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个人简介

1999 Habilitation (venia legendi) in Inorganic Chemistry, ETH Zürich, Switzerland Research field: solid-state and main-group chemistry 1988 Ph. D. in Chemistry, University of Heidelberg (Prof, G. Huttner) Research field: organometal chemistry 1978-1984 Study of Chemistry and Mathematics at the University of Konstanz

研究领域

Inorganic and Analytic Chemistry

The research interests are located at the interface between molecular and solid state chemistry, and involve synthesis, structural characterisation, as well as the study of the electronic and magnetic properties of soluble main group element clusters, fullerides and intermetallic compounds. Main topics are structure-property relations in semiconductors, superconductors and metals as well as molecular clusters. The experimental work is supported by theoretical investigations and graphical analysis of the quantum chemical results.

近期论文

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Synthesis, structure and properties of NaP7, a phosphorus rich polyphosphide C. Grotz, M. Köpf, M. Baumgartner, L. A. Jantke, G. Raudaschl-Sieber, T. F. Fässler, T. Nilges Z. Anorg. Allg. Chem. in press Crystal structure of Mg0.39(2)NiSn1.61(2) and Mg2.61(2)Ni4Sn3.39(2) featuring Mg/Sn atom networks with different connections of Ni@(Mg/Sn)8 coordination polyhedra L. Siggelkow, V. Hlukhyy, T. F. Fässler Z. Anorg. Allg. Chem. in press Linking Deltahedral Zintl Clusters with Conjugated Organic Building Blocks: Synthesis and Characterization of the Zintl triad [RGe9–CH═CH–CH═CH–Ge9R]4– M. M. Bentlohner, W. Klein, T. F. Fässler Angew. Chem. Int. Ed in press Fully and Partially Lithium-Stuffed Diamond Polytypes with Ag-Ge Structures: Li2AgGe and Li2.53AgGe2 A. Henze, V. Hlukhyy, T. F. Fässler Inorg. Chem. 54 (2015) 1152−1158. Alkali metal extraction reactions with the silicides Li15Si4 and Li3NaSi6: amorphous Si versus allo-Si M. Zeilinger, L.-A. Jantke, L. M. Scherf, F. J. Kiefer, G. Neubüser, L. Kienle, A. J. Karttunen, S. Konar, U. Häussermann, T. F. Fässler Chem. Mater. 26 (2014) 6603−6612. The Reduction of Pyridine by K12Si17 to the 4,4’-Bipyridine Radical Anion [C10H8N2]1-·: Crystal Structure and Spectroscopic Characterization of [K([2.2.2]crypt)][C10H8N2] C. B. Benda,T. F. Fässler Z. Naturforsch., 69b (2014) 1119-1123. Vibrational dynamics of the host framework in Sn clathrates B. M. Leu, M. Sturza, M. Y. Hu, D. Gosztola, V. Baran, T. F. Fässler, E. E. Alp Phys. Rev. B, 2014, 90, 104304. Metal-Centered Zintl Ions Isolated by Direct Extraction from Endohedral Intermetallic Precursor: [Co@Sn9]4- and [Co2@Sn17]5- H. He, W. Klein, L. A. Jantke, T. F. Fässler Z. Anorg. Allg. Chem., 640 (2014) 2864–2870. On the formation of intermetalloid clusters: Titanocen(III)diammin as a versatile reactant towards nonastannide Zintl Clusters C. B. Benda, M. Waibel, T. F. Fässler Angew. Chem. Int. Ed., 54 (2015) 522 – 526. (DOI: 10.1002/anie.201407855) Synthesis, structure and chemical bonding in CaCoSi A. V. Hoffmann, V. Hlukhyy, T. F. Fässler Z. Anorg. Allg. Chem., (2014) 2881-2888. (DOI: 10.1002/zaac.201400356) Structure and vibrational analyses of LiP15 N. Eckstein, L. A. Jantke, T. F. Fässler, J. Mink, M. Drees, T. Nilges Eur. J. Inorg. Chem., (2014) 5135–5144.

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