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A gas - liquid - solid three phase reactor and its application, 201110331965.5 A kind of ethylenediamine and water azeotrope separation method, 201110409282.7 A kind of ethanol amine and ammonia as raw material preparation method of ethylenediamine, 201110416319.9 One for using phase transfer catalysts for catalytic reaction of continuous production equipment (utility model patents, invention patents) ,201110414274.1/201120518213.5 A gas - liquid - solid three phase reactor and its application, 201120416971.6