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个人简介

王军虎研究员、光谱学与纳米催化材料专家,中科院优秀导师奖获得者。 1991年毕业于兰州大学现代物理系(现核科学与技术学院)放射化学专业。1994年去日本工作和学习,1998年和2002年分别获得日本东邦大学理学研究科化学专业硕士和博士学位(与日本原子力研究所联合培养)。 1991年起先后在甘肃省敦煌研究院保护研究所、日本东京艺术大学保存科学教室、日本原子力研究所物质科学研究部、物质材料研究机构(NIMS)、产业技术综合研究所(AIST)、中京大学等单位从事科学研究和教学工作多年,并获日本文化财振兴财团、平和中岛财团、文部省等多项奖励基金支持。 2007年起回国担任中国科学院大连化学物理研究所研究员、博士生导师、穆斯堡尔谱研究组(DNL2005组)组长、穆斯堡尔谱数据中心(Mössbauer Effect Data Center, MEDC)秘书长及穆斯堡尔谱数据期刊(Mössbauer Effect Reference and Data Journal, MERDJ, ISSN 0163-9587)执行主编。 2008年获中国科学院引进国外杰出人才荣誉称号和奖励基金支持。在研究生培养工作中,成绩卓著,荣获2018年度“中国科学院优秀导师奖”。中国化学会和美国化学会会员,中国穆斯堡尔谱专业委员会委员,国际穆斯堡尔谱委员会 (International Board on the Applications of the Mössbauer Effect, IBAME)顾问委员,日本首都大学东京客座教授。

研究领域

1)原位穆斯堡尔谱技术的开发及其在化学和催化研究中的应用 2)纳米金和载体间强相互作用的研究 3)新型高效电解水催化材料和离子电池电极材料的开发和表征 4)纳米复合催化材料的开发及其在环境、能源领域的应用 5)纳米复合反应吸附材料的开发及其在环境、能源领域的应用 6)穆斯堡尔谱技术在深空探测中的应用 7)新型穆斯堡尔谱学数据库的开发和应用

近期论文

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Construction of Sintering-Resistant Gold Catalysts via Ascorbic-Acid Inducing Strong Metal-Support Interactions. Yunxia Liu, Guandong Wu, Lin Li, Yiming Niu, Bingsen Zhang, Botao Qiao*, Junhu Wang* Chinese Chemical Letters (2024) 110608 A Hypothesis on the Function of High-Valent Fe in Nife (Hydr)oxide in the Oxygen-Evolution Reaction Nader Akbari, Jafar Hussain Shah, Cejun Hu, Subhajit Nandy, Pavlo Aleshkevych, Rile Ge, Sumbal Farid, Changchang Dong, Liang Zhang, Keun Hwa Chae, Wei Xie, Taifeng Liu, Junhu Wang*, Mohammad Mahdi Najafpour Angewandte Chemie (2024) e202418798 Submicroscopic Magnetite May be Ubiquitous in the Lunar Regolith of the High-Ti Region Zhi Cao, Zhuang Guo, Chen Li, Sizhe Zhao, Yang Li, Qi He, Yuanyun Wen, Zhiyong Xiao, Xiongyao Li, Long Xiao, Lifang Li, Junhu Wang, Jianzhong Liu Science Advances 10/38 (2024) eadn2301 Advances in Catalytic Oxidation of Methane and Carbon Monoxide (2nd Edition) Hongxing Dai*, and Junhu Wang* Catalysts 14/9 (2024) 642 Visualizing Catalytic Dynamics of Single-Cu-Atom-Modified SnS2 in CO2 Electroreduction via Rapid Freeze-Quench Mössbauer Spectroscopy Ruru Chen, Jian Zhao,Xiong Zhang, Qiao Zhao, Yifan Li,Yi Cui,Miao Zhong,Junhu Wang,Xuning Li,* Yanqiang Huang,* and Bin Liu* J Am Chem Soc. 146/35 (2024) 24368-24376 In-situ/Operando Mössbauer Spectroscopic Investigations of Fe-involved Metal Hydroxide-Based OER Electrocatalysts. Peijia Liu, Sumbal Farid, Min Liu* & Junhu Wang* Catalysts Surveys from Asia (2024) Epsilon-Iron Carbide for the Hydrogenation of Carbonyl Groups in Esters Huijiang Huang, Xin Shang, Xin Li, Qiao Han, Qiang Wang, Junhu Wang, Shengping Wang, Peng Jin*, Yujun Zhao*, Xinbin Ma* ACS Catalysis 14/15 (2024) 11294–11301 PS-PPh2 tethered Pt single atoms promoted by SnCl2 as highly efficient and regio-selective catalysts for the hydroformylation of higher α-alkenes Zhounan Yu, Leilei Zhang*, Yuanlong Tan, Rizheng Jing, Hongchen Cao, Caiyi Lou, Rile Ge, Junhu Wang, Aiqin Wang*, Tao Zhang Chinese Journal of Catalysis 60 (2024) 316-326 Atmosphere-Dependent Strong Metal–Support Interactions in Au/ZnO Catalysts and Their Overlayer Permeability Guandong Wu, Yiwei Jiang, Yiming Niu, Bingsen Zhang, Lin Li, Li Xu, Yufei He*, Junhu Wang*, and Dianqing Li ACS Catal. 14/11 (2024) 8767–8775 Charge transfer induced highly active low-spin iron of Prussian blue cathode through calcination strategy for high performance Sodium-ion batteries Zinan Wang, Moulay Tahar Sougrati, Qiong Zheng*, Rile Ge, Junhu Wang* Chemical Engineering Journal 488 (2024) 151090 Highly Active and Sintering-Resistant Pt Clusters Supported on FeOx–Hydroxyapatite Achieved by Tailoring Strong Metal–Support Interactions Yunxia Liu, Guandong Wu, Rile Ge, Xunzhu Jiang, Lin Li, Tamao Ishida, Toru Murayama, Botao Qiao*, and Junhu Wang* ACS Appl. Mater. Interfaces 16/17 (2024) 22007–22015 Capacitive-Controlled Prussian White with a Nickel Iron Hexacyanoferrate Composite Cathode for Rapid Sodium Diffusion Zinan Wang, Moulay Tahar Sougrati, Qiong Zheng*, Rile Ge, and Junhu Wang* ACS Appl. Mater. Interfaces 16/15 (2024) 18908–18917 Prussian Blue Analogues and Their Derivatives: From Elaborate Microstructure Design to Boosted Fenton-Like Application Liang Zhang, Bofan Zhang, Guangda Xia, Xuning Li, and Junhu Wang* Acc. Mater. Res. 5/5 (2024) 585–599 Free-standing Stanene for High Selectivity of Formate in Electrocatalytic Carbon Dioxide Reduction Reaction Xuanhao Mei, Cong Liu, Dezheng Zhang, Jing Cao, Rile Ge, Junhu Wang, Weilin Xu. Advanced Energy Materials 14/13 (2024) 2303889 Decoration of Gold and Platinum Nanoparticle Catalysts by 1-nm-thick Metal Oxide Overlayer and its Effect on CO Oxidation Activity ​Okayama, Kaho; Nakayama, Akihiro; Murayama, Toru; Sakaguchi, Norihito; Hong, Feng; Qiao, Botao; Wang, Junhu; Shimada, Tetsuya; Takagi, Shinsuke; Ishida, Tamao ACS Applied Materials & Interfaces 16/4 (2024) 4570-4580 Photooxidation of Evaporative Ferrous-Ferric Sulfate Brines under a Martian CO2 Atmosphere Di-Sheng Zhou, Xiyu Wang, Yu-Yan Sara Zhao,* Weiqiang Li, Junhu Wang, Li Dongdong, Zongcheng Ling, Yang Li, Xiongyao Li, and Jianzhong Liu ACS Earth Space Chem. 8/1 (2024) 54-66 Toward a Comprehensive Hypothesis of Oxygen-evolution Reaction in the Presence of Iron and Gold N. Hashemi, J. H. Shah, C. Hu, S. Nandy, P. Aleshkevych, F. Sumbal, K. H. Chae, W. Xie, T. Liu, J. Wang, M. M. Najafpour J. Energy Chem. 89 (2024) 172-183 Impacts of Interaction between Active Components on Catalyst Deactivation over KFe/ZSM-5 Bifunctional Catalyst Di Xu, Haifeng Fan, Kaidi Liu, Guoqiang Hou, Chuan Qin, Yanfei Xu, Rui Li, Junhu Wang, and Mingyue Ding* ACS Sustainable Chem. Eng. 11/28 (2023) 10441–10452 Synthesis, Characterization, and Enhanced Sunlight-active Photocatalytic Property of Single-site Octahedral Iron(III) Oxide Complex - Grafted Graphene Oxide G. A. Sundaram, K. Namasivayam, L. Ramesh, S. P. D. Sadhasivam J. Alloys Compd. 968 (2023) 172068 Defect Engineering-Mediated Long-Lived Charge Transfer Excited State in Fe-gallate Complex Improves Iron Cycle And Enables Sustainable Fenton-like Reaction. Y. Shi, G. Zhang, C. Xiang, C. Liu, J. Hu, J. Wang, R. Ge, H. Ma, Y. Niu. Adv. Mater. 36/6 (2023) 2305162 Operando Mössbauer Spectroscopic Tracking the Metastable State of Atomically Dispersed Tin in Copper Oxide for Selective CO2 Electroreduction R. Chen, J. Zhao, Y. Li, Y. Cui, Y. Lu, S. Hung, S. Wang, W. Wang, G. Huo, Y. Zhao, W. Liu, J. Wang, H. Xiao, X. Li, Y. Huang, B. Liu J. Am. Chem. Soc. 145/37 (2023) 20683−20691 Correction to “Reentrant Spin Glass and Large Coercive Field Observed in a Spin Integer Dimerized Honeycomb Lattice”. Y. Zhai, Y. Deng, Z. Fu, E. Feng, Y. Su, T. Shiga, H. Oshio, Z. Klencsár, J. Wang, Y. Zheng. Adv. Funct. Mater. 33 (2023) 2111468 Effects of Iron Corrosion Products on the Degradation of Bentonite Structure and Properties. Y. Sun, Y. Zhou, X. Wei, J. Dong, N. Chen, Q. Ren, J. Wang, W. Ke npj Materials Degradation 7 (2023) 66 Photocatalytic and Antibacterial Activities of a Nickel(II)-Bipyridine Complex-Modified Graphene Oxide Nanocomposite: Synthesis and Characterization G. A. Sundaram, P. Ravikumar, L. Ramesh, H. Kesavan, S. P. D. Sadhasivam, S. K. K. Alagarsamy, J. Wang Catalysts 13 (2023) 1200 Mechanical Insight into Direct Singlet Oxygen Generation Pathway: Pivotal Role of FeN4 Sites and Selective Organic Contaminants Removal L. Zhang, Y. Sun, R. Ge, W. Zhou, Z. Ao, J. Wang. Applied Catalysis B: Environmental 339 (2023) 123130 Unraveling the Electronic Structure and Dynamics of the Atomically Dispersed Iron Sites in Electrochemical CO2 Reduction. Y. Zeng, J. Zhao, S. Wang, X. Ren, Y. Tan, Y. Lu, S. Xi, J. Wang, F. Jaouen, X. Li, Y. Huang, T. Zhang, B Liu J. Am. Chem. Soc. 145 (2023) 15600-15610 Gold/Substituted Hydroxyapatites for Oxidative Esterification: Control of Thin Apatite Layer on Gold Based on Strong Metal–Support Interaction (SMSI) Results in High Activity. A. Taketoshi, Y. Gangarajula, R. Sodenaga, A. Nakayama, M. Okumura, N. Sakaguchi, T. Murayama, T. Shimada, S. Takagi, M. Haruta, B. Qiao, J. Wang, T. Ishida ACS Appl. Mater. Interfaces 15 (2023) 34290-34302 Confirming High-Valent Iron as Highly Active Species of Water Oxidation on the Fe, V‑Coupled Bimetallic Electrocatalyst: In Situ Analysis of X‑ray Absorption and Mössbauer Spectroscopy R. Mehmood, W. Fan, X. Hu, J. Li, P. Liu, Y. Zhang, Z. Zhou, J. Wang, M. Liu, F. Zhang J. Am. Chem. Soc. 145 (2023) 12206-12213 Impact of Adding Fe Ions on the Local Structure and Electrochemical Performance of P2O5–V2O5 Glass and Glass Ceramics used as a Cathode in LIBs. A. Ibrahim, Y. Arita, A. S. Ali, I. Khan, B. Zhang, M. Razum, L. Pavic, A. Santic, Z. Homonnay, E. Kuzmann, M. Y. Hassaan, J. Wang, S. Kubuki J. Phys. Chem. Sol. 179 (2023) 111391 Construction of Homogeneous Catalyst Layers at Proton Exchange Membrane Fuel Cell Cathodes X. Li, X. Wang, J. He, T. Zheng, C. Xu, W. Zhou, J. Wang, J. Liu, Q. He J. Electrochem. Soc. 170 (2023) 044511 High-Temperature Oxidation of Magnesium- and Iron-Rich Olivine under a CO2 Atmosphere: Implications for Venus S. Zhong, Y. Zhao, H. Lin, R. Chang, C. Qi, J. Wang, B. Mo, Y. Wen, W. Yu, D. Zhou, X. Yu, X. Li, J. Liu Remote Sensing 15 (2023) 1959 Oxidative-Atmosphere-Induced Strong Metal–Support Interaction and Its Catalytic Application G. Wu, Y. Liu, J. Wang. Acc. Chem. Res. 56 (2023) 911-923 Operando Spectroscopic Analysis of Axial Oxygen-Coordinated Single-Sn-Atom Sites for Electrochemical CO2 Reduction. Y. Deng, J. Zhao, S. Wang, R. Chen, J. Ding, H. Tsai, W. Zeng, S. Hung, W. Xu, J. Wang, F. Jaouen, X. Li, Y. Huang, B. Liu J. Am. Chem. Soc. 145 (2023) 7242-7251 Maximizing Active Fe Species in ZSM‑5 Zeolite Using OrganicTemplate-Free Synthesis for Efficient Selective Methane Oxidation Q. Cheng, G. Li, X. Yao, L. Zheng, J. Wang, A.-H. Emwas, P. Castaño, J. Ruiz-Martínez, Y. Han J. Am. Chem. Soc. 145 (2023) 5888-5898 Sodium Storage and Capacity Retention Behavior Derived from High-spin/low-spin Fe Redox Reaction in Monoclinic Prussian Blue Based on Operando Mössbauer Characterization Z. Wang, M. T. Sougrati, Y. He, P. N. Le Pham, W. Xu, A. Iadecola, R. Ge, W. Zhou, Q. Zheng, X. Li, J. Wang Nano Energy 109 (2023) 108256 Optimizing the Electronic Structures of CaxSr1-xCo0.7Fe0.3O3-δ Anodes for High-temperature Oxygen Evolution Reaction W. Feng, T. Liu, R. Li, J. Li, X. Zhang, Q. Liu, J. Wang, M. Li, Q. Fu, Y. Song, G. Wang, X. Bao Chem Catalysis 3 (2023) 100504 Halogen-Incorporated Sn Catalysts for Selective Electrochemical CO2 Reduction to Formate T. Wang, J. Chen, X. Ren, J. Zhang, J. Ding, Y. Liu, K. Lim, J. Wang, X. Li, H. Yang, Y. Huang, S. Kawi, B. Liu Angew. Chem. Int. Edit. 62 (2023) e202211174 Modulation of Reaction Pathway of Prussian Blue Analogues Derived Zn-Fe Double Oxides towards Organic Pollutants Oxidation L. Zhang, B. Zhang, Y. Liu, Z. Wang, J. H. Shah, R. Ge, W. Zhou, S. Kubuki, J. Wang Chem. Eng. J. 454 (2023) 140103 Investigation of Nickel Iron Layered Double Hydroxide for Water Oxidation in Different pH Electrolytes Q. Xie, D. Ren, L. Bai, R. Ge, W. Zhou, L Bai, W. Xie, J. Wang, M Grätzel, J. Luo Chinese J. Catal. 44 (2023) 127-138 Ultrastable Fe–N–C Fuel Cell Electrocatalysts by Eliminating Non-Coordinating Nitrogen and Regulating Coordination Structures at High Temperatures D. Xia, X. Tang, S. Dai, R. Ge, A. Rykov, J. Wang, T. Huang, K. Wang, Y. Wei, K. Zhang, J. Li, L. Gan, F. Kang. Adv. Mater. 35 (2022) 2204474 Magnetic Field Manipulation of Tetrahedral Units in Spinel Oxides for Boosting Water Oxidation X. Lyu, Y. Zhang, Z. Du, H. Chen, S. Li, A. I. Rykov, C. Cheng, W. Zhang, L. Chang, W. Kai, J. Wang, L. Zhang, Q. Wang, C. Huang, E. Kan Small 18 (2022) 2204143 Enhanced Effect of the Mesoporous Carbon on Iron Carbide Catalyst for Hydrogenation of Dimethyl Oxalate to Ethanol M. Cao, H. Huang, Y. Zheng, Q. Zhang, S. Wang, R. Ge, J. Wang, Y. Zhao, X. Ma ChemCatChem 14 (2022) e202200500 A Monodisperse ε'-(CoxFe1-x)2.2C Bimetallic Carbide Catalyst for Direct Conversion of Syngas to Higher Alcohols Z. Zeng, Z. Li, L. Kang, X. Han, Z. Qi, S. Guo, J. Wang, A. I. Rykov, J. Lv, Y. Wang, X. Ma ACS Catalysis 12 (2022) 6016-6028 Enhancement Effect of Strong Metal-Support Interaction (SMSI) on the Catalytic Activity of Substituted-Hydroxyapatite Supported Au Clusters. A. Nakayama, R. Sodenaga, Y. Gangarajula, A. Taketoshi, T. Murayama, T. Honma, N. Sakaguchi, T. Shimada, S. Takagi, M. Haruta, B. Qiao, J. Wang, T. Ishida J. Catal. 410 (2022) 194-205 Selective Hydroboration of Terminal Alkynes Catalyzed by Heterometallic Clusters with Uranium–metal Triple Bonds. P. Wang, I. Douair, Y. Zhao, R. Ge, J. Wang, S. Wang, L. Maron, C. Zhu Chem 8 (2022) 1361-1375 In-situ/operando 57Fe Mössbauer Spectroscopic Technique and Its Applications in NiFe-based Electrocatalysts for Oxygen Evolution Reaction J. H. Shah, Q. Xie, Z. Kuang, R. Ge, W. Zhou, D. Liu, A. I. Rykov, X. Li, J. Luo, J. Wang J. Electrochem. 28(3) (2022) 2108541 Investigation on the Demetallation of Fe-N-C for Oxygen Reduction Reaction: the Influence of Structure and Structural Evolution of Active Site X. Xu, X. Zhang, Z. Kuang, Z. Xia, A. I. Rykov, S. Yu. J. Wang, S. Wang, G. Sun. Appl. Catal. B: Environ. 309 (2022) 121290 Preferential formation of Chlorate over Perchlorate on Mars controlled by Iron Mineralogy S. Qu, Y. Zhao, H. Cui, X. Yin, W. A. Jackson, X. Nie, Z. Wu, J. Wang, D. Zhou, C. Qi, X. Li, J. Liu Nature Astronomy 6 (2022) 436-441 Abrading Bulk Metal into Single Atoms G. Han , F. Li , A. I. Rykov , Y. Im, S. Yu, J. Jeon, S. Kim , W. Zhou, R. Ge, Z. Ao , T. Shin , J. Wang , H. Jeong , J. Baek Nature Nanotechnology 17 (2022) 403-407 CoFe Alloy Carbide Catalysts for Higher Alcohols Synthesis from Syngas: Evolution of Active Sites and Na Promoting Effect Z. Zeng, Z. Li, T. Guan, S. Guo, Z. Hu, J. Wang, A. Rykov, J. Lv, S. Huang, Y. Wang, X. Ma Journal of Catalysis 405 (2022) 430-444 A Thiolate-bridged Fe(IV)Fe(IV) μ-nitrido Complex And Its Hydrogenation Reactivity Toward Ammonia Formation. Y. Zhang, J. Zhao, D. Yang, B. Wang, Y. Zhou, J. Wang, H. Chen, T. Mei, S. Ye, J. Qu Nature Chemistry 14 (2022) 46-52 Self-assembly of MoS2 Nanosheet Adhered on Fe-MOF Heterocrystals for Peroxymonosulfate Activation via Interfacial Interaction ​L. Zhang, B. Zhang, L. Wang, R. Ge, W. Zhou, S. Kubuki, R. Wu, J. Wang J. Colloid Interf. Sci. 608 (2022) 3098-3110

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