个人简介

Ph.D., Indiana University, 1983

研究领域

Organometallic Chemistry Materials Chemistry Inorganic Chemistry

Use of ligand design to control the reactivity of main-group and transition metal organometallic and coordination complexes; investigation of steric effects on the reactivity and magnetic properties of metal complexes; synthesis of precursors to materials with desirable electronic/optical properties; computational investigation of bonding and structure in inorganic systems.

近期论文

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Boyde NC, Chmely SC, Hanusa TP, Rheingold AL, Brennessel WW. Structural Distortions in M[E(SiMe3)(2)](3) Complexes (M = Group 15, f-Element; E = N, CH): Is Three a Crowd? Inorganic Chemistry. 2014, 18 (53): 9703-9714. Lichtenberg C, Spaniol TP, Peckermann I, Hanusa TP, Okuda J. Cationic, Neutral, and Anionic Allyl Magnesium Compounds: Unprecedented Ligand Conformations and Reactivity Toward Unsaturated Hydrocarbons. Journal of the American Chemical Society. 2013, 135 (2): 811-821. Engerer LK, Carlson CN, Hanusa TP, Brennessel WW, Young VG. Sigma- vs pi-Bonding in Manganese(II) Allyl Complexes. Organomettallics. 2012, 31 (17): 6131-6138. Jochmann P, Spaniol TP, Chmely SC, Hanusa TP, Okuda J. Preparation, Structure, and Ether Cleavage of a Mixed Hapticity Allyl Compound of Calcium. Organomettallics. 2011, 30 (19): 5291-5296. Bierschenk EJ, Wilk NR, Hanusa TP. 2,4-Pentanediolate as an Alkoxide/Diketonate "Hybrid" Ligand and the Formation of Aluminum and Zirconium Derivatives. InOrganic Chemistry. 2011, 50 (23): 12126-12132. Engerer LK, Hanusa TP. Geometric Effects in Olefinic Cation-pi Interactions with Alkali Metals: A Computational Study. Journal of Organic Chemistry. 2011, 76 (1): 42-49. ChmelySC, Hanusa TP, Brennessel WW. Bis(1,3-trimethylsilylallyl)beryllium. Angewandte Chemie-International Edition. 2010, 49 (34): 5870-5874. Quisenberry KT, White RE, Hanusa TP, Brennessel WW. Allyl complexes of the heavy alkaline-earth metals: molecular structure and catalytic behavior. New Journal of Chemistry. 2010, 34 (8): 1579-1584. Schmidt BW, Rogers BR, Gren CK, Hanusa TP. Carbon incorporation in chemical vapor deposited aluminum oxide films. Thin Solid Films. 2010, 518 (14): 3658-3663. Crisp JA, Meier RM, Overby JS, Hanusa TP, Rheingold AL, Brennessel WW. Indenyl Complexes of Manganese(II). Conformational Flexibility of the Manganese(II) (RnC9H7-n) Bond. Organometallics. 2010, 29 (10): 2322-2331. Chmely SC, Hanusa TP. Complexes with Sterically Bulky Allyl Ligands: Insights into Structure and Bonding. European Journal of Inorganic Chemistry. 2010, 9: 1321-1337. Schmidt BW, Sweet WJ, Bierschenk EJ, Gren CK, Hanusa TP, Rogers BR. Metal-organic chemical vapor deposition of aluminum oxide thin films via pyrolysis of dimethylaluminum isopropoxide. Journal of Vacuum Science & Technology A. 2010, 28 (2): 238-243. Meredith MB, McMillen CH, Goodman JT, Hanusa TP. Ambient temperature imidazolium-based ionic liquids with tetrachloronickelate(II) anions. Polyhedron. 2009, 28 (12): 2355-2358. Gren CK, Hanusa TP, Rheingold AL. Solvent-resistant structures of base-free lithium and potassium allyl complexes, M[(SiMe3)(n)C3H5-n] (M = Li, n=3; M = K, n=2). Main Group Chemistry. 2009, 8 (4): 225-235. Hanusa T. Exploring the Relationships Between Main Group and f-Element Chemistry Transfer of ownership for 2010 Preface. Main Group Chemistry. 2009, 8 (4): 223-224. Harvey MJ, Burkey DJ, Chmely SC, Hanusa TP. Stability of cyclopentadienyl aryloxide complexes of calcium and barium. Journal of Alloys and Compounds. 2009, 488 (2): 528-532. Johns AM, Chmely SC, Hanusa TP. Solution Interaction of Potassium and Calcium Bis(trimethylsilyl)amides; Preparation of Ca[N(SiMe3)(2)](2) from Dibenzylcalcium. Inorganic Chemistry. 2009, 48 (4): 1380-1384. Chmely SC, Carlson CN, Hanusa TP, Rheingold AL. Classical versus Bridged Allyl Ligands in Magnesium Complexes: The Role of Solvent. Journal of the American Chemical Society. 2009, 131 (18): 6344-+. Meredith MB, Crisp JA, Brady ED, Hanusa TP, Yee GT, Pink M, Brennessel WW, Young VG. Tunable Spin-Crossover Behavior in Polymethylated Bis(indenyl)chromium(II) Complexes: The Significance of Benzo-Ring Substitution. Organometallics. 2008, 27 (21): 5464-5473. Brady ED, ChmelySC, JayaratneKC, HanusaTP, Young VG, Jr. s-Block Metal Complexes of the Bis(tetramethylcyclopentadienyl) Phosphonium Diylide [Me(t-Bu)P(C5Me4)2]– . Organometallics. 2008, 27 (7): 1612-1616. Quisenberry KT, Gren CK, White RE, Hanusa TP, Brennessel WW. Trimethylsilylated allyl complexes of the heavy alkali metals, M[1,3-(SiMe3)(2)C3H3](thf)(n) (M = K, Cs). Organometallics. 2007, 26 (17): 4354-4356. White RE, Hanusa TP, Kucera BE. Compositional variations in monomeric trimethylsilylated allyl lanthanide complexes. Journal of Organometallic Chemistry. 2007, 692 (16): 3479-3485.