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研究领域

杨明辉研究员在大连化学物理研究所从事洁净能源材料研究。主要研究方向是具有特殊组成与结构的固体材料的物理化学性质及其应用。研究内容为材料的合成、晶体结构、物性及其在催化、电化学、导电、巨磁等方面的应用。合成方法包括常规的固相合成、纳米材料合成、氮化合成和高温高压合成等。晶体结构分析手段包括X-射线粉末衍射、同步辐射、中子和电子衍射等,并使用Rietveld精修法对材料的晶体结构进行分析得到详细的结构参数。材料的物理性能,如导电性和磁性等,主要使用PPMS和SQUID进行测试。使用电子显微镜TEM和SEM分析纳米材料的形貌结构。以上述方法为基础全方位地研究固体材料的结构、化学和物理性质及其相互关系。

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1. M. Yang, J. Oro′-Sole′, J. Rodgers, A. B. Jorge, A. Fuertes* and J. P. Attfield*, Anion order in perovskite oxynitrides, Nature Chemistry 2011, 3, 47  2. M. Yang, J. Oro?-Sole?, A. Kusmartsva, A. Fuertes* and J. P. Attfield*, Electronic Tuning of Two Metals and Colossal Magnetoresistances in EuWO1+xN2?x Perovskites, J. Am. Chem. Soc., 2010, 132, 4822  3. M. Yang, J. Oro?-Sole?, A. Fuertes* and J. P. Attfield*, Topochemical Synthesis of Europium Molybdenum Oxynitride Pyrochlores, Chem. Mater. 2010, 22, 4132  4. M. Yang, J. Rodgers, L. C. Middler, J. Oro?-Sole?, A. B. Jorge, A. Fuertes* and J. P. Attfield*, Direct solid state synthesis at high pressures of new mixed metal oxynitrides; RZrO2N (R = Pr, Nd, and Sm), Inorg. Chem. 2009, 48, 11498  5. A. Kusmartsva, M. Yang, J. Oro?-Sole?, A. B. Jorge, A. Fuertes* and J. P. Attfield*, Large magnetoresistances and non-Ohmic conductivity in EuWO1+xN2?x, Appl. Phys. Lett. 2009, 95, 022110  6. A. Kusmartsva, M. Yang, Angel M. Arevalo-Lopez, Konstantin V. Kamenev and J. Paul Attfield*, Pressure suppression of charge order without metallisation in Cs2Au2I6, Chem. Comm. 2010, 46, 6681  7.M. Yang, J. Oro′-Sole′, J. Rodgers, A. B. Jorge, A. Fuertes* and J. P. Attfield*, Anion order in perovskite oxynitrides, Nature Chemistry 2011, 3, 47 M. Yang, J. Oro?-Sole?, A. Kusmartsva, A. Fuertes* and J. P. Attfield*, Electronic Tuning of Two Metals and Colossal Magnetoresistances in EuWO1+xN2?x Perovskites, J. Am. Chem. Soc., 2010, 132, 4822 M. Yang, J. Oro?-Sole?, A. Fuertes* and J. P. Attfield*, Topochemical Synthesis of Europium Molybdenum Oxynitride Pyrochlores, Chem. Mater. 2010, 22, 4132 M. Yang, J. Rodgers, L. C. Middler, J. Oro?-Sole?, A. B. Jorge, A. Fuertes* and J. P. Attfield*, Direct solid state synthesis at high pressures of new mixed metal oxynitrides; RZrO2N (R = Pr, Nd, and Sm), Inorg. Chem. 2009, 48, 11498 A. Kusmartsva, M. Yang, J. Oro?-Sole?, A. B. Jorge, A. Fuertes* and J. P. Attfield*, Large magnetoresistances and non-Ohmic conductivity in EuWO1+xN2?x, Appl. Phys. Lett. 2009, 95, 022110 A. Kusmartsva, M. Yang, Angel M. Arevalo-Lopez, Konstantin V. Kamenev and J. Paul Attfield*, Pressure suppression of charge order without metallisation in Cs2Au2I6, Chem. Comm. 2010, 46, 6681 M. Yang, M. J. MacLeod, F. Tessier and F. J. DiSalvo*, Mesoporous metal nitride materials prepared from bulk oxides, J. Am. Ceram. Soc. 2012, 95, 3084 M. Yang*, Z. Cui and F. J. DiSalvo*, Mesoporous vanadium nitride as a high performance catalyst support for formic acid electrooxidation, Chem. Comm. 2012, 48, 10502 M. Yang*, Walter T. Ralston, Franck Tessier, Amy Allen and Francis J DiSalvo*, Mesoporous VN prepared by solid-solid phase separation, J. Solid State Chem. 2012, 197, 398 M. Yang and F. J. DiSalvo*, Template-Free Synthesis of Mesoporous Transition Metal Nitride Materials from Ternary Cadmium Transition Metal Oxides, Chem. Mater. 2012, 24, 4406 M. Yang*, Z. Cui and F. J. DiSalvo*, Mesoporous Titanium Nitride Supported Pt Nanoparticles as High Performance Catalysts for Methanol Electrooxidation, Phys. Chem. Chem. Phys. 2013, 15, 1088 M. Yang*, R. Guarecuco and F. J. DiSalvo*, Mesoporous Chromium Nitride as High Performance Catalyst Support for Methanol Electrooxidation, Chem. Mater. 2013, 25, 1783 M. Yang*, Z. Cui and F. J. DiSalvo*, Mesoporous chromium nitride as a high performance non-carbon support for the oxygen reduction reaction, Phys. Chem. Chem. Phys. 2013, 15, 7041 Z. Cui, M. Yang, and F. J. DiSalvo*, Mo2N/C hybrid material as a promising support for the electro-oxidation of methanol and formic acid, Electrochem. Comm. 2013, 33, 63 M. Yang*, A. J. Allen, Minh T. Nguyen, Walter T. Ralston, Michelle J. MacLeod and F. J. DiSalvo*, Corrosion Behavior of Mesoporous Transition Metal Nitrides, J. Solid State Chem. 2013, 205, 49 M. Yang*, A. Zakutayev?, J. vidal, X. Zhang, D. Ginley and F. J DiSalvo*, Synthesis and Optical Properties of CuTaN2: Potential Solar Cell Applications, Energy Environ. Sci. 2013, 6, 2994 M. Yang*, A. R. V. Wassen, R. Guarecuco, H. D. Abru?a and F. J. DiSalvo*, Nano-structured ternary niobium titanium nitrides as durable non-carbon supports for oxygen reduction reaction, Chem. Comm. 2013, 49, 10853 M. Hermus , M. Yang, D. Grüner , F. J. DiSalvo, and B. P. T. Fokwa*, Drastic Change of Magnetic Interactions and Hysteresis through site-preferential Ru/Ir Substitution in Sc2FeRu5–xIrxB2, Chem. Mater. 2014, 26, 1967 Z. Cui, M. Yang and F. J. DiSalvo*, Mesoporous Ti0.5Cr0.5N Supported PdAg Nanoalloy as Highly Active and Stable Catalysts for the Electro-oxidation of Formic Acid and Methanol, ACS Nano 2014, 8, 6106 A. Zakutayev, A. J. Allen, X. Zhang, J. Vidal, Z. Cui, S. Lany, M. Yang*, F J. DiSalvo, and D. S. Ginley*, Experimental Synthesis and Properties of Metastable CuNbN2 and Theoretical Extension to Other Ternary Copper Nitrides, Chem. Mater. 2014, 26, 4970 M. Yang, M. J. MacLeod, F. Tessier and F. J. DiSalvo*, Mesoporous metal nitride materials prepared from bulk oxides, J. Am. Ceram. Soc. 2012, 95, 3084  8. M. Yang*, Z. Cui and F. J. DiSalvo*, Mesoporous vanadium nitride as a high performance catalyst support for formic acid electrooxidation, Chem. Comm. 2012, 48, 10502

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