Bulk and Surface Structure W. Kleist, C. Haeßner, O. Storcheva, K. Köhler, Inorg. Chim. Acta,2006,359, 4851. Method for Carrying out CC-Coupling Reactions J. Krauter, J. Pietsch, P. Panster, K. Köhler, R. Heidenreich, US-Patent 7.102.045, 2006 Selective Catalytic Reduction of NO by Propane over CoOx/Al2O3: An Investigation of the Surface Reactions Using In Situ Infrared Spectroscopy C. He, K. Köhler, Phys. Chem. Chem. Phys., 2006, 8, 898. Applications of Heterogeneous Pd Catalysts in Heck Coupling Reactions - Problems, Potential and Recent Advances K. Köhler, S. S. Pröckl, W. Kleist, Curr. Org. Chem., 2006, 10, 1585. Design of Highly Active Heterogeneous Palladium Catalysts for the Activation of Aryl Chlorides in Heck Reactions S. S. Pröckl, W. Kleist, K. Köhler, Tetrahedron, 2005, 61, 9855. In-situ Infrared Spectroscopic Studies on the Mechanism of the Selective Catalytic Reduction of NO by C3H8 over Ga2O3/Al2O3 - High Efficiency of the Reducing Agents C. He, M. Paulus, J. Find, J. A. Nickl, H.-J. Eberle, J. Spengler, W. Chu, K. Köhler, J. Phys. Chem. B, 2005, 109, 15906. Identification of Surface States on Finely Divided Supported Palladium Catalysts by Means of Inelastic Incoherent Neutron Scattering P. W. Albers, J. G. E. Krauter, D. K. Ross, R. G. Heidenreich, K. Köhler, S. F. Parker, Langmuir, 2004, 20, 8254. In situ generation of highly active dissolved palladium species from solid catalysts - A concept for the activation of aryl chlorides in the Heck reaction S. S. Pröckl, W. Kleist, M. A. Gruber, K. Köhler, Angewandte Chemie- International Edition, 2004, 43, 1881-1882. Heterogeneous catalysts for hydroamination reactions: structure-activity relationship J. C. Penzien, C. Haeßner, A. Jentys, K. Köhler, T. E. Müller and J. A. Lercher, Journal of Catalysis, 2004, 221, 302-312. Incorporation of manganese and iron into the zirconia lattice in promoted sulfated zirconia catalysts F. C. Jentoft, A. Hahn, J. Krohnert, G. Lorenz, R. E. Jentoft, T. Ressler, U. Wild, R. Schlögl, C. Haeßner, K. Köhler, Journal of Catalysis, 2004, 224, 124-137.