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个人简介

1985年毕业于宜春师专,1991年获兰州大学硕士学位,1994年获南京大学博士学位,1994-1996年中国科学院福建物质结构研究所博士后,1997-1998年中山大学副研究员,2001年起被聘为中国科学院福建物质结构研究所研究员、博士生导师。 2000年入选中国科学院人才计划,2006年获国家杰出青年基金资助,2007年入选新世纪人才工程国家级人选,2009年获政府特殊津贴。

研究领域

金属-有机磷光材料及其有机发光二极管(OLED) 有机-无机杂化材料发光性能及光电器件研究(LED, OLED, Scintillator, CPL, CPEL, Afterglow) 单分子导电机理及单分子电导技术拓展 配合物电致变色材料与器件 配位分子笼的主客体化学、小分子催化和生物医学应用

近期论文

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Xue, S. H.; Yao, J.Y.; Xu, L. J.; Chen, Z. N., Advances in electrically driven light-emitting diodes based on lead-free metal halides. Chem Commun. 2023, DOI: 10.1039/D2CC06680G. Shi, C.M.; Xuan, H.L.; Wu, Y.; Xu, L. J.; Chen, Z. N., Tunable Luminescence on Indium Halide Hybrid Regulated by Sb3+ Doping Concentration. Adv. Opt. Mater. 2022, 10, 2202376. Liang, X.; Pan, Z. Y..; Guo, W.; Mack, J.; Soy, R.; Nyokong, T.; Zhang, Q. C.; Zhu, W., Regulating the Single-Molecule Conductance of Corroles by the Substituents on the B-Site. J. Phys. Chem. C. 2022, 10, doi.org/10.1021/acs.jpcc.2c07140. Lu, H.Y.; Xu, L. J.; Wang, J.Y.; Chen, Z. N., Highly specific fluorescent probe toward acetic acid via structural transformation of Zinc complex. J. Mater. Chem. C. 2022, 10, 16666. Wu, Y.; Shi, C. M.; Kang, S. R.; Xu, L. J., Antimony-doped indium-based halide single crystals enabling white-light emission. Inorg. Chem. Front. 2022, 9, 5008-5015. Zheng, Y.; Duan, P.; Zhou, Y.; Li, C.; Zhou, D.; Wang, Y.; Chen, L.; Zhu, Z.; Li, X.; Bai, J.; Qu, K.; Gao, T.; Shi, J.; Liu, J.; Zhang, Q. C.; Chen, Z. N.; Hong, W., Fano Resonance in Single-Molecule Junctions. Angew. Chem. Int. Ed. 2022, e202210097. Ye, J.; Al-Jobory, A.; Zhang, Q. C.; Cao, W.; Alshehab, A.; Qu, K.; Alotaibi, T.; Chen, H.; Liu, J.; Ismael, A. K.; Chen, Z. N.; Lambert, C. J.; Hong, W., Highly insulating alkane rings with destructive sigma-interference. Sci. China Chem. 2022, 65, 1822. Sang, Y. F.; Zeng, H.; Xu, L. J.; Chen, Z. N., Radical Hybrids with Multiple Responses to Thermal Stimuli via Electron Transfer. Adv. Funct. Mater. 2022, 32, 2206459. Sang, Y. F.; Xu, L. J.; Chen, Z. N., Morphology Engineering toward Highly Emissive Mn2+ Doped PEA2PbBr4 Perovskite with Their LED Application via Phosphonium Passivation. Chinese J. Struct. Chem. 2022, 41, 2205070-2205076 (http://manu30.magtech.com.cn/jghx/CN/abstract/abstract2966.shtml) Qu, K.; Pan, Z. Y.; Wang, J. Y.; Zhang, B.; Zeng, H.; Sang, Y. F.; Zhang, Q. C.; Chen, Z. N., Removing the Destructive Quantum Interference in Cross Conjugation System by Structural Restraint. Chem. Res. Chinese Univ. 2022, DOI: 10.1007/s40242-022-2136-4. Wang, Q.; Wang, J. Y.; Zeng, H.; Zhang, L. Y.; Chen, Z. N., Sensitized ligand narrow-band phosphorescence for high-efficiency solution-processed OLEDs. Sci. China Chem. 2022, 65, 1559. Chen, X.; Li, C.; Cao, X.; Jia, X.; Chen, X.; Wang, Z.; Xu, W.; Dai, F. R.; Zhang, S., Mitochondria-targeted supramolecular coordination container encapsulated with exogenous itaconate for synergistic therapy of joint inflammation. Theranostics 2022, 12, 3251. Xuan, H. L.; Sang, Y. F.; Xu, L. J.; Zheng, D. S.; Shi, C. M.; Chen, Z. N., Amino-Acid-Induced Circular Polarized Luminescence in One-Dimensional Manganese(II) Halide Hybrid. Chem. Euro. J. 2022, 28, e202201299. Xuan, H. L.; Li, J. L.; Xu, L. J.; Zheng, D. S.; Chen, Z. N., Circularly Polarized Luminescence based on 0D Lead-Free Antimony (III) Halide Hybrids. Adv. Optical Mater. 2022, 10, 2200591. Zheng, D. S.; Yang, M.; Wang, J. Y.; Chen, Z. N., Highly Phosphorescent Dimers of PtAu2 Complexes and the Use in Solution-Processed OLEDs. ACS Appl. Mater. & Inter. 2022, 14, 23669. Zeng, H.; Wang, J. Y.; Shi, L. X.; Zhang, L. Y.; Chen, Z. N., Platinum(II)-gold(I) heterotrinuclear complexes with N,N '-diarylamine-functionalized acetylide ligands for red electroluminescence. Inorg. Chem. Front. 2022, 9, 3156. Duan, P.; Wang, Y.; Chen, L.; Qu, K.; Liu, J.; Zhang, Q. C.; Chen, Z. N.; Hong, W., Transport Modulation Through Electronegativity Gating in Multiple Nitrogenous Circuits. SMALL 2022, 18, 2200361. Liu, J. Y.; Sheng, T. P.; Li, C.; Wang, Z.; Dai, F. R.; Chen, Z. N., Iodine Adsorption via Porous Molecular Solids Based on Coordination Containers Derived from Naphthalene-1,8-dicarboxylate. Cryst. Growth Des. 2022, 22, 3182. Xie, P.; Wang, J. Y.; Huang, Y. Z.; Wu, X. M.; Chen, Z. N., Heteroctanuclear Au4Ag4 Cluster Complexes of 4,5-Diethynylacridin-9-One with Luminescent Mechanochromism. Molecules. 2022, 27, 2127. Shi, C. M.; Li, J. L.; Xu, L. J.; Wu, Y.; Xuan, H. L.; Wang, J. Y.; Chen, Z. N., Methanol-induced luminescence vapochromism based on a Sb3+-doped organic indium halide hybrid. Sci. China Mater. 2022, 65, 1876. Zhang, X.; Wang, J. Y.; Xu, L. J.; Jin, X. Y.; Yang, X.; Zhang, L. Y.; Chen, Z. N., Achieving T-Type Photochromism through Generating Copper(I) Metallacyclopentadiene Biradical. CCS Chemistry 2022, 4, 3832-3841. Li, J. L.; Sang, Y. F.; Xu, L. J.; Lu, H. Y.; Wang, J. Y.; Chen, Z. N., Highly Efficient Light-Emitting Diodes Based on an Organic Antimony(III) Halide Hybrid. Angew. Chem. Int. Ed. 2022, 61(6), e202113450. Yan, S. S.; Wang, J. Y.; Pan, Z. Y.; Zheng, S. S.; Zhang, Q. C.; Chen, Z. N., Freezing the conductance of platinum(II) complexes by quantuminterference effect. Chinese Chem. Lett.2021,doi.org/10.1016/j.cclet.2021.10.092. Chen, X.; He, C.; Sheng, T.; Wang, Z.; Xu, W.; Dai, F.; Zhang, S., A magnesium-based coordination container as a multi-drugs co-loadedsystem for boosting anti-inflammatory therapy in joints. Chem. Eng. J.2021,415, 128939. Li, W.; Wang, B.; Miao, T.; Liu, J.; Lü, X.; Fu, G.; Shi, L.; Chen, Z. Qian P.; Wong, W. Y., C1-Symmetric [Ir(C^N1)(C^N2)(O^O)]-Tris-HeterolepticIridium(III)-Complexes with the Preferentially HorizontalOrientation for High-Performance Near-Infrared OrganicLight-Emitting Diodes. Adv. Optical Mater.2021, 9(15), 2100117. He, C.; Chen, X. Z.; Sun, C. Z.; Zhang, L. Y.; Xu, W.; Zhang, S.; Wang, Z.;Dai, F. R., Decahexanuclear Zinc(II) Coordination Container Featuring a Flexible Tetracarboxylate Ligand: A Self-Assembly Supermolecule for Highly Efficient Drug Delivery of Anti-Inflammatory Agents. ACS Appl. Mater. & Inter. 2021, 13(29), 33812-33820. Wang, Z. Y.; Zeng, H.; Shi, L. X.; Zhang, L. Y.; Xu, L. J.; Wang, J. Y.; Chen, Z. N., Solution-Processed Organic Light-Emitting Diodes of Yellow-Emitting PtAg2 Complexes with an External Quantum Efficiency of 21.7%. Energy& Fuels 2021, 35(23), 19132-19138. Qu, K.; Duan, P.; Wang, J. Y; Zhang, B..; Zhang, Q. C.; Hong, W.; Chen, Z. N., Capturing the Rotation of One Molecular Crank by Single-Molecule Conductance. Nano Lett. 2021, 21(22), 9729-9735. Sheng, T. P.; He, C.; Quan, J.; Wang, Z.; Zheng, G. Z.; Dai, F. R.; Chen, Z. N., Precise Assembly and Supramolecular Catalysis of Tetragonal- and Trigonal-Elongated Octahedral Coordination Containers. CCS Chemistry 2021,3, 1306-1315 (https://www.chinesechemsoc.org/doi/10.31635/ccschem.021.202100987) Chen, X.; He, C.; Sheng, T.; Wang, Z.; Xu, W.; Dai, F.; Zhang, S., A magnesium-based coordination container as a multi-drugs co-loaded system for boosting anti-inflammatory therapy in joints. Chem. Eng. J.2021, 415, 128939. Luo, S. Q.; Wang, Q.; Quan, J.; Yang, M.; Wang, Y.; Zhang, X.; Chen, Z. N., A sky-blue luminescent silver(I) complex with a one-dimensional zipper-like structure constructed with 2-diphenylphosphinopyridine and thiocyanate. Trans. Metal Chem. 2021,46(5), 415-421. Wang, Z. Y.; Shi, L. X.; Xu, L. J.; Zhang, L. Y.; Wang, J. Y.; Chen, Z. N., Modulating the carrier transport of PtAg2 heteronuclear complexes to attain highly efficient OLEDs with narrow-band emission. J. Mater. Chem. C 2021,9(16),5403-5410. Jiao, Z.; Yang, M.; Wang, J. Y.; Huang, Y. Z.; Xie, P.; Chen, Z. N., High-efficiency solution-processed light-emitting diode based on a phosphorescent Ag3Cu5 cluster complex. J. Mater. Chem. C 2021,9(16), 5528-5534. Quan, J.; Chen, Z. H.; Zhang, X.; Wang, J. Y.; Zhang, L. Y.; Chen, Z. N., Geometrically isomeric Pt2Ag2 acetylide complexes of 2,6-bis(diphenylphosphino)pyridine: luminescent and vapochromic properties. Inorg. Chem. Front. 2021,8(9), 2323-2332. Wu, Y.; Shi, C. M.; Xu, L. J.; Yang, M.; Chen, Z. N., Reversible Luminescent Vapochromism of a Zero-Dimensional Sb3+-Doped Organic-Inorganic Hybrid. J. Phys. Chem. Lett. 2021,12 (13), 3288-3294. Wang, Z. Y.; Zhang, L. Y.; Xu, L. J.; Shi, L. X.; Wang, J. Y.; Chen, Z. N., Elaborate Design of d(8)-d(10) Heteronuclear Phosphors for Ultrahigh-Efficiency Solution-Processed Organic Light-Emitting Diodes. ACS Appl. Mater. & Inter. 2021,13 (12), 14446-14452. Sheng, T. P.; Dai, F. R.; Zheng, G. Z.; Chen, Z. N., Synthesis, Crystal Structure and Gas Adsorption Properties of Metal-organic Supercontainer Based 2,6-Naphthalenedicarboxylate Linker. Chinese J. Struc. Chem. 2020,40 (3), 311-316. Duan, P.; Qu, K.; Wang, J. Y.; Zeng, B.; Tang, C.; Su, H. F.; Zhang, Q. C.; Hong, W.; Chen, Z. N., Effective Suppression of Conductance in Multichannel Molecular Wires. Cell Rep. Phys. Sci. 2021,2 (2), 100342. Duan, P.; Liu, J.; Wang, J. Y.; Qu, K.; Cai, S.; Wang, F.; Chen, L.; Huang, X.; Li, R.; Shi, J.; Zhang, Q. C.; Hong, W.; Chen, Z. N., Enhancing single-molecule conductance of platinum(II) complexes through synergistic aromaticity-assisted structural asymmetry. Sci. China Chem. 2020, 63 (4), 467-474. He, C.; Sheng, T. P.; Dai, F. R.; Chen, Z. N., Sulfonylcalix[4]arene-based Coordination Supercontainers. Chinese J. Struc. Chem. 2020, 39 (12), 2077-2084. Huang, Y. Z.; Shi, L. X.; Wang, J. Y.; Su, H. F.; Chen, Z. N., Elaborate Design of Ag8Au10 Cluster [2]Catenane Phosphors for High-Efficiency Light-Emitting Devices. ACS Appl. Mater. Inter. 2020, 12 (51), 57264-57270. Pang, A. Y.; Li, J. L.; Wei, X. F.; Ruan, Z. W.; Yang, M.; Chen, Z. N., UV-O-3 treated annealing-free cerium oxide as electron transport layers in flexible planar perovskite solar cells. Nanoscale Adv 2020, 2 (9), 4062-4069. Ruan, Z. W.; Zhang, X.; Pang, A. Y.; Dai, F. R.; Chen, Z. N., Blue luminescent silver(I) complexes constructed by 2-diphenylphosphinopyridine and dicyanamide or tricyanomethanide. Inorg. Chem. Commun. 2020, 116. 107916. Sheng, T. P.; Fan, X. X.; Zheng, G. Z.; Dai, F. R.; Chen, Z. N., Cooperative Binding and Stepwise Encapsulation of Drug Molecules by Sulfonylcalixarene-Based Metal-Organic Supercontainers. Molecules 2020, 25 (11), 2656. Wang, Q.; Xiao, H.; Wu, Y.; Wang, Z. Y.; Zheng, D. S.; Chen, Z. N., From homonuclear to heteronuclear: a viable strategy to promote and modulate phosphorescence. Chem. Commun. 2020, 56 (73), 10607-10620. Wang, Z. Y.; Wang, J. Y.; Zhang, L. Y.; Yang, M.; Zhang, X.; Chen, Z. N., Substituent steric effect boosting phosphorescence efficiency of PtCu2 complexes. J. Mater. Chem. C 2020, 8 (15), 5174-5182. Wu, Y.; Wang, J. Y.; Zhang, L. Y.; Xu, L. J.; Chen, Z. N., Vapor-triggered Green-to-Yellow Luminescence Conversion due to the Variation of Ligand Orientations in Tetranuclear Copper(I) Complex. Inorg. Chem. 2020, 59 (23), 17415-17420. Wu, Y.; Yang, M.; Wang, J. Y.; Chen, Z. N., Recent Process of Luminescent Materials and Devices Based on Manganese(II) Complexes. Chinese J. Inorg. Chem. 2020, 36 (6), 1001-1013. Zhang, X.; Li, L. B.; Wang, J. X.; Wen, H. M.; Krishna, R.; Wu, H.; Zhou, W.; Chen, Z. N.; Li, B.; Qian, G. D.; Chen, B. L., Selective Ethane/Ethylene Separation in a Robust Microporous Hydrogen-Bonded Organic Framework. J. Am. Chem. Soc. 2020, 142 (1), 633-640. Zhang, X.; Zhang, L. Y.; Wang, J. Y.; Dai, F. R.; Chen, Z. N., Two-step phosphorescent mechanochromism due to intramolecular deformation. J. Mater. Chem. C 2020, 8 (2), 715-720. Zhang, Z. Y.; Su, Y.; Shi, L. X.; Li, S. F.; Fabunmi, F.; Li, S. L.; Yu, T.; Chen, Z. N.; Su, Z.; Liu, H. K., Coordination-Bond-Driven Dissolution-Recrystallization Structural Transformation with the Expansion of Cuprous Halide Aggregate. Inorg. Chem. 2020, 59 (18), 13326-13334. Duan, P.; Liu, J.; Wang, J. Y.; Chen, L.; Wang, F.; Zhang, Q. C.; Hong, W.; Chen, Z. N., Modulation of the conductance in platinum(ii) bis(acetylide) molecules through "gating" metal ions. J. Mater. Chem. C 2019, 7 (24), 7259-7266. Kang, J. J.; Ni, J.; Su, M. M.; Li, Y. Q.; Zhang, J. J.; Zhou, H. J.; Chen, Z. N., Facile and Equipment-Free Data Encryption and Decryption by Self-Encrypting Pt(II) Complex. ACS Appl. Mater. Inter. 2019, 11 (14), 13350-13358. Natarajan, N.; Shi, L. X.; Xiao, H.; Wang, J. Y.; Zhang, L. Y.; Zhang, X.; Chen, Z. N., PtAu3 cluster complexes with narrow-band emissions for solution-processed organic light emitting diodes. J. Mater. Chem. C 2019, 7 (9), 2604-2614. Qiao, D.; Wang, J. Y.; Zhang, L. Y.; Dai, F. R.; Chen, Z. N., Aggregation-induced emission enhancement and reversible mechanochromic luminescence of quinoline-based zinc(ii)-Schiff base complexes. Dalton Trans. 2019, 48 (29), 11045-11051. Sun, C. Z.; Sheng, T. P.; Dai, F. R.; Chen, Z. N., Sulfonylcalixaren-Based ortho-Dicarboxylate-Bridged Coordination Containers for Guest Encapsulation and Separation. Cryst. Growth Des. 2019, 19 (2), 1144-1148. Xiao, H.; Zhang, X.; Wang, J. Y.; Zhang, L. Y.; Zhang, Q. C.; Chen, Z. N., Enhancing Phosphorescence through Rigidifying the Conformation to Achieve High-Efficiency OLEDs by Modified PEDOT. ACS Appl. Mater. Inter. 2019, 11 (49), 45853-45861. Zhang, L. Y.; Duan, P.; Wang, J. Y.; Zhang, Q. C.; Chen, Z. N., Ruthenium(II) as Conductive Promoter To Alleviate Conductance Attenuation in Oligoynyl Chains. J. Phys. Chem. C 2019, 123 (9), 5282-5288. Zhang, Q. C.; Xiao, H.; Zhang, X.; Xu, L. J.; Chen, Z. N., Luminescent oligonuclear metal complexes and the use in organic light-emitting diodes. Coord. Chem. Rev. 2019, 378, 121-133. Zhang, X.; Wang, J. Y.; Huang, Y. Z.; Yang, M.; Chen, Z. N., Silver(i) nanoclusters of carbazole-1,8-bis(acetylide): from visible to near-infrared emission. Chem. Commun. 2019, 55 (44), 6281-6284. Bhuvaneswari, N.; Dai, F. R.; Chen, Z. N., Sensitive and Specific Guest Recognition through Pyridinium-Modification in Spindle-Like Coordination Containers. Chem. Eur. J. 2018, 24 (25), 6580-6585. Liao, J. L.; Rajakannu, P.; Gnanasekaran, P.; Tsai, S. R.; Lin, C. H.; Liu, S. H.; Chang, C. H.; Lee, G. H.; Chou, P. T.; Chen, Z. N.; Chi, Y., Luminescent Diiridium Complexes with Bridging Pyrazolates: Characterization and Fabrication of OLEDs Using Vacuum Thermal Deposition. Adv. Opt. Mater. 2018, 6 (11). Natarajan, N.; Shi, L. X.; Xiao, H.; Wang, J. Y.; Zhang, L. Y.; Zhang, X.; Chen, Z. N., Using phosphorescent PtAu3 clusters for superior solution-processable organic light emitting diodes with very small efficiency roll-off. J. Mater. Chem. C 2018, 6 (33), 8966-8976. Pang, A. Y.; Shen, D. L.; Wei, M. D.; Chen, Z. N., Highly Efficient Perovskite Solar Cells Based on Zn2Ti3O8 Nanoparticles as Electron Transport Material. Chemsuschem 2018, 11 (2), 424-431. Sun, C. Z.; Cheng, L. J.; Qiao, Y. P.; Zhang, L. Y.; Chen, Z. N.; Dai, F. R.; Lin, W.; Wang, Z. Q., Stimuli-responsive metal-organic supercontainers as synthetic proton receptors. Dalton Trans. 2018, 47 (30), 10256-10263. Sun, C. Z.; Zhang, L. Y.; Wang, J. Y.; Chen, Z. N.; Dai, F. R., Sensitive and selective urinary 1-hydroxypyrene detection by dinuclear terbium-sulfonylcalixarene complex. Dalton Trans. 2018, 47 (25), 8301-8306. Wu, Y.; Zhang, X.; Xu, L. J.; Yang, M.; Chen, Z. N., Luminescent Vapochromism Due to a Change of the Ligand Field in a One-Dimensional Manganese(II) Coordination Polymer. Inorg. Chem. 2018, 57 (15), 9175-9181. Wu, Y.; Zhang, X.; Zhang, Y. Q.; Yang, M.; Chen, Z. N., Achievement of ligand-field induced thermochromic luminescence via two-step single-crystal to single-crystal transformations. Chem. Commun. 2018, 54 (99), 13961-13964. Zhang, H. X.; Ke, W. S.; Zhu, C. Y.; Wang, J. Y.; Sasaki, Y.; Chen, Z. N.; Lin, C. W.; Wang, Z. B.; Liao, S.; Wu, W. W., Synthesis, characterization and properties of oxo-bridged diruthenium (III) complexes with thiocyanato and cyanato ligands. Inorg. Chim. Acta 2018, 469, 469-477.

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